Академический Документы
Профессиональный Документы
Культура Документы
Heat and Temperature, Thermal Properties of Matter, The First Law of Thermodynamics, The Second Law of Thermodynamics, Heat Engines, Internal-Combustion Engines, Refrigerators, Carnot Cycle, Entropy
Homework#1
1. What is a heat engine? 2. What is an internal-combustion engine? 3. How does an internal-combustion engine work? Enumerate. 4. How is heat transferred in a refrigerator? Enumerate.
Example
A surveyor uses a steel measuring tape that is exactly 50.000m long at a temperature of 20C. What is its length on a hot summer day when the temperature is 35C? = 1.2 x103/C
Example
Feed a cold, starve a fever: During a bout with the flu, an 80-kg man ran a fever of 2.0C above normal, that is a body temperature of 39.0C. Assuming that the body is mostly water, how much heat is required to raise his temperature by that amount? cwater= 4190J/Kg
Thermal Equilibrium, Temperature Scales, Thermal Expansion, Quantity of Heat, Calorimetry and Phase Changes, Mechanisms of Heat transfer
Thermometric Scales
1 cal = 4.186J 1 kcal =1000 cal = 4186 J 1 Btu= 778 ft.lb = 252 cal = 1055 J
Phase Changes
The term phase is used to describe the specific state of matter. A transition from one phase to another is called a phase change or phase transition.
Phase Change
Heat of fusion (Lf)- the heat required per unit mass in changing solid to liquid Heat of vaporization (Lv)- the heat required per unit mass in changing liquid to gas Heat of combustion (Lc) - the heat required per unit mass in complete combustion of one gram of gasoline
Example
A surveyor uses a steel measuring tape that is exactly 50.000m long at a temperature of 20C. What is its length on a hot summer day when the temperature is 35C? = 1.2 x103/C
50.009m
Example
Feed a cold, starve a fever: During a bout with the flu, an 80-kg man ran a fever of 2.0C above normal, that is a body temperature of 39.0C. Assuming that the body is mostly water, how much heat is required to raise his temperature by that amount? cwater= 4190J/Kg.K
6.7x105J= 133kcal
KMT
1. Gases are considered to be composed of minute discrete particles. 2. The molecule in a container are believed to be in ceaseless motion during which they collide with each other and the walls of the container
KMT
3. The molecular collision is perfectly elastic. 4. The molecules average KE is proportional to any given absolute temperature. 5. All forces of attraction are negligible due to rapid molecular separation.
Gas Laws
Boyles Law:P1 x V1 = P2 x V2 Charles Law: V1/T1 = V2/T2 Gay-Lussacs Law: P1/T1 = P2/T2
Example
How much faster does H2 travel than O2 molecule at the same temperature and pressure if molecular weights of H2 and O2 are 2g/mole and 32g/mole respectively? H2 molecules travel 4times faster than O2 molecules
Internal energy is the change in initial and final energies of the system
Internal energy is the sum of heat exchange between the system and the surroundings and W done on or by the system
Sign Convention W done on the system: + W done by the system: Heat added to the system: + Heat released by the system: -
Internal energy is the change in initial and final energies of the system
Internal energy is the sum of heat exchange between the system and the surroundings and W done on or by the system
Sign Convention W done on the system: W done by the system: + Heat added to the system: + Heat released by the system: -
2 vs 7
Thermodynamics Processes
Adiabatic: no heat transfer into or out of the system- Q=0 U= Q + W= W Isochoric: constant volume; it does no work- W=0 U= Q + W= Q
Thermodynamics Processes
Isobaric: constant pressure W= p(V2-V1) Isothermal: constant temperatureU=0 Q=W