Академический Документы
Профессиональный Документы
Культура Документы
Solutions
1
Chapter Goals
The Dissolution Process
2. Spontaneity of the Dissolution Process
3. Dissolution of Solids in Liquids
4. Dissolution of Liquids in Liquids (Miscibility)
5. Dissolution of Gases in Liquids
6. Rates of Dissolution and Saturation
7. Effect of Temperature on Solubility
8. Effect of Pressure on Solubility
9. Molality and Mole Fraction
2
Chapter Goals
Colligative Properties of Solutions
2. Lowering of Vapor Pressure and Raoult’s Law
3. Fractional Distillation
4. Boiling Point Elevation
5. Freezing Point Depression
6. Determination of Molecular Weight by Freezing
Point Depression or Boiling Point Elevation
7. Colligative Properties and Dissociation of
Electrolytes
8. Osmotic Pressure
3
Chapter Goals
Colloids
2. The Tyndall Effect
3. The Adsorption Phenomena
4. Hydrophilic and Hydrophobic Colloids
4
The Dissolution Process
5
The Dissolution Process
Seven Homogeneous Possibilities
Solute Solvent Example
Solid Liquid salt water
Liquid Liquid mixed drinks
Gas Liquid carbonated beverages
Liquid Solid dental amalgams
Solid Solid alloys
Gas Solid metal pipes
Gas Gas air
Two Heterogeneous Possibilities
Solid Gas dust in air
Liquid Gas clouds, fog
6
Spontaneity of the Dissolution
Process
As an example of dissolution, let’s assume that
the solvent is a liquid.
Two major factors affect dissolution of solutes
Change of energy content or enthalpy of
solution, ∆Hsolution
If ∆Hsolution is exothermic (< 0) dissolution is favored.
If ∆Hsolution is endothermic (> 0) dissolution is not
favored.
7
Spontaneity of the Dissolution
Process
Change in disorder, or randomness, of the
solution ∆Smixing
If ∆Smixing increases (> 0) dissolution is favored.
If ∆Smixing decreases (< 0) dissolution is not favored.
Thus the best conditions for dissolution are:
For the solution process to be exothermic.
∆Hsolution < 0
For the solution to become more disordered.
∆Smixing > 0
8
Spontaneity of the Dissolution
Process
Disorder in mixing a solution is very common.
9
Spontaneity of the Dissolution
Process
Solvent-solvent attractions such as hydrogen
bonding in water.
This also requires an absorption of E.
Solvent-solute attractions, solvation,
solvation releases
energy.
If solvation energy is greater than the sum of the
solute-solute and solvent-solvent attractions, the
dissolution is exothermic, ∆Hsolution < 0.
If solvation energy is less than the sum of the
solute-solute and solvent-solvent attractions, the
dissolution is endothermic, ∆Hsolution > 0.
10
Spontaneity of the Dissolution
Process
11
Dissolution of Solids in
Liquids
The energy released (exothermic) when a
mole of formula units of a solid is formed from
its constituent ions (molecules or atoms for
nonionic solids) in the gas phase is called the
crystal lattice energy.
energy
M +
(g) X (g) M X (s) crystal lattice energy
- + -
12
Dissolution of Solids in
Liquids
Dissolution is a competition between:
1. Solute -solute attractions
crystal lattice energy for ionic solids
2. Solvent-solvent attractions
H-bonding for water
Solute-solvent attractions
Solvation or hydration energy
13
Dissolution of Solids in
Liquids
Solvation is directed by the water to ion
attractions as shown in these electrostatic
potentials.
14
Dissolution of Solids in
Liquids
In an exothermic dissolution, energy is
released when solute particles are dissolved.
This energy is called the energy of solvation or the
hydration energy (if solvent is water).
Let’s look at the dissolution of CaCl2.
15
Dissolution of Solids in
Liquids [ Ca(OH 2 ) 6 ] + 2Cl ( H 2 O ) x
CaCl 2 (s) →
H O
2 2+ -
where x is approximately 7 or 8
OH2 2+ O
OH2 H H
H2O
H H
Ca O
O Cl-
H2O H
OH2 H
H H
OH2 O
16
Dissolution of Solids in
Liquids
The energy absorbed when one mole of
formula units becomes hydrated is the molar
energy of hydration.
hydration
M n + (g) + x H 2 O → [ M(OH 2 ) x ]
n+
+ hydration E for M n +
X y- ( g ) + n H 2 O → [ X(H 2 O) n ]
y−
+ hydration E for X y-
17
Dissolution of Solids in
Liquids
Hydration energy increases with increasing charge
density
Ion Radius(Å) Charge/radius Heat of Hydration
K+ 1.33 0.75 -351 kJ/mol
Ca2+ 0.99 2.02 -1650 kJ/mol
Cu2+ 0.72 2.78 -2160 kJ/mol
Al3+ 0.50 6.00 -4750 kJ/mol
18
Dissolution of Liquids in
Liquids (Miscibility)
Most polar liquids are miscible in other polar
liquids.
In general, liquids obey the “like dissolves like”
rule.
Polar molecules are soluble in polar solvents.
Nonpolar molecules are soluble in nonpolar solvents.
For example, methanol, CH3OH, is very soluble
in water
19
Dissolution of Liquids in
Liquids (Miscibility)
Nonpolar molecules essentially “slide” in
between each other.
For example, carbon tetrachloride and benzene
are very miscible.
H
Cl H C H
C C
Cl C Cl
C C
Cl H C H
20
Dissolution of Gases in
Liquids
Polar gases are more soluble in water than
nonpolar gases.
This is the “like dissolves like” rule in action.
Polar gases can hydrogen bond with water
Some polar gases enhance their solubility by
reacting with water.
HBr + H 2 O → H 3O +
( aq ) + Br -
( aq )
strong acid
SO 2 + H 2 O → H 2SO 3( aq )
H 2SO 3( aq )
←→
H O + ( aq ) + HSO - ( aq )
H 2O
3 3
weak acid 21
Dissolution of Gases in
Liquids
A few nonpolar gases are soluble in water because
they react with water.
CO2 ( g )
+ H 2O → H 2CO3 ←
→
H 2O
+ −
H 3O ( aq ) + HCO3 ( aq )
very weak acid
Because gases have very weak solute-solute
interactions, gases dissolve in liquids in exothermic
processes.
22
Rates of Dissolution and
Saturation
Finely divided solids dissolve more rapidly than large crystals.
Compare the dissolution of granulated sugar and
sugar cubes in cold water.
The reason is simple, look at a single cube of NaCl.
Breaks
many smaller crystals
up
NaCl
The enormous increase in surface area helps the solid to
dissolve faster.
23
Rates of Dissolution and
Saturation
Saturated solutions have established an
24
Rates of Dissolution and
Saturation
Symbolically this equilibrium is written as:
→ +
MX ( s ) ← M ( aq ) + X ( aq )
-
25
Rates of Dissolution and
Saturation
Supersaturated solutions have higher-than-
saturated concentrations of dissolved solutes.
26
Effect of Temperature on
Solubility
According to LeChatelier’s Principle when stress is
applied to a system at equilibrium, the system
responds in a way that best relieves the stress.
Since saturated solutions are at equilibrium, LeChatelier’s
principle applies to them.
Possible stresses to chemical systems include:
1. Heating or cooling the system.
2. Changing the pressure of the system.
3. Changing the concentrations of reactants or products.
27
Effect of Temperature on
What will be the effect of heating or cooling the
Solubility
28
Effect of Temperature on
Solubility
For ionic solids that dissolve endothermically
dissolution is enhanced by heating.
heating
For ionic solids that dissolve exothermically
dissolution is enhanced by cooling.
cooling
Be sure you understand these trends.
29
Effect of Pressure on
Solubility
Pressure changes have little or no effect on
solubility of liquids and solids in liquids.
Liquids and solids are not compressible.
Pressure changes have large effects on the
solubility of gases in liquids.
Sudden pressure change is why carbonated
drinks fizz when opened.
It is also the cause of several scuba diving related
problems including the “bends”.
30
Effect of Pressure on
Solubility
The effect of pressure on the solubility of gases in
liquids is described by Henry’s Law.
gas ==kkMM
Pgas gasgas
where M
where M gas = molar concentration of gas
gas = molar concentration of gas
31
Molality and Mole Fraction
32
Molality and Mole Fraction
1. Molarity
moles of solute
M =
Liters of solution
We must introduce two new concentration
units in this chapter.
33
Molality and Mole Fraction
34
Molality and Mole Fraction
Example 14-1: Calculate the molarity and the
molality of an aqueous solution that is 10.0%
glucose, C6H12O6. The density of the solution is 1.04
g/mL. 10.0% glucose solution has several medical
uses. 1 mol C6H12O6 = 180 g
35
Molality and Mole Fraction
Example 14-1: Calculate the molality and the
molarity of an aqueous solution that is 10.0%
glucose, C6H12O6. The density of the solution is 1.04
g/mL. 10.0% glucose solution has several medical
uses. 1 mol C6H12O6 = 180 g
You calculate the molarity!
? mol C 6 H12 O 6 10.0 g C 6 H12 O 6 1.04 g sol' n
= × ×
L H 2O 100.0 g sol' n mL sol' n
1000 mL 1 mol C 6 H12 O 6
× = 0.578 M C 6 H12 O 6
1L 180 g C 6 H12 O 6
36
Molality and Mole Fraction
Example 14-2: Calculate the molality of a solution
that contains 7.25 g of benzoic acid C6H5COOH, in
2.00 x 102 mL of benzene, C6H6. The density of
benzene is 0.879 g/mL. 1 mol C6H5COOH = 122 g
You do it!
? mol C 6 H 5COOH 7.25g C 6 H 5COOH 1 mL C 6 H 6
= ×
kg C 6 H 6 200.0 mL C 6 H 6 0.879 g C 6 H 6
1000 g C 6 H 6 1 mol C 6 H 5COOH
× = 0.338 m C 6 H 5COOH
1 kg C 6 H 6 122 g C 6 H 5COOH
37
Molality and Mole Fraction
Mole fraction is the number of moles of one
component divided by the moles of all the
components of the solution
Mole fraction is literally a fraction using moles of one
component as the numerator and moles of all the
components as the denominator.
In a two component solution, the mole fraction of
one component, A, has the symbol XA.
number of moles of A
XA =
number of moles of A + number of moles of B
38
Molality and Mole Fraction
The mole fraction of component B - XB
number of moles of B
XB =
number of moles of A + number of moles of B
Note that X A + X B = 1
The sum of all the mole fractions must equal 1.00.
39
Molality and Mole Fraction
Example 14-3: What are the mole fractions of
glucose and water in a 10.0% glucose
solution (Example 14-1)?
You do it!
In 1.00 ×10 g of this solution there are
2
41
Molality and Mole Fraction
Now we can calculate the mole fractions.
5.00 mol H 2 O
X H 2O =
5.00 mol H 2 O + 0.0556 mol C 6 H 12 O 6
= 0.989
0.0556 mol C 6 H 12 O 6
X C 6 H12 O 6 =
5.00 mol H 2 O + 0.0556 mol C 6 H 12 O 6
= 0.011
. = 0.989 + 0.011
100
42
Colligative Properties of
Solutions
Colligative properties are properties of
solutions that depend solely on the number of
particles dissolved in the solution.
Colligative properties do not depend on the kinds
of particles dissolved.
Colligative properties are a physical property
of solutions.
43
Colligative Properties of
Solutions
There are four common types of colligative
properties:
1. Vapor pressure lowering
2. Freezing point depression
3. Boiling point elevation
4. Osmotic pressure
Vapor pressure lowering is the key to all
four of the colligative properties.
44
Lowering of Vapor Pressure
and Raoult’s Law
Addition of a nonvolatile solute to a solution
lowers the vapor pressure of the solution.
The effect is simply due to fewer solvent
molecules at the solution’s surface.
The solute molecules occupy some of the spaces
that would normally be occupied by solvent.
Raoult’s Law models this effect in ideal
solutions.
45
Lowering of Vapor Pressure
and Raoult’s Law
Derivation of Raoult’s Law.
0
Psolvent = X solvent Psolvent
where Psolvent = vapor pressure of solvent in solution
0
Psolvent = vapor pressure of pure solvent
X solvent = mole fraction of solvent in solution
46
Lowering of Vapor Pressure
and Raoult’s Law
Lowering of vapor pressure, ∆Psolvent, is defined as:
∆Psolvent = P 0
solvent − Psolvent
=P 0
solvent - ( X solvent )(P 0
solvent )
= (1 − X solvent )P 0
solvent
47
Lowering of Vapor Pressure
and Raoult’s Law
Remember that the sum of the mole fractions
must equal 1.
Thus Xsolvent + Xsolute = 1, which we can
substitute into our expression.
X solute = 1 - X solvent
∆Psolvent = X solute P 0
solvent
49
Fractional Distillation
Distillation is a technique used to separate solutions
that have two or more volatile components with
differing boiling points.
A simple distillation has a single distilling column.
Simple distillations give reasonable separations.
A fractional distillation gives increased separations
because of the increased surface area.
Commonly, glass beads or steel wool are inserted into the
distilling column.
50
Boiling Point Elevation
Addition of a nonvolatile solute to a solution
raises the boiling point of the solution above
that of the pure solvent.
This effect is because the solution’s vapor
pressure is lowered as described by Raoult’s law.
The solution’s temperature must be raised to
make the solution’s vapor pressure equal to the
atmospheric pressure.
The amount that the temperature is elevated
is determined by the number of moles of
solute dissolved in the solution.
51
Boiling Point Elevation
52
Boiling Point Elevation
∆Tb = K b m
∆Tb = (0.512 0 C/m)(2.50m)
∆Tb = 1.280 C
Boiling Point of the solution = 100.0 0 C + 1.280 C = 101.280 C
53
Freezing Point Depression
Addition of a nonvolatile solute to a solution
lowers the freezing point of the solution
relative to the pure solvent.
See table 14-2 for a compilation of boiling
point and freezing point elevation constants.
54
Freezing Point Depression
55
Freezing Point Depression
Notice the similarity of the two relationships
for freezing point depression and boiling point
elevation.
∆Tf = K f m vs.∆Tb = K b m
Fundamentally, freezing point depression and boiling
point elevation are the same phenomenon.
The only differences are the size of the effect which is
reflected in the sizes of the constants, Kf & Kb.
This is easily seen on a phase diagram for a solution.
56
Freezing Point Depression
57
Freezing Point Depression
∆Tf = 4.650 C
Freezing Point of solution = 0.00 0 C - 4.650 C = - 4.650 C
58
Freezing Point Depression
59
Freezing Point Depression
1. Calculate molality!
? mol C 6 H 5 COOH 8.50 g C 6 H 5 COOH
= ×
kg C 6 H 6 0.0750 kg C 6 H 6
1 mol C 6 H 5 COOH
=0.929m
122 g C 6 H 5 COOH
2. Calculate the depression for this solution.
∆Tf = K f m
∆Tf =(5.12 0 C/m)(0.929m) = 4.76 0 C
F.P. = 5.480 C - 4.76 0 C = 0.72 0 C
60
Determination of Molecular
Weight by Freezing Point
Depression
The size of the freezing point depression
depends on two things:
The size of the Kf for a given solvent, which are
well known.
And the molal concentration of the solution which
depends on the number of moles of solute and
the kg of solvent.
If Kf and kg of solvent are known, as is
often the case in an experiment, then we
can determine # of moles of solute and use
it to determine the molecular weight. 61
Determination of Molecular
Weight by Freezing Point
Depression
Example 14-7: A 37.0 g sample of a new
covalent compound, a nonelectrolyte, was
dissolved in 2.00 x 102 g of water. The
resulting solution froze at -5.58oC. What is
the molecular weight of the compound?
62
Determination of Molecular
Weight by Freezing Point
Depression
∆T = K m thus the
f f
∆Tf 5.580 C
m= = 0
= 3.00m
K f 1.86 C
In this problem there are
200 mL = 0.200 kg of water.
? mol compound in 0.200 kg H 2 O = 3.00 m × 0.200 kg
= 0.600 mol compound
37 g
Thus the molar mass is = 61.7 g/mol
0.600 mol
63
Colligative Properties and
Dissociation of Electrolytes
Electrolytes have larger effects on boiling point
elevation and freezing point depression than
nonelectrolytes.
This is because the number of particles released in
solution is greater for electrolytes
One mole of sugar dissolves in water to produce
one mole of aqueous sugar molecules.
One mole of NaCl dissolves in water to produce
two moles of aqueous ions:
1 mole of Na+ and 1 mole of Cl- ions
64
Colligative Properties and
Dissociation of Electrolytes
Remember colligative properties depend on the
number of dissolved particles.
Since NaCl has twice the number of particles we can
expect twice the effect for NaCl than for sugar.
The table of observed freezing point
depressions in the lecture outline shows this
effect.
65
Colligative Properties and
Dissociation of Electrolytes
Ion pairing or association of ions prevents the
effect from being exactly equal to the number
of dissociated ions
66
Colligative Properties and
Dissociation of Electrolytes
The van’t Hoff factor, symbol i, is used to
introduce this effect into the calculations.
i is a measure of the extent of ionization or
dissociation of the electrolyte in the solution.
∆Tf ( actual )
i=
∆Tf ( if nonelectrolyte)
67
Colligative Properties and
Dissociation of Electrolytes
i has an ideal value of 2 for 1:1 electrolytes like NaCl,
KI, LiBr, etc.
Na + Cl - H
2O
→ Na (+aq ) + Cl (-aq ) 2 ions
formula unit
i has an ideal value of 3 for 2:1 electrolytes like
K2SO4, CaCl2, SrI2, etc.
Ca 2+ Cl -2 H
2O
→ Ca (2aq+ ) + 2 Cl (-aq ) 3 ions
formula unit
68
Colligative Properties and
Dissociation of Electrolytes
Example 14-8: The freezing point of 0.0100 m NaCl
solution is -0.0360oC. Calculate the van’t Hoff factor
and apparent percent dissociation of NaCl in this
aqueous solution.
meffective = total number of moles of solute particles/kg
solvent
First let’s calculate the i factor.
∆ Tf ( actual ) K f meffective meffective
i= = =
∆Tf ( if nonelectrolyte ) K f mstated mstated
69
Colligative Properties and
Dissociation of Electrolytes
∆Tf ( actual ) K f meffective meffective
i= = =
∆Tf ( if nonelectrolyte ) K f mstated mstated
∆Tf ( actual ) 0.0360 0 C
∆Tf ( actual ) = K f meffective ∴ meffective = = 0
Kf 1.86 C m
meffective 0.0194 m
meffective = 0.0194 m ∴i = = = 194
.
mstated 0.0100 m
70
Colligative Properties and
Dissociation of Electrolytes
Next, we will calculate the apparent percent
dissociation.
Let x = mNaCl that is apparently dissociated.
71
Colligative Properties and
Dissociation of Electrolytes
NaCl → Na + Cl
H 2O + -
(0.0100 − x)m xm xm
72
Colligative Properties and
Dissociation of Electrolytes
NaCl
H 2O
→ Na + Cl
+ -
(0.0100 − x)m xm xm
meffective = [ 0.0100 − x + x + x ] m
= [ 0.0100 + x ] m = 0.0194 m
x = 0.0094 m
73
Colligative Properties and
Dissociation of Electrolytes
mapp diss
apparent % dissociation = ×100%
mstated
0.0094m
= ×100%
0.0100m
= 94%
74
Colligative Properties and
Dissociation of Electrolytes
Example 14-9: A 0.0500 m acetic acid
solution freezes at -0.0948oC. Calculate the
percent ionization of CH3COOH in this
solution.
You do it!
75
Colligative Properties and
Dissociation of Electrolytes
→H + + CH COO -
CH 3COOH ← 3
( 0.0500 − x )m x m xm
meff = [( 0.0500 − x ) + x + x ] m = ( 0.0500 + x ) m
∆Tf = K f ×meff
∆Tf 0.09480 C
meff = = 0
= 0.0510 m
Kf 1.86 C m
meff = ( 0.0500 + x ) m = 0.0510 m
x = 0.0010 m
mionized 0.0010 m
% ionized = ×100% = ×100%
moriginal 0.0500 m
= 2.0% ionized and 98.0% unionized
76
Osmotic Pressure
Osmosis is the net flow of a solvent
between two solutions separated by a
semipermeable membrane.
The solvent passes from the lower concentration
solution into the higher concentration solution.
Examples of semipermeable membranes
include:
1. cellophane and saran wrap
2. skin
3. cell membranes
77
Osmotic Pressure
semipermeable membrane
H2O H2O
H2O H2O
78
Osmotic Pressure
79
Osmotic Pressure
Osmosis is a rate controlled phenomenon.
The solvent is passing from the dilute solution into
the concentrated solution at a faster rate than in
opposite direction, i.e. establishing an equilibrium.
The osmotic pressure is the pressure exerted
by a column of the solvent in an osmosis
experiment.
π = MRT
where: π = osmotic pressure in atm
M = molar concentration of solution
L atm
R = 0.0821
mol K
T = absolute temperature
80
Osmotic Pressure
π = mRT
for dilute aqueous solutions only
81
Osmotic Pressure
Osmotic pressures can be very large.
For example, a 1 M sugar solution has an osmotic
pressure of 22.4 atm or 330 p.s.i.
Since this is a large effect, the osmotic
pressure measurements can be used to
determine the molar masses of very large
molecules such as:
1. Polymers
2. Biomolecules like
proteins
ribonucleotides
82
Osmotic Pressure
83
Osmotic Pressure
π
π = MRT ∴ M =
RT
1 atm
? atm = 2.80 torr × = 0.00368 atm = π
760 torr
0.00368 atm −4
M = = 150
. × 10 M
( 0.0821 mol K ) ( 298 K)
L atm
84
Osmotic Pressure
π
π = MRT ∴ M =
RT
1 atm
? atm = 2.80 torr × = 0.00368 atm = π
760 torr
0.00368 atm −4
M = = 150
. × 10 M
( 0.0821 mol K)(
L atm
298 K)
?g 1.00 g 1L 4g
= × −4
= 6.67 × 10 mol
mol 0.100 L 150 . × 10 M
typical of small proteins
85
Osmotic Pressure
Water Purification by Reverse Osmosis
If we apply enough external pressure to an
osmotic system to overcome the osmotic
pressure, the semipermeable membrane
becomes an efficient filter for salt and other
dissolved solutes.
Ft. Myers, FL gets it drinking water from the Gulf
of Mexico using reverse osmosis.
US Navy submarines do as well.
Dialysis is another example of this phenomenon.
86
Colloids
Colloids are an intermediate type of mixture that
has a particle size between those of true solutions
and suspensions.
The particles do not settle out of the solution but they
make the solution cloudy or opaque.
Examples of colloids include:
1. Fog
2. Smoke
3. Paint
4. Milk
5. Mayonnaise
6. Shaving cream
7. Clouds
87
The Tyndall Effect
88
The Adsorption Phenomenon
Colloids have very large surface areas.
They interact strongly with substances near their
surfaces.
One of the reasons why rivers can carry so
much suspended silt in the water.
[ ] [
2 × Fe 2+ + 3 Cl - + ( y + 3) H 2 O → Fe 2 O 3 ⋅ y H 2 O + 6 H + + Cl - ]
A colloidal particle contains many Fe 2 O 3 ⋅ y H 2 O units with Fe3+ ions
bound to its surface. The + charged particles repel each other and
keep the colloid from precipitating.
89
Hydrophilic and Hydrophobic
Colloids
Hydrophilic colloids like water and are water soluble.
Examples include many biological proteins like blood plasma.
Hydrophobic colloids dislike water and are water insoluble.
Hydrophobic colloids require emulsifying agents to stabilize in
water.
Homogenized milk is a hydrophobic colloid.
Milk is an emulsion of butterfat and protein particles dispersed in
water
The protein casein is the emulsifying agent.
90
Hydrophilic and Hydrophobic
Colloids
Mayonnaise is also a hydrophobic colloid.
Mayonnaise is vegetable oil and eggs in a colloidal
suspension with water.
The protein lecithin from egg yolk is the emulsifying
agent.
Soaps and detergents are excellent emulsifying
agents.
Soaps are the Na or K salts of long chain fatty acids.
Sodium stearate is an example of a typical soap.
91
Hydrophilic and Hydrophobic
Colloids
Sodium stearate
O
nonpolar tail CH2 C
hydrophobic portion O-Na+
CH2 CH2
H3C CH2 CH2 CH2
CH2 CH2 CH2 CH2
CH2 CH2 CH2 CH2
polar (ionic) head
CH2 CH2 hydrophilic portion
92
Hydrophilic and Hydrophobic
Colloids
93
Hydrophilic and Hydrophobic
Colloids
So called “hard water” contains Fe3+, Ca2+,
and/or Mg2+ ions
These ions come primarily from minerals that are
dissolved in the water.
These metal ions react with soap anions and
precipitate forming bathtub scum and ring
around the collar.
2+
Ca + soap anion → Ca(soap anion)2(s)
insoluble scum
94
Hydrophilic and Hydrophobic
Colloids
Synthetic detergents were designed as soap
substitutes that do not precipitate in hard
water.
Detergents are good emulsifying agents.
Chemically, we can replace COO- on soaps with
sulfonate or sulfate groups
95
Hydrophilic and Hydrophobic
Colloids
Linear alkylbenzenesulfonates are good
detergents.
CH2 CH2 CH2 CH2 CH2 CH2
CH3 CH2 CH2 CH2 CH2 CH2 O
S
O-Na+
O
96
Synthesis Question
The world’s record for altitude in flying gliders
was 60,000 feet for many years. It was set
by a pilot in Texas who flew into an updraft in
front of an approaching storm. The pilot had
to fly out of the updraft and head home not
because he was out of air, there was still
plenty in the bottle of compressed air on
board, but because he did not have a
pressurized suit on. What would have
happened to this pilot’s blood if he had
continued to fly higher?
97
Synthesis Question
98
Group Question
99
End of Chapter 14
100