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  • Alkylation

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    Đinh Hoàng Thanh
    255 просмотров14 страниц
    Alkylation is a process that combines light olefins like propylene and butylene with isobutene in the presence of a strong acid catalyst like sulfuric acid or hydrofluoric acid. Alkylation produces alkylate, the most desirable gasoline blendstock due to its high octane rating and favorable emissions profile. Feedstocks include olefins from dehydrogenation or FCC and isobutane from C4 fractions. The reaction proceeds via an ionization mechanism to form carbocations, which are then alkylated. Alkylation can use sulfuric acid or hydrofluoric acid catalysts in distinct unit processes to produce high octane alkylate gasoline. Future developments may focus on new catalyst systems like heterogeneous

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    Alkylation is a process that combines light olefins like propylene and butylene with isobutene in the presence of a strong acid catalyst like sulfuric acid or hydrofluoric acid. Alkylation produces alkylate, the most desirable gasoline blendstock due to its high octane rating and favorable emissions profile. Feedstocks include olefins from dehydrogenation or FCC and isobutane from C4 fractions. The reaction proceeds via an ionization mechanism to form carbocations, which are then alkylated. Alkylation can use sulfuric acid or hydrofluoric acid catalysts in distinct unit processes to produce high octane alkylate gasoline. Future developments may focus on new catalyst systems like heterogeneous

    Авторское право:

    Attribution Non-Commercial (BY-NC)
    Скачайте в формате PPTX, PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    255 просмотров14 страниц

    Alkylation

    Загружено:

    Đinh Hoàng Thanh
    Alkylation is a process that combines light olefins like propylene and butylene with isobutene in the presence of a strong acid catalyst like sulfuric acid or hydrofluoric acid. Alkylation produces alkylate, the most desirable gasoline blendstock due to its high octane rating and favorable emissions profile. Feedstocks include olefins from dehydrogenation or FCC and isobutane from C4 fractions. The reaction proceeds via an ionization mechanism to form carbocations, which are then alkylated. Alkylation can use sulfuric acid or hydrofluoric acid catalysts in distinct unit processes to produce high octane alkylate gasoline. Future developments may focus on new catalyst systems like heterogeneous

    Авторское право:

    Attribution Non-Commercial (BY-NC)
    Скачайте в формате PPTX, PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    из 14

    Alkylation

    Nhm 5: Nguyn Duy Quyn Nguyn Trng Thi inh Hong Thanh Nguyn L Ti Thu Lng Th Huyn Trang

    Overview
    1. Whats alkylation?
    2. Purpose & significane 3. Feedstock & catalyst

    4. Reaction Mechanism
    5. Description process flow 6. Alkylation in the future

    7. Summary

    1. Whats Alkylation
    Alkylation is a conversion processes that combine light olefins

    (primarily propylene and butylene) with isobutene in the presence of a strong acid catalyst, either sulfuric acid or hydrofluoric acid

    Alkylation reaction
    Sulfuric acid catalyst

    Purpose & significane


    Alkylate is the most desirable gasoline blend stock

    No Olefins No Aromatics Low Sulfur Low RVP (Reid Vapour Pressure) High Octane Good Distillation Characteristics

    Besides the alkylation of benzene with light olefins was also obtained alkylbenzenes with high octane

    Feedstock
    Olefin: propylene, butylene.
    Butylene: from dehydrogenation butane

    Iso-butane: from C4s fraction of FCC

    Catalyst

    H2SO4
    HF

    Reaction Mechanism
    Ionization mechanism to intermediate stage

    establish carbocation of proton acid catalyst

    Description process flow


    Depending on the acid used as catalyst
    SAAU (Sulphuric Acid Alkylation Unit) HFAU (Hydrofluoric Acid Alkylation Unit)

    SAAU (Sulphuric Acid Alkylation Unit)


    Feedstock Olefin, isobutane Reactor
    Caustic scrubber

    Settler

    Deisobutanizer

    Alkylate Recycle acid

    Fresh acid

    Reject acid

    HFAU (Hydrofluoric Acid Alkylation Unit)

    Alkylation in the future


    What can chemicals advance for the alkylation process?
    Catalyst Reactor Technology conditions

    Catalyst
    Homogeneous catalyst Heterogeneous catalyst

    Alkylation in the future


    Homogeneous catalyst Heterogeneous catalyst

    The capital is very high


    Separate products: very difficult

    Reduce the capital for build the factory

    Separate products: very easy

    Alkylation in the future


    Purpose of the Alkylation process???

    To produce gasoline
    Iso octane

    To petrochemical
    LAB, LAS PP

    Thank you for your attention!

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