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EQUILIBRIOS DE SOLUBIBLIDAD
Reacciones de precipitacin
Los iones solubles se pueden combinar para formar un compuesto insoluble. Se produce la precipitacin.
Ag+(aq) + Cl-(aq) AgCl(s)
Iones espectadores
Ag+(aq) + NO3-(aq) + Na+(aq) + I-(aq)
Reglas de solubilidad
Compuestos solubles: Todos los de los metales alcalinos y el ion amonio. Nitratos, percloratos y acetatos
NO3ClO4CH3CO2Li+, Na+, K+, Rb+, Cs+ NH4+
Reglas de solubilidad
Compuestos en su mayora solubles:
Cloruros, bromuros e ioduros Cl-, Br-, I Excepto los de Pb2+, Ag+ y Hg22+.
Sulfatos SO42 Excepto los de Sr2+, Ba2+, Pb2+ y Hg22+. Ca(SO4) es un poco soluble.
Reglas de solubilidad
Compuestos insolubles:
Hidrxidos y sulfuros HO-, S2 Excepto los metales alcalinos y los iones amonio. Los sulfuros de los alcalinotrreos son solubles. Los hidrxidos de Sr2+ y Ca2+ son un poco solubles.
Carbonatos y fosfatos
CO32-, PO43-
12.4
Fractional crystallization is the separation of a mixture of substances into pure components on the basis of their differing solubilities.
Suppose you have 90 g KNO3 contaminated with 10 g NaCl. Fractional crystallization: 1. 2. 3. 4. Dissolve sample in 100 mL of water at 600C Cool solution to 00C All NaCl will stay in solution (s = 34.2g/100g) 78 g of PURE KNO3 will precipitate (s = 12 g/100g). 90 g 12 g = 78 g 12.4
12.4
Solubility Equilibria
AgCl (s) Ksp = [Ag+][Cl-] MgF2 (s) Ag2CO3 (s) Ca3(PO4)2 (s) Ag+ (aq) + Cl- (aq)
Ksp is the solubility product constant Mg2+ (aq) + 2F- (aq) 2Ag+ (aq) + CO32- (aq) 3Ca2+ (aq) + 2PO43- (aq) Ksp = [Mg2+][F-]2 Ksp = [Ag+]2[CO32-] Ksp = [Ca2+]3[PO33-]2
Dissolution of an ionic solid in aqueous solution: Q < Ksp Q = Ksp Q > Ksp Unsaturated solution Saturated solution Supersaturated solution Precipitate will form
No precipitate
16.6
16.6
Molar solubility (mol/L) is the number of moles of solute dissolved in 1 L of a saturated solution. Solubility (g/L) is the number of grams of solute dissolved in 1 L of a saturated solution.
16.6
Ksp = s2
s = Ksp s = 1.3 x 10-5
Solubility of AgCl =
16.6
16.6
If 2.00 mL of 0.200 M NaOH are added to 1.00 L of 0.100 M CaCl2, will a precipitate form? The ions present in solution are Na+, OH-, Ca2+, Cl-. Only possible precipitate is Ca(OH)2 (solubility rules). Is Q > Ksp for Ca(OH)2? [Ca2+]0 = 0.100 M Q = [Ca2+]0[OH-]0 [OH-]0 = 4.0 x 10-4 M
2 = 0.10 x (4.0 x 10-4)2 = 1.6 x 10-8
Q < Ksp
16.6
What is the molar solubility of AgBr in (a) pure water and (b) 0.0010 M NaBr?
AgBr (s)
NaBr (s)
16.8
pH and Solubility
The presence of a common ion decreases the solubility. Insoluble bases dissolve in acidic solutions Insoluble acids dissolve in basic solutions
Mg(OH)2 (s)
Ksp = [Mg2+][OH-]2 = 1.2 x 10-11 Ksp = (s)(2s)2 = 4s3 4s3 = 1.2 x 10-11 s = 1.4 x 10-4 M [OH-] = 2s = 2.8 x 10-4 M pOH = 3.55 pH = 10.45
Lower [OH-]
OH- (aq) + H+ (aq) H2O (l)
Increase solubility of Mg(OH)2 At pH greater than 10.45 Raise [OH-] Decrease solubility of Mg(OH)2
16.9
The formation constant or stability constant (Kf) is the equilibrium constant for the complex ion formation. [CoCl4 2] [Co2+][Cl-]4
Kf =
Co(H2O)6
2+
CoCl24
Kf
stability of complex
16.10
16.10
16.11
16.11
lithium
sodium
potassium
copper
16.11