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This document summarizes solubility rules and concepts related to saturated solutions and precipitation. It states that alkali metal salts, ammonium salts, and salts containing nitrate ions are very soluble. Salts of halide ions are also usually soluble, except for those containing silver and lead. When a salt dissolves in water, it dissociates into ions until the solution reaches equilibrium and the rates of dissolution and precipitation are equal, creating a saturated solution. The solubility product constant, Ksp, describes the equilibrium between an ionic solid and its saturated solution. The Ksp value can be used to determine if precipitation will occur for a given salt in solution.
This document summarizes solubility rules and concepts related to saturated solutions and precipitation. It states that alkali metal salts, ammonium salts, and salts containing nitrate ions are very soluble. Salts of halide ions are also usually soluble, except for those containing silver and lead. When a salt dissolves in water, it dissociates into ions until the solution reaches equilibrium and the rates of dissolution and precipitation are equal, creating a saturated solution. The solubility product constant, Ksp, describes the equilibrium between an ionic solid and its saturated solution. The Ksp value can be used to determine if precipitation will occur for a given salt in solution.
This document summarizes solubility rules and concepts related to saturated solutions and precipitation. It states that alkali metal salts, ammonium salts, and salts containing nitrate ions are very soluble. Salts of halide ions are also usually soluble, except for those containing silver and lead. When a salt dissolves in water, it dissociates into ions until the solution reaches equilibrium and the rates of dissolution and precipitation are equal, creating a saturated solution. The solubility product constant, Ksp, describes the equilibrium between an ionic solid and its saturated solution. The Ksp value can be used to determine if precipitation will occur for a given salt in solution.
water Alkali Metal salts are very soluble in water. Ammonium salts are very soluble in water. Salts containing the nitrate ion, NO 3 - , are very soluble in water. Most salts of Cl - , Br - and I - are very soluble in water - exceptions are salts containing Ag +
and Pb 2+ . Dissolving a salt... At first, the only process occurring is the dissolving of the salt - the dissociation of the salt into its ions.
However, soon the ions floating in the water begin to collide with the salt crystal and are pulled back in to the salt. (precipitation)
Eventually the rate of dissociation is equal to the rate of precipitation. The solution is now saturated. It has reached equilibrium. There is no change in amount of solid precipitate at the bottom of the beaker. Concentration of the solution is constant. The rate at which the salt is dissolving into solution equals the rate of precipitation.
Saturated Solution Example: BaSO 4, in water When barium sulfate dissolves, it dissociates into ions. When the solution is saturated, the following equilibrium exists:
BaSO 4 (s) Ba 2+ (aq)
+ SO 4 2- (aq)
Since this is an equilibrium, we can write an equilibrium expression for the reaction:
K = [Ba 2+ ][SO 4 2- ]
Since K is always calculated by just multiplying concentrations, it is called a solubility product constant, Ksp Example For each salt below, write a balanced equation showing its dissociation in water. Then write the Ksp expression for the salt.
Values Note: These are experimentally determined, and may be slightly different on a different Ksp table. Solubility vs Ksp Solubility Ksp Quantity of solute that dissolves to form a saturated solution g/L or mol/L Changes with changes of concentration Equilibrium constant for equilibrium between an ionic solid and its saturated solution Unitless One value for a given solute at any specific temperature Solubility and Ksp Generally, it is fair to say that salts with very small solubility product constants (Ksp) are only sparingly soluble in water. When comparing the solubilities of two salts, however, you can sometimes simply compare the relative sizes of their Ksp values. This works only if the salts have the same formula type!
Example CuI has Ksp = 5.0 x 10 -12 and CaSO 4
has Ksp = 6.1 x 10 -5 . Which is more soluble in water?
Calcium sulfate is more soluble.
But be careful... Salt Ksp Solubility (mol/L) CuS 8.5 x 10 -45 9.2 x 10 -23 Ag 2 S 1.6 x 10 -49 3.4 x 10 -17 Bi 2 S 3 1.1 x 10 -73 1.0 x 10 -15 Example A saturated solution of silver chromate, Ag 2 CrO 4 , has [Ag + ] = 1.3 x 10 -4 M. What is the Ksp for Ag 2 CrO 4 ? Example The Ksp of NiCO 3 is 1.4 x 10 -7 at 25C. Calculate its molar solubility. What mass of NiCO 3 is needed to prepare 500 mL of saturated solution?
Calculate the pH of a saturated solution of silver hydroxide, AgOH. Ksp = 2.0 x 10 -8
Example The Common Ion Effect on Solubility The solubility of MgF 2 in pure water is 2.6 x 10 -4 mol/L. What happens to the solubility if we dissolve the MgF 2 in a solution of NaF, instead of pure water?
The Common Ion Effect on Solubility The presence of a common ion in a solution will lower the solubility of a salt.
LeChateliers Principle:
The addition of the common ion will shift the solubility equilibrium backwards. This means that there is more solid salt in the solution and therefore the solubility is lower!
Example Calculate the solubility of MgF 2 (K sp = 7.4 x 10 -11 ) in a solution of 0.080 M NaF. Criteria for Precipitation or Dissolution Solubility equilibria can be achieved starting from either side When precipitating from the ions, one can calculate for Q (ion product) at any moment in precipitation process If Q > Ksp, precipitation occurs until Q=Ksp If Q = Ksp, equilibrium (saturated solution) If Q < Ksp, solid dissolves until Q = Ksp Example Will a precipitate form if 10.0 mL of 0.010 M AgNO 3 and 10.0 mL of 0.00010 M NaCl are mixed? Assume final volume of solution is 20.0 mL. Ksp AgCl = 1.7 x 10 -10
Example Assume that 0.10 M NaF solution is added slowly, with stirring, to a solution that contains 0.10 M Cr(NO 3 ) 3 and 0.10 M Ca(NO 3 ) 2 . Which salt precipitates first? Ksp, CaF 2 = 5.3 x 10 -9
Ksp, CrF 3 = 6.6 x 10 -11
Example The solubility product for gadolinium hydroxide, Gd(OH) 3 is 1.8 x 10 -23 . If a solution is 0.010 M in Gd 3+ ion and the pH of the solution is slowly increased, at what pH will Gd(OH) 3 begin to precipitate? Solubility and pH Solubility of any substance whose anion is basic will be affected by pH Example: Mg(OH) 2(s) Mg 2+ (aq) + 2OH - (aq)
In acidic buffers, S increases Rule: The solubility of slightly soluble salts containing basic anions, increases as [H + ] increases.