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n
R
z
NR
3
+
OH
-
+ A
n-
(R
z
NR
3
)nA +
n
OH
-
Ion Exchanger Selectivity
There are 2 factors influence the
selectivity :
The exchanged ions properties
The ion exchanger properties.
Exchanged ions properties:
At room temperature and low
concentration, ion with higher
charge will tightly held by resin.
Ex : Al
3+
> Ca
2+
> Na
+
In the same condition for the same
charge ion :
+1 ion
Lower the size of ion, stronger the resin hold the ion.
Ex : Li
+
< H
+
< Na
+
< NH
4+
< K
+
+2 ion
Resin absorption determinated by the ion size and
dissosiation of salt .
Ex : Cd
2+
< Ba
2+
< Mn
2+
< Mg
2+
= Zn
2+
< Cu
2+
< Co
2+
Exchanged ions properties:
In strong base ion exchanger -1
anionhas the equivalent absorption
selectivity with the +1 cation. (Lower
the size of ion, stronger the resin hold
the ion)
Ex : F
-
< HCO
3-
< Cl
-
< HSO
3-
< OH
-
< Br
-
<
NO
3-
< I
-
In dilute solution -X anion (X>1)
absorbed stronger than the -1 anion.
When the charge of cations to be
exchanged is not same. Ion activity
with the higher charge is higher
when the concentration of higher
charge ion is lower.
Example :
M
+2
in solution and M
+1
in resin will
effectively exchanged at low
concentration
M
+1
in solution and M
+2
in resin will
effectively exchanged at high
concentration.
Ion exchanger properties
Quantitatively, afinity of ion exchanger resin
to the exchanged ions terms as distribution
coefficient (D):
sama yang pelat pada larutan dalam sampel Kuantitas
entu pelat tert pada resin dalam sampel Kuantitas
D
Complexing agent
Complexing agent is anions like Cl
-
, Br
-
and I
-
which
have ligand nature. The complexion is influenced by
pH value.
Many metals could be separated in anion exchanger
column after transformed to anion by complexing
agent.
Metal separation in anion exchanger column carry
out by addition of high concentration acid to
transform metal ion to be complex anion.
Example
Concentrated HCL forms complex anion with most
metal except alkali and earth alkali metal.
Al(III), Ni(II), dan Cr(III) form complex anion with
Cl
-
.
Almost all complex anion of metal absorbed by
quarternar ammonium resin.
Resin Regeneration
Amount of cation and anion to be exchanged
by resin depends on the resin capacity.
When resin absorb amount of ion more than
its capacity, resin is exhausted. It should be
regenerated.
Regeneration of anion exchanger resin :
Acid : HCl, H
2
SO
4
.
Reaction : Rz C + H
+
Rz H + C
+
Regeneration of cation exchanger resin :
Base : NaOH.
Reaction : Rz A + OH
-
Rz OH + A
-
Resin Column
a
.