Density is a broader term. It is used in mathematics (statistics, geometry,
number density),physics(magnetic field density, current density etc.). It is always a ratio. If simply density is mentioned then it is assumed as mass density.
Mass Density Density:-It is defined as the ratio between the mass and volume for a substance. It is a measure of how much mass is contained in a given unit of volume. = m/v. It is a intensive property. i.e. does not depend on amount of matter.
Unit of density: SI unit = kg/m other units :- gm/ml, gm/l = gm/dm
Characteristics Density changes with temperature, pressure etc. Change in density is higher for gases as compared to liquid and solid. Generally more dense material remains at the bottom if mixture is poured in column.
DENSITY MEASUREMENT PYCNOMETRIC DENSITY MEASUREMENT Pycnometer are static device. A pycnometer is a glass beaker of defined volume. It is weighed without sample (M1), then filled with the sample and weighed again (M2). The difference between M1 and M2 (=Mass of the sample) divided by the volume of the beaker is the density of the sample. For good precision, ultimate care must be exercised during the measurements; i.e., the bottle must be cleaned after each measurement, the temperature must be kept constant, and precision balances must be used.
Advantage Disadvantage Application simple method breakable glassware educational: what is density, how to measure density relatively inexpensive instrument long and difficult thermostating production control: where more precision is required special instruments with direct readings in Alcohol%, Sugar% (BRIX) or other density related values available density must be calculated (some balances include this calculation)
large sample volume required
analytical labs: where GLP is not required operator dependent readings, therefore limited accuracy INSTRUMENT USED DENSITY KIT It includes a weighing machin of fixed accuracy ,glass beaker, and holder for beaker BOUYANCY TYPE DENSITOMETER Uses archimedes principle. Archimedes' principle: When a body is fully or partly immersed in a liquid, that body experiences an upward force (the buoyant force) equal to the weight of the displaced liquid. The displaced liquid is that volume of liquid equal to the volume of the body below the water surface. A suspended sinker, with a known mass and volume attached to a ne wire, is totally immersed in the sample liquid. A precision force balance is used to measure the force to support the sinker. Once the mass, volume, and supporting weight of the sinker are known, the density of the liquid can be calculated. Some corrections need to be made for: surface tension on the suspension wire, the cubicle expansion coefcient of the sinker, and the temperature of process. Give accurate results and are used for the calibration of the other liquid density transducers. One advanced version of the buoyancy technique is the magnetic suspension system. The sinker is fully enclosed in a pressure vessel, thus eliminating surface tension errors. Their uses can also be extended to applications such as the specic gravity measurements under low vapor pressures, and density measurements of hazardous uids.
HYDROMETER Main technique of operation : BOUYANCY PRINCIPLE. The hydrometer (aerometer) is a glass body which is dipped into the sample. After a short equilibration time it will swim at a certain level (when the mass of the hydrometer is equal to the buoyancy effect). The higher the density of the sample, the less the aerometer will sink. The level of equlibriation reads the density on the calibrated scale. The volume of xed mass is converted to a linear distance by a sealed bulb-shaped glass tube containing a long stem measurement scale.
FIG. - HYDROMETER Advantage Disadvantage Application simple method breakable glassware quick control of a "rough" density value, mainly for process control quick measurement long and difficult thermostating suitable for the measurement of the same kind of sample (wine, beer) due to the limited measuring range inexpensive instrument very small measuring range (requires several hydrometers to cover a wider range, typically 20 units) special instruments with direct readings in Alcohol%, Sugar% (BRIX) or other density related values available operator dependent readings, therefore limited accuracy U- TUBE DENSITY MEASUREMENT The oscillating U-tube is a technique to determine the density of liquids and gases based on an electronic measurement of the frequency of oscillation, from which the density value is calculated. This measuring principle is based on the Mass-Spring Model. The sample is filled into a container with oscillation capacity. The eigen frequency of this container is influenced by the samples mass. This container with oscillation capacity is a hollow ,U-shaped glass tube (oscillating U-tube) which is electronically excited into undamped oscillation (at the lowest possible amplitude). The two branches of the U- shaped oscillator function as its spring elements. The direction of oscillation is normal to the level of the two branches. The oscillators eigen frequency is only influenced by the part of the sample that is actually involved in the oscillation. The volume involved in the oscillation is limited by the stationary oscillation knots at the bearing points of the oscillator. If the oscillator is at least filled up to its bearing points, the same precisely defined volume always participates in the oscillation, thus the samples mass can be considered proportional to its density.
In the digital density meter, the mechanic oscillation of the U-tube is e.g. electromagnetically transformed into an alternating voltage of the same frequency. The period can be measured with high resolution and stands in simple relation to the density of the sample in the oscillator
A and B are the respective instrument constants of each oscillator. Their values are determined by calibrating with two substances of the precisely known densities 1 and 2. Balanced-Flow Vessel A xed volume vessel is employed for the measurements. While the liquid is owing continuously through the vessel, it is weighed automatically by a sensitive scale a spring balance system or a pneumatic force balance transmitter. As the volume and the weight of the liquid are known, the density or specic gravity can easily be calculated and scaled in respective units. In the design process, extra care must be exercised for the exible end connections.
BALANCE TYPE DENSITOMETER Chain Balanced Float A self-centering, xed-volume, submerged plummet is used for density measurements. The plummet is located entirely under the liquid surface. At balance, the plummet operates without friction and is not affected by surface contamination. Under steady-state conditions, the plummet assumes a stable position. The effective weight of the chain on the plummet varies, depending on the position of the plummet, which in turn is a function of the density of the liquid. The plummet contains a metallic transformer core that transmits changes in the position to be measured by a pickup coil. The voltage differential, a function of plummet displacement, is calibrated as a measure of variations in specic gravity. A resistance thermometer bridge is used for the compensation of temperature effects on density. REFRACTOMETER Principle:- By measuring the refraction (refraction rate) of light, the refractometer can be used as a measuring device various concentrations.
1. ABBE REFRACTOMETER (benchtop) A few drops of the liquid to be measured are put on the prism. The refractive index can be read directly from the built-in scale, looking into the refractometer. Connection to an external water bath allows thermostating required for accurate refractive index measurements. Some models use natural light, the most advanced a light source with defined wave length. Advantage :- Relatively inexpensive instrument.
Disadvantage:- Long and difficult thermostating Operator dependant reading ,therefore less accuracy. Tedius calibration. This measurement technique is not recommended in applications in processes containing suspended solids, high turbidity, entrained air, heavy colors, poor transparency and opacity, or extremely high ow rates
Main Applicaion:- Production control Raw material control 2. HANDHELD REFRACTOMETER A few drops of the liquid to be measured are put on the prism. The refractive index can be read directly from the built-in scale, looking into the refractometer. Some models feature a temperature compensation scale. There are refractometers for specific concentration measurement with dedicated concentration scales (BRIX, salinity). Advantage Simple method inexpensive instrument special instrument with direct reading
Disadvantage:- small measuring range operator dependant reading no measuremnt protocol Application quick control for rough density value sugar control in wine production
3. DIGITAL REFRACTOMETER The latest in refractive index measurement. A high resolution optical sensor measures the total reflection of a light beam emitted by a special LED light source after hitting the sample.This total reflection is converted into refractive index, BRIX, HFCS or user defined concentrations. A built-in Peltier thermostat controls the temperature (no water bath required).
Advantage: built in thermostate high accuracy measurement Operator independent result automation Disadvantage Relatively expensive
Application perfume ,fragrances Production Control Raw Material
DIGITAL DENSITY METER A hollow glass tube vibrates at a certain frequency. This frequency changes when the tube is filled with the sample: the higher the mass of the sample, the lower the frequency. This frequency is measured and converted into density. Calibration is carried out with air and distilled water. A built-in Peltier thermostat controls the temperature very precisely, without using a water bath.
Advantage Disadvantage Application Built in thermostate Relatively expensive High accuracy measurement Very high accuracy Perfumes ,fragrance where small sample volume is required Operator independent result Soft drinks ,cola drinks BRIX measurement Small sample volume Alcoholic beverage, alcohol measurement Petroleum API measurement NUCLEONIC DENSITY GAUGE Nucleonic Density gauges send a focused beam of radiation from the source holder to a detector mounted on the opposite side of the process pipe or vessel. As the density within the pipe increases, the energy reaching the detector progressively decreases and therefore process density can be calculated. The integral HART transmitter in the detector is pre-programmed with a density linearisation curve. Therefore it can be commissioned easily with single-point or two-point calibration. The optional flow meter input enables the density gauge to calculate the mass flow in pipes with diameters from 50 mm to 1000 mm.
DSG provided by OHMART VEGA ADVANTAGES PROCESS TEMPERATURE COMPENSATED DENSITY With input from a temperature probe, the density can be calculated to a reference process temperature. EASE OF CALIBRATION For most applications, users can utilize a one-point calibration method referencing a fluid of known density. The two-point calibration method is also supported. PERCENT SOLIDS MEASUREMENT When the carrier fluid remains stable, nuclear density gauges provide highly accurate measurement of percent solids for most slurries. MASS FLOW MEASUREMENT When used in conjunction with a flow meter, nuclear density gauges provide online mass flow monitoring. POINT LEVEL SWITCH Due to its high sensitivity, the DSG can be used for point level applications. System includes one analog and one discrete output. COMPATIBLE WITH MOST SOURCE HOLDERS AVAILABLE WITH PVT PLASTIC OR SODIUM IODIDE CRYSTAL
APPLICATION Pulp & paper White liquor Black liqour Green liquor Lime mud Soap and detergent Liquid soap density Dry detrgent bulk density Mining slurries Coal Potash Brine phaspheae Lime stone gold Taconite copper chemical acid concentrati on/mixture.
polymer density
Ammonia
Lime slurry Refinery/pipe line Crude oil density Refined oil density Pipeline product interface Food & grain Mesh density Soy slurry ULTRASONIC DENSITY SENSOR The determination of the density of different liquids is very important for process automation. Commonly available sensors are limited to pipe diametersbelow 60 mm. Ultrasonic measurement principles overcome this limitation, thus allowing measurements in large pipes without pressure loss. The sensor comprises a transducer consisting of a piezoceramic disk mounted between two reference rods of quartz glass. Additionally, a second transducer is used as a sound receiver. The density is obtained from the reflection coefficient of ultrasound at the interface between the quartz glass rod and the liquid, and the transit time of sound between this interface and the second transducer SENSOR PRINCIPLE The density p of a liquid is obtained from its acoustic impedance Z and sound velocity with the help of the relation Z = p ' c. The sound velocity is calculated from the transit time of an ultrasonic pulse along a known distance. The acoustic impedance can be calculated from the measurement of the reflection coefficient R of sound at the interface of a material with known acoustic impedance (reference material) and the unknown liquid Model 9690 Inline Ultrasonic Density Sensor and Analyzer By Rhosonics Analytical BENEFITS Very easy to install Medium-independent density measurement Fully inline, zero intrusion Easy fix in Rhosonics wafer cell Very insensitive to gas bubbles
DYNATROL DENSITY SENSOR Principle of Operation The media under test flows through the internal U-tube portion of the Dynatrol cell. The tubing is driven into mechanical vibration by the electrically excited drive coil. As the density or specific gravity of the media increases or decreases, so does the effective mass of the U-tube, changing the frequency of vibration. The pick-up end, consisting of an armature and coil arrangement, senses the vibration and provides an output that is a function of the density, specific gravity or percent solids of the process media.
SPECIFIC GRAVITY TRANSDUCER Functional Principle The instrument utilizes an acoustical principle whereby a transmitter membrane vibrating sinusoidally at a constant frequency and amplitude transfers its motion to the gas in the sample chamber. The pressure amplitude received at a pressure transducer in direct proximity is directly related to the density of the gas sample. The propagation of the sound waves in the analyzer chamber is in general not only a function of the gas- density, but is also influenced by other gas parameters such as viscosity and heat capacity. The analyzer's high selectivity to the density is the result of proper chamber geometry, dimensioning and operational parameters.
DENSITY OF SOLIDS To calculate the density of solids ,mass and volume of solids are measured. Mass can be measured easily by using weighing machin with high precision(if required). Measurement of volume of solids can not be done directly so an indirect method is generally adopted. In this we use the defination of buoyancy.
left hand side of the equation is evaluated. If mass of solid is measured in the air and then in liquid then apparent mass loss is
g V F o f B f O V M The density of object can be deduced to be
One can therefore take advantage of a modern high precision balance with re-zeroing capability to monitor the apparent change in mass of the liquid and container when the object is lowered into the liquid.