Bonding

Siti Sunarintyas
Biomaterial, FKG - UGM
PRINCIPLE OF ADHESION
(BONDING)
Definition
Adhesion
unlike molecules are attracted e.g. A-B
Cohesion
same kind of molecules are attracted e.g. B-B
Adhesive
material or film added to produce the adhesion B
Adherend/substrate
material to which adhesive is applied A
A B A
Adhesion can be measured from the spreading of liquid
droplets on enamel surfaces.
Adherend 1 Adherend 2
Adhesive System
or Luting Cement
Interface 2 Interface 1
DENTAL
JOINT
ENAMEL, DENTIN >
Liner, Base, Cement >
Post and Core >
Dental Amalgam >
Implant >
< Composite, Amalgam
< Cast Inlay, Onlay, or Crown
< All-Ceramic Inlay, Onlay, or Crown
< Veneers, Maryland Bridges
< Orthodontic Brackets
Adhesive Interface 1
DENTAL
ADHESION
FORMING GOOD ADHESION
(1) Clean adheren
(2) Good wetting
(3) Close adaptation
(4) Bonding
(5) Good curing
physical
bonding
chemical
bonding mechanical
bonding
+

(1) OPERATOR
Technical skill, ages, view, ...
(2) Desain
Bevel, Outline Form, .
(3) MATERIALS
Composition, expire date, T, %RH, ...
(4) INTRAORAL LOCATION
Anterior-Posterior, Maxillary-Mandibular,
Lingual-Facial, Premolar-Molar, ...
(5) PATIENT
F-exposure, Diet, Oral Hygiene, IQ, Caries Risk, ...
Factor influencing the appearance
EMAIL BONDING SYSTEM
89v/o HA,
6% Organic,
5% Water
FROSTY
APPEARANCE
SBS = 20 MPa
e f
g
Intertubular dentin
Peritubular dentin
Dentinal tubule
Residual smear
layer particles
Residual smear
plug particles
Macrotag Microtag
Conditioning
Priming
Bonding
COMPOSITE
HYBRID LAYER: resin microtags that are within
intertubular dentin and surround collagen fibers.
Collagen fibers
B. Removing of smear layer and hybrid layers
BONDING SYSTEM

A. Classification of bonding system :
1. Substrate type (email, dentin)
2. Generation
3. Component amount
Prime&Bond
Dentsply International
(Acetone solvent system)
Single Bond
3M Dental Products Division
(Ethanol and water solvent system)
Scotchbond Multipurpose Plus
3M Dental Products Division
(Ethanol and water solvent system)
One-Step
BISCO
(Acetone solvent system)
HOW
MUCH
SOLVENT?
Designing Bonding Systems
BONDING AGENT
PRIMER
ETCHANT
E+nP+B
US Companies
2 =
1 =
E+nPB
Japanese Companies
= 2
= 1
or nEP+B
Self-Etching
Primer
???
nEPB
Self-Etching
Adhesive
hydrophilic tooth structure
hydrophobic restorative material
Total Etch Systems
E + nP + B or nEP + B E + nPB nEPB
Self-Etching Primer
Self-Etching Adh
nP =
HEMA, ,
(Polymers),
Alcohol, H2O, Acet
E =
H3PO4,
H2O
B =
Bis-GMA, TEGDMA
Acetone or Alcohol
E =
H3PO4,
H2O
nPB =
HEMA, , TEGDMA
(Polymers),
Alcohol, H2O, Acet
B =
MMA, Bis-GMA, TEGDMA,
(Polymers),
Acetone or Alcohol
Acid Monomer,
HEMA,
H2O
nEP =
Acid Monomer,
HEMA,
Polymer,
(TEGDMA),
H2O, Alcohol
nEP =
BONDING SYSTEM: pH
3-Component (E+P+B), Total Etch
10% H3PO4 0.8
35% H3PO4 0.1
2-Component (E+PB), Total Etch
One-Step 0.8 + 4.7
Bond 1 0.8 + 3.9
SingleBond 0.8 + 3.6 (5.1)
Optibond S 0.8 + 2.8
Prime&Bond NT 0.8 + 2.6 (3.2)
Cabrio 0.8 + 2.5
PQ1 0.8 + 2.2
2-Component (EP+B), Self-Etching Primer
SE Bond 2.6
Tyrian SPE 0.4
1-Component (EPB), Self-Etching Adhesive
Panavia 2.9 (A+B)
iBond 2.4
One-Up 2.3
Prompt L-Pop 1.3
Xeno III 1.1
7.0
5.0
4.0
3.0
2.0
1.0
0.0
-1.0
6.0
Basic
Acidic
Effectifity of Etching Variable
E+nP+B E+nPB nEP+B
Self-Etching
Primer
nEPB
Self-Etching
Adhesive
Total-Etch Systems Self-Etch Systems
Reliable Bonding No Postoperative Sensitivity
1. Keep in refrigerator.

2. Use steel burs or carbide burs (not diamonds)
for dentin bonding.

3. Application of multiple layers by applicator.

4. Use etching of H3PO4, if enamel is contributed.
Hybrid
Layer
Hybrid
Layer
Hybrid
Layer
Hybrid
Layer
hydrophilic
hydrophobic
BONDING SYSTEM
2-COMPONENT SYSTEMS (nEP + B)
Clearfil SE Bond & LinerBond 2v (Kuraray)
Tyrian SPE (Bisco)
Optibond Solo SE Plus (Kerr)
Fluoro Bond (Shofu)
UniFil Bond (GC)
Mac Bond II (Tokuyama)
NanoBond (Pentron)

1-COMPONENT SYSTEMS (nEPB)
AQBond (Sun Medical)
or Touch-and-Bond (Parkell)
Adper Prompt or LP3 (3M-ESPE)
Solist (One-bottle-bond) (DMG Hamburg)
iBond (Hereaus-Kulzer)
Xeno III (Dentsply)
3-COMPONENT SYSTEMS (E + nP + B)
Scotchbond Multipurpose Plus (3M)
Permaquick (Ultradent)
Bond-It (Jeneric / Pentron)
All-Bond 2 (BISCO)
Tenure A/B/S (Denmat)
ProBond (Dentsply)

2-COMPONENT SYSTEMS (E + nPB)
Syntac Single Component (Ivoclar)
Ecusit Primer/Mono (DMG Hamburg)
One Coat Bond (Coltene / Whaledent)
Bond-1 (Jeneric / Pentron)
Tenure Quik with Fluoride (Denmat)
Solid Bond (Hereaus-Kulzer)
Imperva Bond (Shofu)
EG Bond (Sun Chemical)
PQ1 (Ultradent)
Easy Bond (Parkell)
Paama 2 and Stae (SDI)
Prime&Bond NT (Dentsply)
Single-Bond (3M)
Optibond Solo and Solo Plus (Kerr)
One-Step (BISCO)
Excite (Ivoclar/Vivadent)
OSB Bonding System (ESPE)
IntegraBond (Premier)

ENAMEL or
DENTIN
DENTAL
AMALGAM
AMALGAM
BONDING SYSTEM
Amalgam Reaction
Product Matrix
Residual
Amalgam Alloy
AMALGAM BONDING
Mechanical Interlocking
Interfacial Interlocking of phases
Amalgambond Plus
(Parkell)
ENAMEL
CERAMIC
INLAY
Acid-etched
enamel
and dentin
Dentin
bonding
system
Silanated /
Bonded surface
HF acid-etched
surface
RESIN
INLAY
CEMENT
CERAMIC BONDING
Resin Cement
= Composite
HF ETCHING
High-Leucite Porcelains
High-Alumina Porcelains
Alumina Cores (ProCera)
Zirconia Cores (Cercon, Lava)
DENTIN