Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd.
How can we measure the mass of an atom? Chemists often compare masses of different atoms with the carbon-12 atom (an isotope of carbon). Atoms also have very small masses, so it is not practical to use the actual masses of atoms in calculations. The masses of all other atoms are compared with one-twelfth the mass of one carbon-12 atom. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Relative Atomic Mass The relative atomic mass of any atom is the number of times the mass of one atom of an element is greater than 1/12 of the mass of one carbon-12 atom. Relative atomic mass = Mass of 1/12 of an atom of carbon-12 Mass of one atom of the element Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Relative Atomic Mass The symbol for relative atomic mass is A r . Relative atomic mass is a ratio and has no unit. The relative atomic mass of each element is given in the Periodic Table. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Relative Atomic Mass of Some Elements Some A r values are not whole numbers. 35.5 Chlorine 16 Oxygen 12 Carbon 1 Hydrogen Relative atomic mass, A r Element Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Why are some A r values not whole numbers? This is because such elements occur as mixtures of isotopes. For example, chlorine exists in two isotopic forms: chlorine-35 and chlorine-37. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. How do we derive the A r of chlorine? Hence, relative atomic mass of chlorine = (0.75 35) + (0.25 37) = 26.25 + 9.25 = 35.5 A sample of chlorine is made up of 75% of chlorine-35 atoms and 25% of chlorine-37 atoms. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Relative Molecular Mass
Many elements and compounds exist as molecules. For example, chlorine exists as molecules.
Cl Cl Hence, we use relative molecular mass instead of relative atomic mass. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd.
The relative molecular mass (M r ) of an element or compound is the mass of a molecule, compared to 1/12 the mass of one atom of carbon-12. Like A r , it is a ratio and therefore has no unit. Relative Molecular Mass
M r Mass of 1 molecule Mass of 1/12 of a carbon-12 atom
= Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. How do we calculate the relative molecular mass of ammonia (NH 3 )? A r of N = 14 A r of H = 1 M r of NH 3 = 14 + 1 3 = 17 Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. How do we calculate the relative molecular mass of ethanoic acid (CH 3 COOH)? A r of C = 12 A r of H = 1 M r of CH 3 COOH = 12 + 1 3 + 12 + 16 + 16 + 1 = 17 A r of O = 16 Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. (2 x 12) + (6 x 1) + (1 x 16) = 46 2 C; 6 H; 1 O C 2 H 5 OH Ethanol (2 x 1) + (1 x 16) = 18 2 H; 1 O H 2 O Water (1 x 12) + (2 x 16) = 44 1 C ; 2 O CO 2 Carbon dioxide (1 x 14) + (3 x 1) = 17 1 N; 3 H NH 3 Ammonia 2 x 14 = 28 2 N N 2 Nitrogen Calculating M r Number of atoms in one molecule Chemical formula Molecule Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Relative Formula Mass
Many substances such as water are covalent and exist as molecules. However, substances like sodium chloride are ionic and do not exist as molecules. The relative molecular mass of an ionic compound is more accurately known as relative formula mass. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Relative Formula Mass
Like relative molecular mass, relative formula mass has the symbol M r and relative formula mass has no units.
For example, the relative formula mass of sodium chloride (NaCl) is 23 + 35.5 = 58.5. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Calculating M r of MgSO 4 A r of Mg = 24 A r of S = 32 M r of MgSO 4 = 24 + 32 + (16 4) = 120 A r of O = 16 Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Calculating M r of CuSO 4 . 5H 2 O A r of Cu = 64 A r of S = 32 M r of CuSO 4 .5H 2 O
= 64 + 32 + (16 4) + 5 (2 1 + 16) = 250 A r of O = 16 A r of H = 1 The dot means plus in calculation. 5 needs to be multiplied to entire M r of water. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Molecule Chemical Formula Number of atoms in one molecule Calculating M r Magnesium sulphate MgSO 4 1 Mg; 1 S; 4 O (1 x 24) + (1 x 32) + (4 x 16) = 120
Calcium carbonate CaCO 3 1 Ca; 1 C; 3 O (1 x 40) + (1 x 12) + (3 x 16) = 100
Calcium nitrate Ca(NO 3 ) 2 1 Ca ; 2 N; 6 O (1 x 40) + (2 x 14) + (6 x 16) = 164 Copper(II) sulphate crystals CuSO 4 . 5H 2 O 1 Cu; 1 S; 9 O; 10 H (1 x 64) + (1 x 32) + (9 x 16) + (10 x 1) = 250 Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. The Mole Atoms are too small and numerous to be counted one at a time. Instead, the quantity of atoms is measured by mass. The unit of measurement for atoms and molecules is the mole. The symbol for the mole is mol. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. The Mole A mole of substance contains the same number of particles as the number of atoms in 12 g of carbon-12. 12 g of carbon-12 contain approximately 6 10 23 carbon atoms. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. How many particles are there in a mole? There are approximately 6 10 23 particles in one mole of substance. 6 10 23 is called the Avogadros constant or Avogadros number. One mole of particles means 6 10 23 particles. The particles could be atoms, molecules, ions or electrons. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. How do we convert between number of moles and number of particles? Number of moles Number of particles 6 10 23 = Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 1: Convert 1 10 23 neon atoms to moles of neon atoms Number of moles of neon atoms Number of moles of neon atoms 6 10 23 = 1 10 23 6 10 23 = = 0.167 mol Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 2: How many iron atoms are there in 0.5 mol of iron? Number of iron atoms Number of moles 6 10 23 = = 3 10 23 In 1 mole of iron, there are 6 10 23 iron atoms. 0.5 6 10 23 = Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 3: How many hydrogen atoms are there in 3 moles of hydrogen gas? Hydrogen gas is made up of hydrogen molecules (H 2 ). In 3 moles of H 2 molecules, there are 3 2 = 6 moles of H atoms. In 1 mole of H 2 molecules, there are 2 moles of H atoms. Number of hydrogen atoms Number of moles 6 10 23 = = 3.6 10 24 6 6 10 23 = Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. How is the mole related to chemical equations? 2 particles (atoms) of sodium 1 particle (molecule) of chlorine 2 moles of sodium atoms 1 mole of chlorine molecules Na + Cl 2 NaCl 2 2 OR OR 2 units of sodium chloride 2 moles of sodium chloride OR Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd.
The molar mass of an element is the mass of one mole of atoms of the element. What is the mass of one mole of atoms of an element? Do you notice a relationship between the value of A r and the molar mass of a substance? Element A r Molar mass Aluminium 27 27 g carbon 12 12 g Neon 20 20 g Oxygen 16 16 g Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. What is the relationship between mole and molar mass? The number of moles of an element can be calculated using the formula: Number of moles of an element Mass of element (g) A r of element
= Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 1 Determine the number of moles in 0.196 kg of iron. (A r : Fe = 56) Number of moles of iron mass of iron in grams A r of iron = 0.196 1000 56 = = 3.5 mol Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 2 a) How many moles of lead are there in 1.204 10 22 atoms of lead? b) What is the mass of 1.204 10 22 atoms of lead? (A r : Pb = 207) a) Number of moles of lead number of atoms of lead Avogadros constant = 1.204 10 22
6 10 23
= = 0.02 mol Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 2 (continued) a) How many moles of lead are there in 1.204 10 22 atoms of lead? b) What is the mass of 1.204 10 22 atoms of lead? (A r : Pb = 207) b) Mass of lead = number of moles A r of lead = 0.02 207 = 4.14 g Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. What is the mass of one mole of molecules or one mole of a compound? One mole of a substance has a mass equal its M r . 18 g (2 1) + 16 = 18 H 2 O Water 40 g 24 + 16 = 40 MgO Magnesium oxide 254 g 2 127 = 160 I 2 Iodine 32 g 2 16 = 32 O 2 Oxygen Molar mass M r Formula Substance Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. The number of moles of a substance can be calculated using the following formulae: Number of moles Mass of substance (g) M r = or Number of particles 6 10 23 = Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd.
Example 1 A conical flask contains 68.4 g of octane (C 8 H 18 ). How many molecules of octane are there in the flask?
Number of moles of octane Mass of octane M r of octane = 6.84 114 = = 0.6 mol Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 1 (continued) A conical flask contains 68.4 g of octane (C 8 H 18 ). How many molecules of octane are there in the flask? Number of molecules of octane = number of moles Avogadros constant = 0.6 6 10 23 = 3.6 10 23
Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 2 How many ions are there in 20 g of magnesium oxide (MgO)?
Number of moles of MgO Mass of magnesium oxide M r of magnesium oxide = 20 40 = = 0.5 mol Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 2 (continued) How many ions are there in 20 g of magnesium oxide (MgO)? MgO Mg 2+ + O 2 1 mol of MgO 1 mol of Mg 2+ ions and 1 mol of O 2 ions. 0.5 mol of MgO 0.5 mol of Mg 2+ ions and 0.5 mol of O 2 ions. Hence, 0.5 mol of MgO contains 1 mol of ions. Number of ions = 1 6 10 23 = 6 10 23 Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Molar Gas Volume Unlike solids and liquids, gases weigh very little.
It is easier to measure the volume of a gas than its mass.
Is there a way to relate moles to the volumes of gases? Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Molar Gas Volume One mole of any gas occupies 24 dm 3 (24 000 cm 3 ) at room temperature and pressure (r.t.p.). 24 dm 3 is called the molar volume of a gas. Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. This means that at r.t.p. 1 mol of oxygen occupies 24 dm 3 , 1 mol of carbon dioxide occupies 24 dm 3 ,
2 mol of oxygen occupy 2 24 = 48 dm 3 , 2 mol of carbon dioxide occupy 2 24 = 48 dm 3 . how many dm 3 ? how many dm 3 ? how many dm 3 ? how many dm 3 ? 2 24 = 48 dm 3 24 dm 3 2 24 = 48 dm 3 24 dm 3 Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. How can we calculate the number of moles of a gas? The number of moles of a gas can be measured in 2 ways: Number of moles of gas = M r of gas Mass of gas in grams Number of moles of gas = 24 000 cm 3 Volume of gas in cm 3 at r.t.p Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Example 1 What is the volume, in dm 3 , of 8 g of oxygen gas (O 2 ) at r.t.p.? Relative molecular mass of oxygen = 2 16 = 32 Volume of oxygen = number of moles of oxygen 24
= 24
= 6 dm 3 32 8 Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Number of moles of carbon dioxide given off Number of molecules of carbon dioxide given off = number of moles Avogadros constant = 3.33 10 3 6 10 23
= 2.00 10 21
Example 2 In an experiment, hydrochloric acid was reacted with calcium carbonate at r.t.p. 80 cm 3 of carbon dioxide was produced. Calculate the number of molecules of carbon dioxide given off.
Example 3 Calculate the mass of oxygen gas (O 2 ) in a room that measures 4 m high, 8 m wide and 10 m long. Assume that air contains 20% oxygen. (1 m 3 = 10 6 cm 3 ) Volume of air in room = 4 x 8 x 10 = 320 m 3 = 320 x 10 6 cm 3 Volume of oxygen in room = 20% x 320 x 10 6 = 64 x 10 6 cm 3 Mass of oxygen = 24 000 cm 3 Volume of oxygen Number of moles of oxygen x M r Molar volume = = x 32 64 x 10 6 cm 3 8.53 x 10 4 g = x 32 Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Do the balloons of the same volume contain the same number of particles?
According to Avogadros Law, each of these balloons contains the same number of gaseous particles since they have the same volume. Yes, they do! Copyright 2006-2011 Marshall Cavendish International (Singapore) Pte. Ltd. Do the balloons of the same mass contain the same number of particles?
No, they dont! Same mass but different number of moles. Gas Mass (g) A r or M r Number of moles = mass / A r or M r Helium (He) 0.18 4 Hydrogen (H2) 0.18 2 Methane (CH4) 0.18 16 = 0.011 16 0.18 = 0.090 2 0.18 = 0.045 4 0.18