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http://www.edwardsmoving.com/Flash%20Drum.html
http://www.sidem-desalination.com/en/process/MSF/
BIODIESEL MANUFACTURING
Biodiesel is made by transesterification of triglycerides
with methanol, using NaOH as the catalyst:
The DPS Delta glycol dehydration unit removes water vapor from a gas stream to allow further
treatment and transportation without risk of hydrate formation or corrosion in the presence of
H2S or CO2, using ethylene glycol as a liquid desiccant.
http://www.dps-delta.com/portfolio/glycol.htm
F=L+V
F zi = L x i + V y i
Ki = yi / xi
Fzi
Fzi
zi
xi =
=
=
L +VK i (F -V ) +VK i 1+ (K -1)V
i
K i zi
1+ (K i -1)V
x
i
=1
F
or
y
i
=1
Rachford-Rice Solution
trial-and-error method (except binary); easy to program
xi =
zi
1+ (K i -1)V
possible solution:
and
=1
F
zi
1+ (K i -1)V
faster convergence:
y - x =
i
K i zi
1+ (K i -1)V
(K i -1)zi
i 1+ (K -1)V
i
=0
F
-
F
zi
1+ (K i -1)V
=0
F
Rachford-Rice equation
Finding V/F
( )
f V
(K i -1)zi
=
F
i 1+ (K -1)V
i
=0
F
( )
V
( F)
= V
( F)
= -
i
prev
fprev
dfprev
( F)
d V
(K i -1)2 zi
1+ (K -1)V
i
F
Guess Tdrum
Calculate Ki values
Evaluate V/F using R-R equation
If f(V/F) 0, guess new Tdrum (recall Tbp calculation)
xi =
zi
1+ (K i -1)V
or
F
yi =
K i zi
1+ (K i -1)V
Separation is compromised
materials issues:
high temperature?
high pressure?
corrosive feed?
rL - rV
rV
uperm = K drum
4Ac
rule-of-thumb: 3 h/D 5
Graphical solution
for binary mixtures
CMB:
F zi = L xi + V yi
yi = -(L/V) xi + (F/V) zi
equation of a straight line
the operating line
slope = -(L/V)
solution to the flash drum problem must simultaneously
satisfy CMB (operating line) and VLE (equilibrium line)
for a binary mixture, we can represent both on a 2D graph
McCabe-Thiele diagram
yE = -(L/V) xE + (F/V) zE
simultaneous
solution of
CMB and VLE
yE
Find Tdrum?
yE/xE = KE (Tdrum)
xE
yi = -(L/V) xi + (F/V) zi
yint = (F/V)zE
for specified feed (zi), Pdrum and V/F:
yint = (F/V) zi
when yi = xi,
yi = -(L/V) yi + (F/V) zi
yi (1 + L/V) = (F/V) zi
yi (V + L)/V = (F/V) zi
i.e., yi = xi = zi
zE
Limits of separation
as x xmin, or y ymax, product yield 0
to achieve finite yield, must have less separation
yi = -(L/V) xi + (F/V) zi
for a given feed (zi), 0 (V/F) 1
(V/F) = 1
V/F = 0
yE,max
(vaporize no feed)
(L/V) = (F/V) 1 =
operating line is vertical
corresponds to ymax
V/F = 1
xE,min
V ,i
Feed temperature
What temperature must the feed be to cause the flash?
EB:
Case 1:
EB
i.e., Tdrum is determined
Case 2:
EB
i.e., TF is determined
F, zi, TF