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H and Hrxn
EXAMPLE:
Calculate the value of Ho for the reaction:
2 S (g) + 2 OF2 (g)
SO2 (g) + SF4 (g)
When
OF2 (g) + H2O(l)
O2 (g) + 2HF(g) Ho = -277 kJ
SF4 (g) + 2 H2O (l)
SO2(g) + 4HF(g) Ho = -828 kJ
S(g) + O2 (g)
SO2 (g)
Ho = -297 kJ
SOLUTION:
( OF2 (g) + H2O (l)
(SF4 (g) + 2 H2O(l)
( S(g) + O2 (g )
2 O2 (g) + 4 HF (g)
SF4 (g) + 2 H2O (l)
2 SO2 (g)
SO2 (g) + SF4 (g)
Ho = -277 kJ x 2
= -554 kJ
Ho = -828 kJ
+ 828 kJ
Ho = -297 kJ x 2 = -594 kJ
Ho = -320 kJ
Use material
balances and phase
equilibrium
relationship such
as Roult's Law to
determine as many
stream component
amounts as flow
rate as possible
Choose
reference states
for specific
enthalphy
calculations and
prepare and fill
in an inlet-outlet
enthalphy table
Calculate H,
subtitute the
calculated value
in the appropriate
form of the
energy balances
question and
complete the
required
calculation
HC = [Hc (reactants) ]
[Hc(products)]