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Compounds
Oxides
-Rutile is a titanium dioxide
body-centred tetragonal unit cell
Sulfides
-Titanium disulfide is an inorganic compound with
the formula TiS2 hexagonal close packed (hcp )
crystal structure and octahedral coordination
geometry
Carbides
-Titanium carbide, TiC has Cubic, cF8, crystal structure
and coordination geometry is an Octahedral
Halides
Titanium tetrachloride
is the inorganic compound
with the formula TiCl4 .
TiCl4 is an unusual
example of a metal halide
that is highly volatile.
Organometallic complexes
Dicarbonylbis(cyclopentadienyl)titanium is the chemical
compound with the formula (5-C5H5)2Ti(CO)2, abbreviated
Cp2Ti(CO)2.
Hexaaquatitanium(III) or
(Titanium III hexahyrate)
hexaaquotitanium(III), Ti(H2O)63+.
The ligands (H2O in this example which is monodentate ligand)
are bound to the central ion by electron pairs contributed by
each ligand. Because the six ligands are located at the corners
of an octahedron centered around the metal ion, these electron
pairs are equivalent to clouds of negative charge that are
directed from near the central ion out toward the corners of the
octahedron. We will call this an octahedral electric field, or
the ligand field.
UV-vis spectroscopy
Figure shows
Visible absorption
spectrum of [Ti(H2O)6] .