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PROPERTIES:
FREEZING POINT
DEPRESSION AND
BOILING POINT
ELEVATION
DAY 1 04 FEBRUARY 2015
Colligative Properties
Depends on the NUMBER of solute, not on the
nature of solute particles
Freezing Point Depression
Boiling Point Elevation
Vapor Pressure Lowering
Osmotic Pressure
Freezing
Point
Depressio
n
Freezing Point
Depression
Adding a solute to a solvent decreases freezing point of
the solvent
Freezing
Point of
solvent
Amount of
solute
Freezing point of
solvent 0o
(solution)
Tf = Tf - Tf
Freezing Point
Depression
Formula (nonelectrolytes):
Temperature
Freezing Point
Depression
Tf
Formula (electrolytes):
freezing point
temperature
Tf = i Kf
m
Kf
Depression
C /m)
Freezing Point
constant (1.860
Molality (mol/kg)
Freezing Point
Depression
EXAMPLES
3PO4point
Tf Nafreezing
CaCl2
NaCl
temperature
Na
Cl2
Cl
1
i=2
Ca
1
2
Na
(PO )
3
van t Hoff factor
(sum of
subscripts)
4
Kf
+
Depression
i=3
Freezing Point
i=4
Molality (mol/kg)
PRACTICE
What is the new freezing point of 200 g
of water (Kf = -1.86 oC) if195 g of
sucrose (C12H22O11) are added to it?
ANSWER
Tf = -5.301C
PRACTICE
What is the molality of barium sulfate
(Ba2SO4) with a freezing a point of
1.12C?
ANSWER
Molality = 0.20 m
PRACTICE
A solution of 3.39 g of an unknown compound in
10.00 g of water has a freezing point of 7.31C.
The solution does not conduct electricity. What
is the molar mass of the compound?
ANSWER
Molar mass = 86.26 g/mol
Boiling
Point
Elevation
Amount of
solute
Tb (solution) > Tb
pure
Boiling Point
Elevation
Boiling Point of
solvent - 100C
(pure solvent)
Tb = Tb + Tb (+)
Boiling point of
elevation
Molal boiling elevation
constant (0.5120 C /m)
Molality (mol/kg)
Formula (electrolytes):
freezing point
temperature
Tb = i Kb
m
Kb
Elevation
C /m)
Molality (mol/kg)
PRACTICE
What will be the boiling point of an
aqueous solution containing 55.0 g of
glycerol, C3H5(OH)3, and 250 g of water?
Kb(H2O)= 0.512 c/m
ANSWER
Tb = 1.23C
PRACTICE
What is the boiling point of a solution
containing 34.3 g of magnesium nitrate
dissolved in 0.107 kg of water?
ANSWER
Tb = 3.3C
PRACTICE
A solution containing 28.4 g of sodium
bromate dissolved in water. Find the
mass of the solvent if the boiling point of
the solution is 8.5C.
ANSWER
Mass of solvent = 0.034 kg