Академический Документы
Профессиональный Документы
Культура Документы
Content
Introduction
Natural occurrences
Radioactivity
Fr - heaviest element in group
- highly radioactive - form by particle emission from
actinium
K and Cs natural radioactive isotope
Element
Mineral
Lithium, Li
Sodium, Na
6th most abundant in
the earth crust
Potassium
8th most abundant in
the earth crust
Compound
Petalite
Spodumene
LiAlSi4O10
Caustic Soda
Rock salt
Saltpeter
Trona
Mirabilite
Albite
NaOH
NaCl
NaNO3
Potash
Sylvite
Carnalite
Orthoclase
K2CO3
Rubidium, Rb
Lepiodolite impurities
Cesium, Cs
Pollucite
Lepiodolite impurities
LiAlSi4O10
Na2CO3.NaHCO3.2H2O
Na2SO4.10H2O
NaAlSi3O8
KCl
KCl.MgCl2.6H2O
KAlSi3O8
CsAl4Si9O26.H2O
Physical properties
Silvery
Soft : can be cut with knife ; but Li is harder
- Na soft (cold butter)
- Cs slightly golden and melts in hand
- K squeezed like clay or dough
Metals are soft and relatively low melting point
Reason : - one valence electron, ns1
- distance between the nucleus and valence electron is far
- the attraction between them is relatively weak
- weak metallic bonding cause the crystal structure to be
deformed or broken down easily.
Low densities : lowest molar mass in their period and largest atomic
radii.
- Li floats on lightweight household oils
Element
Mp
Bp
Density,
g/mL
Standard
Reduction
Potential
(SRP), V
First
Ionization
energy,
KJ/mol
Lithium
180.5
1347
0.534
-3.05
520
Sodium
97.8
881
0.971
-2.71
496
Potassium
63.2
766
0.862
-2.92
419
Rubidium
39.0
688
1.53
-2.92
403
Cesium
28.5
705
1.87
-2.92
377
Chemical properties
Forms less stable compounds with MOH (M = Na, K, Rb, Cs) is very
large anions. For example, LiOH
stable
decomposes to Li2O
Strong tendency to form covalent
compounds
General reaction :
2M + 2H2O
2MOH +
H2
Properties
oxide ;
M2O
White crystals
[O]2Li2O
Peroxide
M2O2
Basic oxide
Basic oxide
[O2]2Na2O2
Superoxide Basic oxide
MO2
[O2]KO2
RbO2
CsO2
Reaction
Preparation :
4Li + O2
(Lithium Oxide)
(limited oxygen)
Reaction:
Li2O + H2O
Preparation :
2Na + O2
Reaction:
Na2O2 + H2O
Preparation:
K + O2
Reaction:
2KO2 + 2H2O
Li2O
2LiOH
Na2O2
2NaOH + H2O2
KO2
2KOH + H2O2 + O2
Uses
Properties
Metal
hydroxide
-Strong
base
-Basicity
increases
down a
group
-White
crystalline
solid
-water
soluble
-Become
liquid when
expose to
air; except
LiOH
Reaction
Preparation:
2Na + 2H2O
2NaOH
Uses
+ H2
or from
Oxides or
Peroxides or
Superoxides
Reaction:
NaOH + HCl
Breathing equipment
NaCl + H2O
Properties
Alkali
metal
-White
crystalline solid
-Thermally
stable
-Soluble in
water except LiF
-LiCl, LiBr and
LiI : soluble in
alcohol and less
polar solvent,
ethoxyethane
Reaction
Preparation:
1. 2M + Cl2
2. NaOH + HCl
Reaction:
2NaCl + 2H2O
2MCl
NaCl + H2O
2NaOH + Cl2 + H2
Uses
Na2CO3 + H2O
Uses :
NaCl : glazing the earthenware,
regenerating water softeners and
salting out of soap
KCl : fertilizer and others
(chlor-alkali
process)
Solvay process
to produce
Na2CO3
LiH
NaH, KH
Properties
Reaction
-white
crystalline solid
-reactivity
increases down
a group
Preparation:
M + H2
Most stable,
melts at 700 0C,
decomposes at
1000 0C
-unreactive O2
and Cl2
8LiH + Al2H6
Decompose at
400 0C
2NaH
Uses
2LiAlH4 + 6LiCl
2Na + H2
LiAlH4 :
versatile
reducing agent
Hydrides
Properties
-base
Reaction
Reaction:
NaH + H2O
4NaH + (CH3)3BO3
+ 3CH3ONa
2NaH + B2H6
Uses
H2 + NaOH
NaBH4
2NaBH4
NaH good
reducing agent;
descaling iron and
making NaBH4
Properties
Reaction
-Nature : Na2C03
, K2CO3
-Thermally
stable; except
Li2CO3
-Soluble in
water; except
Li2CO3 slightly
soluble
Li2CO3
Li2O + CO2
Uses
Li2CO3 porcelain
enamels Li2CO3 and
glass
K2CO3 to produce KCN
and K2CrO4
Na2CO3 from solvay
process
Hydrate Na2CO3
Reactions Summary
1.
4M
O2
2M2O
limited O2
2.
4Li
O2
2Li2O
Excess O2 (Litihium
oxide)
3.
2Na
+ O2
Na2O2
sodium peroxide
4.
MO2
M = K, Rb, Cs ; excess
O2 (superoxide)
5.
2M
+ H2
2MH
Molten metals
6.
2M
+ X2
2MX
X = halogen
7.
2M
+ H 2O
2MOH + H2
K, Rb, Cs react
explosively
O2
The presence of CaCl2 reduces the melting point of the mixture to 580
0C, the eutectic mixture
Graphite electrode : anode
Cylindrical steel : cathode
Liquid Na drawn off the electrolytic chamber into container which cools
the liquid and finally freezes as solid sodium
Cl2 gas liberated at graphite anode and flow to the top of reaction
chamber into tank.
2Na+ +
2Cl-
ELECTROCHEMICAL CHANGES
At cathode Na+ ions migrate to cathode where they are reduced to Na.
2Na+ + 2e-
2Na (Reduction)
At anode Cl- ions migrate to anode and oxidised to form chlorine gas.
2Cl-
Cl2 + 2e-
Overall Reaction
2Na+ + 2e2Cl2Na+ + 2Cl-
(Oxidation)
2Na
Cl2 + 2e2Na + Cl2
Application of sodium :
- chemical industries eg : glass, rubber, pharmaceutical
- as reducing agent in metallurgy such as titanium
- to manufacture drugs and dye
- sodium arcs(luminous discharege of electric current crossing a
gap between two electrodes) highway lighting