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Determinatio
n of pH
Judy Ann M. Cocadiz
Louise Joy A. Martin
Objectives of
THE EXPERIMENT VI
Objectives
An Introduction
WHAT IS COLORIMETRY?
Introduction
Definition of Colorimetry
pH Indicator
pH Indicators
Indicator
Lower pH
color
pH range
Higher pH
color
Thymol blue
Red
1.2-2.8
Yellow
Bromophenol
blue
Yellow
3.0-4.6
Purple
Chlorophenol
red
Yellow
4.8-6.4
Violet
Bromothymo
l blue
Yellow
6.0-7.6
Blue
Phenol red
Yellow
6.8-8.4
Red
McIlave Buffers
The ionization
With
the colorimetric
constant
determination
is the extent
of pH, to
it
is important
which
the substance
to know the
willionization
dissociateconstant
in water.
of
the weak
Since
weak
acid
acids
involved.
only partially dissociate, they
have low ionization constants.
Henderson-Hasselbalch equation
Colorimetri
c
Determinati
on
of
Experiment
pH:
Procedure
2.0
2.2
2.4
2.6
2.8
3.0
mL
DSP
mL
CA
pH
mL
DSP
mL
CA
pH
mL
DSP
mL
CA
2.2
0.20
9.80
4.2
4.14
5.86
6.2
6.61
3.39
2.4
0.62
9.38
4.4
4.41
5.59
6.4
6.92
3.08
2.6
1.06
8.91
4.6
4.67
5.33
6.6
7.34
2.66
2.8
1.58
8.42
4.8
4.93
5.07
6.8
7.72
2.28
3.0
2.05
7,95
5.0
5.15
4.85
7.0
8.24
1.76
3.2
2.47
7.53
5.2
5.20
4.80
7.2
8.69
1.31
3.4
2.85
7.15
5.4
5.58
4.42
7.4
9.08
0.92
3.6
3.22
6.78
5.6
5.80
4.20
7.6
9.37
0.63
3.8
3.55
6.45
5.8
6.05
3.95
7.8
9.57
0.43
4.0
3.25
6.15
6.0
6.31
3.69
8.0
9.72
0.28
6.2
6.4
6.6
Thym
ol
Blue
Bromophen
ol Blue
Chlorophen
ol Red
Bromothym
ol Blue
Phenol Red
Experimental
RESULTS
Test Tube A
Test Tube A
pH
= -log []
antilog(4.8) = [] = 1.58 M
0
+x
Test Tube A
= 7.60
pH of 0.01 M HOAc
[] of 0.01 M HOAc
Calculated of HOAc
4.8
Test Tube B
I
C
E
(1mL)(0.1M)
-x
+x
0.1-x
x
(1mL)(0.1M)
+x
0.1+x
Test Tube B
*since
0.1 >> x
Test Tube C
(0.1mL)
+x
0.01+x
Test Tube C
*since
0.1 >> x
Test Tube D
(0.1mL)(0.1M)
-x
+x
0.01-x
x
(1mL)(0.1M)
+x
0.1+x
Test Tube D
*since
0.1 >> x
Overall Results
Solution
pH
Observed
Calculated
A. 0.01 M HOAc
4.8
xxxxxx
4.8
4.74
3.8
3.74
5.2
5.2
5.74
5.74
Experiment VI
DISCUSSION
Overall Results
Solution
pH
Observed
Calculated
A. 0.01 M HOAc
4.8
xxxxxx
4.8
4.74
3.8
3.74
5.2
5.2
5.74
5.74
Discussion:
Discussion:
Discussion:
Discussion:
This
Sources:
http://
chemwiki.ucdavis.edu/Physical_Chemistry/Acids_and_Bases/Buffers/Hende
rson-Hasselbalch_Approximation
http://www.carlos-arano.com.ar/pHing.html
http://www.anaesthesiamcq.com/AcidBaseBook/ab1_4.php
Thank you :D