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WHMIS
Revised November 2011
Workplace
Hazardous
Materials
Information
System
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WHMIS is
The Workplace Hazardous Materials Information
System is a Canada-wide system designed to
give employers and workers information about
hazardous materials used in the workplace.
WHMIS standards are coordinated between both
Federal and Provincial governments.
Manitoba Workplace Safety and Health Act and
Regulations sets the WHMIS requirements.
The GOAL is
A Controlled Product is
Act
Nuclear Safety and Control Act
Risks
Physical hazard
(120kg)
Explosive hazard
Content hazard
Examples
CO2
cylinders
N2
cylinders
O2
cylinders
acetylene
Risks
Frostbite
Samples may
explode
Asphyxiation
Six Subdivisions
1. Flammable gas
2. Flammable liquid
3. Combustible liquid
4. Flammable solid
5. Flammable aerosol
6. Reactive flammable material
Risks
Fire hazard will burn if ignited
Could ignite spontaneously
Could ignite upon mixing with water or other
chemicals
Many are poisonous
Risks
Increase fire and explosion
hazard
Examples
Nitrates
Peroxides
Persulfates
Hypochlorites
(bleach)
Division 3 Biohazardous
Infectious Material
20
Examples
All halogens
Carbon
monoxide
Cyanides
Examples
Asbestos
Formaldehyde,
benzene
Ammonia
Examples
Blood, tissue,
and body fluids
Tissue culture
Experimental
cultures
Risks
Will burn human
tissue including skin,
eyes, nose mouth,
throat & lungs
Examples
Hydrogen
fluoride
Strong
acids & bases
Hydrogen
chloride
Risks
May be unstable or vigorously
polymerize
May react with water to release
a toxic or flammable gas
May self-react when shocked or
heated
Highly reactive with
incompatible materials
May burn eyes and skin on
contact
Examples
Ether
Acrylates
1,3-butadiene
Metal azides
Label Types
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Labels
Supplier Labels
The following must be
included on a supplier
label:
Product Name
WHMIS Symbols
Risk Phrases
Precautionary Measures
First Aid Measures
MSDS Reference
Supplier Name
All information must be
Labels
Laboratory Supply House - Supplier Label
3) Symbol
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Labels
Workplace Labels
The following must be
included on a workplace
label:
Methanol
Product Name
Safe Handling
Instructions
MSDS Reference
Labels
Methanol
x
Workplace Labels
x
x
x
x
Labels
Workplace Labels Hazardous Waste
The following must be
included on a hazardous
waste label:
Product Name
Concentration
Hazard
Labels
Workplace Labels Hazardous Waste
Waste Tags must:
Be present on containers that do not have a
correct supplier label
Must list any chemical over 1% or any quantity if
it poses a significant hazard
Use only chemical names (no trade names,
abbreviations, or formulas)
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MSDS
Information Provided
Product Information
This section identifies product name, manufacturer and
suppliers names, addresses, and emergency phone
numbers, and the intended use of the product.
Hazardous Ingredients
This section lists All potentially hazardous ingredients,
with the approximate amount (percent), and toxicity
data for the individual ingredients. Information regarding
the LD50 and LC50 (the amount of a chemical that is
expected to kill 50% of a test animal population within a
specified time) will also be given. The lower the value
the greater the poisoning potential.
MSDS
Information Provided
Physical Data
Provides information on the physical and chemical
properties such as odour, boiling point, and vapour
density.
MSDS
Information Provided
Reactivity Data
Provides information regarding stability, self-reactivity,
hazardous decomposition products, and conditions to
avoid when using the product.
Toxicological Properties
Identifies how the substance can enter the body and the
possible health effects from short term (acute)
exposures such as irritation, sensitization; and long-term
(chronic) such as liver or kidney damage, sensitization,
cancer, or reproductive effects. Known exposure limits
will also be given.
MSDS
Information Provided
Preventative Measures
Provides preventive measures you can take to protect
yourself from exposure including: extra ventilation,
personal protective equipment (PPE), safe use, handling,
storage, disposal, transport, and spill control.
Preparation information
Indicated who was responsible for preparation and date
of preparation of MSDS. It is 3 years from this date when
the MSDS needs to be renewed.
Information may be labeled as Trade Secret if a claim
has been filed. The information is released to medical
professionals in case of emergency.
MSDS
Example
MSDS
Location, Location, Location
Spill Clean-up
Chemical, Radiological, or Biological
If a spill occurs that poses an immediate risk to people,
or if someone is injured it is an EMERGENCY call 555
Minor spills should be cleaned up by trained staff
Spills must never be cleaned up by untrained staff
Under no circumstance shall caretakers be instructed to
clean up any lab spills
The best time to learn about and practice cleaning up a
spill is before it happens read the MSDS
EHSO is also available to assist with the cleanup of nonemergency spills beyond the capabilities of available staff
Chemical Storage
General Chemical Organization
Chemical Storage
General Chemical Organization
Flammables
Bases
Oxidizers
Acids
Chemical Storage
Potentially Explosive Chemicals
Picric Acid and Nitro Compounds
Dry picric acid may explode if subjected to heat, shock,
or friction (opening the lid)
Picric acid must be stored under wet.
Some nitro compounds may have similar requirements
Chemical Storage
General Chemical Segregation
Do Not Store:
Oxidizers
Alkali metals
Acetic Acid
Acetone
Hypochlorites
Chlorine
Cyanides (Alkaline)
Potassium chlorate
Chlorates (ClO3)
Hydrogen Sulphide
H2O2
Chromic Acid
Annhydrous
Ammonia
Acids (conc.)
With:
Flammables
Water, CO2, CO, or CCl4
Chromic, nitric or perchloric acid, peroxides, permanganates,
or hydroxides i.e. KOH
Concentrated sulphuric or nitric acids
Acids
Ammonia, acetylene, butadiene, benzene, petroleum
derivatives, or sodium carbides
Acids
Acids
Ammonium salts, acids, metal powders, sulphur, or carbon
Nitric acid
Flammables, Cu, Cr, Fe, or respective salts
Acetic acid, alcohol, naphthalene, glycerine, or other
flammable liquids
Halogens, Hg, HF, or CaClO4
Bases (conc.)
Chemical Storage
General Chemical Organization & Segregation
Do Not:
Chemical Inventory
U of M Chemical Inventory Database
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