Академический Документы
Профессиональный Документы
Культура Документы
Fire Chemistry
Definition of FIRE :- Combustion reaction where heat and flame
is evolved.
FUEL + O2
Heat
CO2 + CO
FIRE =
Flammable vapour or gas (FUEL)
+
Air in correct proportion (O2)
+
Source of ignition (Naked Flame)
+
Chain reaction
Fire Chemistry
He
at
Ai
r
FIRE TRIANGLE
Fuel
Fire Tree
Heat stage - uncontrollable heat,
large amount of smoke etc.
Flame stage
- flame starts,
smoke increases
Smoking stage - visible smoke
Incipient stage - no visible smoke
Few Terminology
Flash point; It is the lowest temperature at which
the substance gives off sufficient vapour to be
ignited at the surface. The concentration of vapour
above this temp forms an ignitable mixture with
air.
Flammability limits: These limits give the range
between the lowest and highest concentration of
vapour in air that will burn or explode when an
ignition source (such as a spark or open flame) is
present.
The concentration is generally expressed as
percent fuel by volume.
Few Terminology
Fire Load; Amount of combustible matter
present that can act as a fuel to feed a hostile
fire.
Unit - kg / m2.
CLASS OF FIRE
FIRE INVOLVING
FIRE INVOLVING
Liquids such as
* Oil
* Petroleum
* Solvents
* Grease
* Paints etc.,
FIRE INVOLVING
* L.P.G
* GASEOUS SUBSTANCE UNDER
PRESSURE
FIRE INVOLVING
Magnesium
Sodium
Potassium
Flammable metals
etc.,
METHODS OF
EXTINGUISHING
STARVATION
STARVATION
REMOVE FUEL
VACATE PEOPLE
BLANKETING
*
COOLING
COOLING
*
CONTROL THE
FLOW OF HEAT
&
THE
CHAIN
REACTION BY
POURING WATER
OR
ANY
OTHER
COOLING MEDIUM
EXTINGUISHING MEDIA
CLASS A (PAPER ,WOOD)
- WATER
CLASS B (OIL)
- FOAM, DCP
CLASS C (GASES)
- DCP,CO2,
CLASS D (METAL)
- SP. POWDER
Powder
Several chemicals used to make extinguishing powders.
Efficient in the extinction of Class A, B & C Fires.
Extinction of solids by forming a flame- retardant layer on the surface
of the material.
On Electrical Installations
To be cleaned off;
Corrosion problem;
Fire Chart
Extingsuihing Agent / Principle
Type of Fuel
Class "A",
Solid fuels
Class "B"
Liquid fuels
Class "C",
Gas fuels
Class "D",
Metals
Fires Intiated
from electric
1st Option
2nd Option
Not Suitable
Water /
Cooling
Foam /
Powder /
Gas /
Blanketing Blanketing Blanketing
ABC
Stored
Pressure
2)FOAM TYPE
1. Chemical
2. Mechanical
Plunger knob
Inner chamber
(Aluminum sulfate)
Outer chamber(sodium
Bi-carbonate)
by
Construction
Aqueous Film Forming
Foam (AFFF) solution;
CO2
expel the foam
solution;
Discharge Hose
Cartridge
Operation
Remove the safety clip;
Hold the discharge hose
firmly
and
press
the
plunger;
Na2CO3 will be thrown out;
Co2 Gas
by
Flammable liquids;
Gases;
Fires starting from electrical,
Fire Prevention
Bucket of sand;
Carpentry Shop
Saw dust;
Wooden scarp;
Periodical disposal of dust;
P&M Workshop
Waste cotton rugs;
Waste oil;
Disposing out of site;
Fire plan
DOs
Inform time office or security or site safety
personnel in case of any fire.
Know the use of diff. Type of extinguishers.
Never use water on an electrical or oil fire.
Store inflammable materials in a closed
container and in its assigned place.
Clean immediately any spillage of inflammable
liquids.
Remove unwanted waste materials
Don'ts
Smoke in prohibited areas.
Store inflammables near any electrical
switch boards.
Obstruct the path leading to fire
extinguishers or emergency doors wherever
provided.
Throw
cotton
waste
soaked
with
inflammable liquids in the drains or room
corners.
Fire Extinguishers
Inspection Checklist
Inspection checklist
1. Confirm the extinguisher is in its proper location;
2. Confirm the extinguisher is not obstructed;
3. All seals and pins are in place and have not been removed
or tampered with;
4. If applicable, check gauge to ensure that the pressure is
within the operable range;
5. Examine the extinguisher for obvious signs of physical
damage, leakage, corrosion or clogged nozzles; and
6. Ensure that a current service tag is present on
extinguisher.
Hazardous Area
The Petroleum Rules, 2002
Hazardous area;
Petroleum having flash point below 65 0C or
any inflammable gas or vapour in a
concentration capable of ignition is likely to
be present.
Petroleum or any inflammable liquid having
flash point above 650C is likely handled,
stored etc..
Electric apparatus
Zone 0 area :
No electric apparatus shall be allowed in a zone 0 area;
Zone 1 area :
Flame proof apparatus
Intrinsically safe apparatus approved by the chief controller of
explosives;
An industrial-type apparatus;
Purging with a plenum of atmosphere free from significant concentrations of
inflammable gas;
Automatic cut off or a warning
Zone 2 area :
non sparking apparatus of a type approved by the chief controller;
THANK YOU