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ATOMIC STRUCTURE
2.1 Bohrs Atomic Model
2.2 Quantum Mechanical Model
2.3 Electronic Configuration
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1
n2
1)
2)
3)
4)
5)
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atomic structure
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1
1H
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H Nucleus
(proton)
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n=1
n=3
n=2
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atomic structure
e- absorb energy,
promoted to
excited state
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e-
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Points to Remember
Ground
state
state
level
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E n R H 2
n
RH (Rydberg constant)
= 2.1810-18J.
atomic structure
E = Ef - Ei
1
1
E R H 2 R H 2
nf
ni
Thus,
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1
1
E R H 2 2
nf
ni
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1
E i R H 2
ni
1
E f R H 2
nf
10
Thus,
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hc
E
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n =1
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Potential energy
n=
n=4
n=3
n=2
Energy
absorbed
Energy
released
n=1
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Example
Calculate:
i) The E of an e- has when it occupies
when it was at n=3 & n=4.
ii) The E of the photon emitted when
one mole e- of drops from the fourth E
level to third E level.
iii) The frequency & wavelength of this
photon.
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Solution :
1
E n R H 2
n
i) at n=3, E3 = -RH 1 = - 2.18 x 10-18 J
32
9
= -2.422 x 10-19 J
at n=4, E4 = -RH
42
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= - 2.18 x 10-18 J
16
= -1.363 x 10-19J
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ii
)
n=
4
E = Ef Ei = E3 E4
= -2.422x 10-19J- (-1.363 x 1019
n=3
J)
= -1.06 x 10-19J
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Exercises:
1)
2)
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