Вы находитесь на странице: 1из 16

ADSORPTIO

N
alviera

desi

lili

ghifaris

rizka

Adsorption
Adsorption is the process in which a gas,
liquid, or solid adheres (accumulated) to
the surface of a solid or (less frequently) a
liquid, but doesnt penetrate it.
(only in the surface)
Adsorption is way different from absorption

explainations

Adsorbate
Adsorbate is a liquids or gas substance
that consentrated to the surface of the
adsorbent.
There are two types of adsorbate,
such as:
Polar types
Non-polar types

Adsorptive
Adsorptive is the substance that would
be adsorp before it reach the surface
of a liquids.

Adsorbent
Adsorbent are usually a solid substance that
adsorps another substance. Adsorbents are used
usually in form of spherical pellets, rods, moldings
or monoliths with hydrodynamic diameters.

Adsorbent Material

Silica gel
Properties of Silica Gel
Bulk Density
44-56
lb/ft3
Heat Capacity
0.220.26
BTU/lboF
Pore Volume
0.37
cm3/g
Surface Area
750 m2/g
Average Pore
22
Diameter
Regeneration
120-250
o
Temperature
C
Maximum Allowable
400 oC
Temperature

Adsorbent Material
Activated Allumina
Properties of Activated
Alumina
Bulk Density
Granules
Pellets
Specific Heat
Pore Volume
Surface Area
Average Pore Diameter
Regeneration
Temperature
(Steaming)
Maximum Allowable
Temperature

38-42 lb/ft3
54-58 lb/ft3
0.21-0.25
BTU/lboF
0.29-0.37
cm3/g
210-360
m2/g
18-48
200-250 oC
500 oC

Adsorbent Material
Activated Carbon
Properties of Activated
Carbon
Bulk Density
22-34 lb/ft3
Heat Capacity
0.27-0.36
BTU/lboF
Pore Volume
0.56-1.20
cm3/g
Surface Area
600-1600 m2/g
Average Pore
15-25
Diameter
Regeneration
100-140 oC
Temperature
(Steaming)
Maximum
150 oC
Allowable
Temperature

Adsorbent Material

Molecular Sieves
Properties of Molecular Sieves

Type
Density in bulk (lb/ft3)
Specific Heat (BTU/lboF)
Effective diameter of pores
()
Regeneration Temperature
(oC)
Maximum Allowable
Temperature (oC)

Anhydrous
Anhydrous
Sodium
Calcium
Aluminosilicate Aluminosilicate
4A
5A
44
44
0.19
0.19
4
5

Anhydrous
Aluminosilic
ate
13X
38
13

200-300

200-300

200-300

600

600

600

Types of Adsorption
Based on its processes, there are two types of
adsorption as follows:
Physical adsorption (Physisorption)

interaction that happened between adsorben and adsorbate is the


Van der Walls force, whereas the force between the liquid and the
surface are bigger than the force of substance that solve in liquids.
Example :
The adsorption happens by activated carbon.

Chemical adsorption (Chemisorption)

It happens when it formed chemical bound between the solute in the


liquids with the molecules in the media. It usually formed covalent
bound.
Example :
Ion exchange reactions

The differences between chemical & physical adsorption

Physisorption
Molecules bounded to adsorbent
by Van der Walls force
The enthalpy is between -4 to
40 kJ/mol

Chemisorption
Molecules bounded to

adsorbent by chemical bound


The entalphy is between -40

to 800 kJ/mol

Multi-layer adsorpytion

Mono-layer adsorption

Adsorption happens below the

Adsorptions happen in higher

boiling point of its adsorbate


Unspecific

temperatures
Very Specific

Adsorption can be utilized in a variety of


ways, including the following

The bleaching process granulated sugar in the sugar industry


with soil diatomic
and bone charcoal.

Healing of abdominal pain with carbon powder or norit

Staining of fiber silk, wool or cotton in a solution of Al2(SO4)3

in the textile industry.


Turbid water treatment with the use of alum (Al2 (SO4) 3).

Water taps (TAPS) that exist today contains colloidal particles of clay,
mud,
and a variety of other negatively charged particles. Therefore,
to make it worth to drink, should be done in a few steps to the colloidal
particles can be separated. It is done by adding alum (Al2SO4) 3 Al3 +
Ions contained on the alum hydrolyzed colloidal particles formed be of Al
(OH) 3 positively through the reaction:

Al3++ 3H2O Al(OH)3 + 3H+

After that, Al (OH) 3 remove the charge-the negative charge of the


colloidal
particles of clay/mud and mud coagulation occurs at. The sludge is
then settles
with alum which also settles because of the influence of gravity.

The use of active charcoal


Subtle use of charcoal on the mask, serves to absorb the toxic
gas Filter on smoking, which serve to bind the smoke nicotine and
tar

Cleaning of dirt and SOAP.

Adsorption of colloidal humus by colloidal clay.

Applications of Adsorption
Adsorptionfinds extensive applications both in research laboratory
and in industry. A few applications are discussed below:
Inadsorptionindicators:
In chromatographic analysis

Incatalysis
In softening of hard water
In clarification of sugar
In paint industry
In preserving vacuum
In glass masks

QUESTION?
Thank you

Вам также может понравиться