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SYNTHETIC FIBERS
Fibre made by chemical processes, unknown in nature. There are two kinds.
One, a regenerated synthetic fibre, is made from natural materials that have
been chemically processed in some way; rayon, for example, is made by
processing the cellulose in wood pulp. The other type is the true synthetic fibre,
made entirely from chemicals. Nylon was the original true synthetic fibre, made
from chemicals obtained from petroleum (crude oil).
Fibres are drawn out into long threads or filaments, usually by so-called spinning
methods, melting or dissolving the parent material and then forcing it through
the holes of a perforated plate, or spinneret.
SYNTHETIC FIBERS
NYLON
POLYESTER
ACRYLIC
SPANDEX
OLEFIN
NYLON FIBER
Science of Nylon
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Its Chemistry
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Chemical Bonding
Its Structure
LINEAR POLYAMIDES
Characteristics of Nylon
Wrinkle Resistance
Excellent
Strength
Very Good
Absorbency
Poor
Abrasion Resistance
Excellent
Sunlight Resistance
Good
Effect of Heat
Excellent
Wash-and-wear
Excellent
Resistance to alkalies
Good
Resistance to acids
Effect of bleach
Good
Resistance to pilling
Poor to good
Resistance to perspiration
Very good
Resistance to mildew
Excellent
Resistance to moth/insects
Excellent
i) Apparel:
Blouses, dresses, foundation garments, hosiery, lingerie, underwear, raincoats, ski
apparel, windbreakers, swimwear, and cycle wear .
curtains, upholstery.
Industrial and Other Uses: Tire cord, hoses, conveyer and seat belts,
parachutes, racket strings, ropes and nets, sleeping bags,
tarpaulins, tents, thread, monofilament fishing line, dental floss .
Advantages
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Disadvantages
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Damaged by sunlight.
Build up static electricity.
Oils stains are difficult to remove.
Melts in fire.
Low ironing temperature is required.
ACRYLIC FIBRE
ACRYLIC YARN
PHYSICAL PROPERTIES
ACRYLIC
TENSILE STRENGTH
(GRAMS/DENIER) DRY
2.5 4.0
TENSILE STRENGTH
(GRAMS/DENIER) WET
2.0-3.5
BREAKING ELONGATION
(PERCENT) DRY
20-55
BREAKING ELONGATION
(PERCENT)-WET
26-60
SPECIFIC GRAVITY
1.16 1.18
235 255
DECOMPOSES
18.2
SOFTENING POINT
MELTING POINT
LIMITING OXYGEN INDEX (%)
PRODUCTION OF ACRYLIC
FIBRE
BUKLY
FASTNESS TO LIGHT
DURABILITY
LIGHT
WEATHER RESISTANCE.
DURING THE LAST 5-YEAR PERIOD ENDED 2005, ASF PRODUCTION HAS
INCREASED AT A RATE OF 1.25% PER ANNUM, THE SLOWEST GROWTH
RATE AMONG ALL CHEMICAL FIBRES PRODUCTION.
POLYESTER
INTRODUCTION
The name "polyester" refers to the linkage of several monomers (esters) within
the fiber
Polyester is the general name for any group of widely used synthetic products.
Polyesters are strong, tough materials that are manufactured in a variety of
colours, shapes and sizes. . Polyester fibers are the first choice for apparel and
are used in trousers, skirts, dresses, suits, jackets, blouses and outdoor clothing
Blends with cotton and virgin wool are very popular. They are often referred to
as the "classical blend". This is normally a combination of 55% polyester and
45% wool.
History
Structure
Manufacturing
Properties
Applications
Maintenance and Care
HISTORY
Polyester was put on the back burner, however, once Carothers discovered nylon. A
group of British scientists--J.R. Whinfield, J.T. Dickson, W.K. Birtwhistle, and C.G.
Ritchie--took up Carothers' work in 1939. In 1941 they created the first polyester fiber
called TERYLENE. In 1946 duPont bought all legal rights from the Brits and came up
with another polyester fiber which they named DACRON.
Polyester was first introduced to the American public in 1951. It was advertised as a
miracle fiber that could be worn for 68 days straight without ironing and still look
presentable.
In 1958 another polyester fiber called KODEL was developed by Eastman Chemical
Products, Inc. Today, polyester is still widely regarded as a "cheap, uncomfortable"
fiber, but even now this image is slowly beginning to change with the emergence of
polyester luxury fibers such as POLYESTER MICRO FIBER.
STRUCTURE
STRUCTURE
MANUFACTURING PROCESS
Most polyester is made from petroleum from which the constituent acids and
alcohols are derived.
PET is made by reacting ethylene glycol with either terephthalic acid or its
methyl ester in the presence of an antimony catalyst. The reaction is carried
out at high temperature and vacuum to achieve the high molecular weights
need to form useful fibers. PET is melt spun.
SYNTHESIS OF POLYESTER
1) POLYMERIZATION
Condensation polymerization occurs when the acid and alcohol are reacted in a
vacuum at high temperatures. The polymerized material is extruded in the form of a
ribbon onto a casting trough or cooling wheel. After the ribbon hardens, it is cut into
chips.
2) SPINNING
The chips are dried and then put into hopper reservoirs for melting. Polyester is a
"melt spun" fiber, which means that it is heated, extruded through the spinnerets, and
cools upon hitting the air. From there it is loosely wound around cylinders.
3) DRAWING
The fibers are then hot stretched until they are about five times their original length in
order to decrease their width. The fiber is then wound onto cones as filaments or is
crimped and then is cut into staple lengths.
SYNTHESIS OF POLYESTER
1) ADDING A DELUSTERANT -Polyester is a naturally bright fiber, but can be made dull or
semi-dull by the addition of a delusterant.
2) CHANGING THE SHAPE OF THE SPINNERET -The simplest and most common shape is
a circle, but by changing the shape of the spinneret, square, oval, and bean-shaped fibers can
be formed. One can even create a hollow fiber. The different shapes affect the hand and
strength of the fiber.
3) DRAWING IT OUT MORE- Drawing out the fiber to five times its original length is normal,
but polyester can be stretched even further to create the now-popular micro fiber. Drawing it
out may also affect the strength, elasticity, and dye ability.
4) ADDING DYE- In its natural state, polyester is a slightly transparent off-white. Adding dye at
the manufacturing stage can create brilliant colors like electric blue and atomic red.
5) CRIMPING - When the fiber is drawn out it is long and smooth. Crimping can give the fiber
more texture and bulk and can increase its insulation properties, as well as its elasticity.
MAKING YARNS
After the fiber itself is created, it is made into a yarn. There are two types of polyester
yarns
Filament yarns are made by taking the long polyester filaments, grouping them together,
and then twisting them to make them thicker and stronger.
A monofilament yarn has just one, long polyester fiber that is not twisted.
Spun yarns are produced in much the same way that a cotton or wool yarn is produced.
The long filaments are fist cut into short pieces called staples.
These are then combined together and spun to create a yarn made up of thousands of
short filaments.
BLENDS
At this stage, polyester can also be combined with other fibers to produce a variety of effects.
Polyester and cotton is probably the most famous and popular blend. The polyester helps
the fabric retain its shape and resist stains and wrinkles. The cotton makes the fabric more
absorbent and comfortable.
Polyester is combined with wool to give it wrinkle-resistance and shape retention in all
kinds of weather. Since polyester is stronger than wool, it increases the durability and life of
the fabric. The wool contributes good draping characteristics and elasticity.
Polyester and rayon is another popular blend fabric. Here again the polyester makes the
fabric more resilient and durable, and helps it keep its shape. The rayon adds a different
texture, has a good hand, is good for draping, and is absorbent.
Polyester and nylon produce a strong fabric because of nylon's strength and abrasion
resistance and polyester's wrinkle-free properties. This combination produces a yarn that is
strong, durable, stable, easy to launder, and resistant to mildew and insects.
Problems with this blend, however, are that pilling may occur, and it does not have a very
good hand. Furthermore, since neither nylon nor polyester is very absorbent, the fabric may
feel wet and clammy in warm or humid weather
WEAVING:
After the yarns are made, they are shipped out to textile mills to be
woven into fabric. Polyester can be made into both woven and knitted
fabrics.
FINISHING PROCESSES
Finally, after the fabric is made, one or more of the following finishing processes is
often used to improve the quality of the fabric:
Water and stain repellency - increases comfort and makes it easier to clean; also
used for rainwear
PROPERTIES
PHYSICAL PROPERTIES:
PROPERTIES
CHEMICAL PROPERTIES
PROPERTIES
MISCELLANEOUS PROPERTIES:
POLYESTER FIBER
CHARACTERISTICS
Strong
Resistant to stretching and shrinking
Resistant to most chemicals
Crisp and resilient when wet or dry
Wrinkle resistant
Mildew resistant
Abrasion resistant
Easily washed .
It is Polyester fibres are particularly resistant to light and weather and
can withstand climatic effects.
They can be used where lightness and fineness are primary
requirements.
Polyester fibres have good moisture transport and dry quickly.
They are easy care.
High tenacity ensures above-average wear qualities.
Other Uses: Fancy yarn, power belting, ropes and nets, thread, tire
cord, auto upholstery, sails, floppy disk liners,thermal bonding and
fiberfill for various products including pillows and furniture
MAINTAINENCE
OLEFIN
INTRODUCTION
Olefin fiber is a manufactured fiber in which the fiber-forming substance is any longchain synthetic polymer composed of at least 85% by weight of ethylene, propylene, or
other olefin units.
Olefin fiber is a generic description that covers thermoplastic fibers derived from olefins.
Polypropylene (PP) and polyethylene (PE) are the two most common members of the
family.
Since its introduction into the textile industry in the 1950s, the list of successful products
and markets for polypropylene fiber has increased exponentially
OLEFIN FIBER
CHARACTERISTICS
Able to give good bulk and cover
Abrasion resistant
Colorfast
Quick drying
Low static
Resistant to deterioration from chemicals, mildew, perspiration, rot and
weather
Thermally bondable
Stain and soil resistant
Strong
Sunlight resistant
Dry hand; wicks body moisture from the skin
Very comfortable
Very lightweight (olefin fibers have the lowest specific gravity of all fibers)
FIBER STRUCTURE
The speculates developed from a nucleus can range in size from fractions of a
micrometer to centimeters in diameter.
The a-axis of the crystal unit cell is aligned radically and the chain axis is
homogeneously distributed in planes perpendicular to this radial direction.
Consumption
0.5
0
Year
1998
1999
2000
Year
2001
2005
PROCESSING METHODS OF
POLYOLEFINS
There are six important processing methods for Polyolefins, these are:
Injection molding
Rotational molding
Blow molding
Extrusion
MANUFACTURE OF PP FIBER/FILAME
Polypropylene chips can be converted to fiber/filament by traditional melt
spinning, though the operating parameters need to be adjusted
depending on the final products. Spunbonded and melt blown processes
are also very important fiber producing techniques for nonwovens .
PROPERTIES OF
POLYPROPYLENE
CRYSTALLINITY OF PP FIBER
MECHANICAL PROPERTIES
THERMAL PROPERTIES
DYEABILITY
OTHER PROPERTIES OF PP
In general, PP fiber has excellent chemical resistance to acids and alkalis, high
abrasion resistance and resistance to insects and pests. PP fiber is also easy to
process and inexpensive compared to other synthetic fibers. Its low moisture
absorption helps aid the quick transport of moisture.
Home Furnishings: Indoor and outdoor carpets; carpet backing; upholstery and
wall coverings; furniture and bedding construction fabrics
PRODUCTS
APPLICATIONS
If fabric is laundered, it should be line dried or tumble dried with gentle heat
or no heat. Olefin dries very rapidly.
Do not iron. (For specific instructions, refer to garment's sewn-in care label.)
THANK
YOU.