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Source Models
Introduction
Liquid Discharge
Vapor Discharge
Flashing Liquids
Liquid Pool Evaporation or Boiling
Loss of containment
Rupture or break in pipeline
Hole in a tank or pipeline
Runaway reaction
Fire external to vessel
Flammable/Toxic
Models
TNT Equivalency
Multi-Energy Explosion
Fireball
Selection of Fire
Selection of
Results
& Explosion Model
Effect Model
Blast overpressure
Radiant heat flux
Escape
Emergency Response
Mitigation Factors
Containment dikes
PPE
Response vs dose
Probit model
Toxic response
No. of individuals affected
Property damage
Consequence Model
3
Introduction
Spills of materials can lead to disaster
toxic exposure
fire
explosion
Materials are released from holes, cracks in
various plant components
tanks, pipes, pumps
flanges, valves
Source models represent the material
release process provision of useful
information for determining the consequences
of an accident
rate of material release
total quantity released
4
Source Models
Release Mechanisms
Classified into wide and limited aperture
releases.
Wide aperture large hole develops and substantial
amount of material released in a short time.
E.g. overpressure and explosion of a storage tank.
Limited aperture material is released at a slow rate
that upstream conditions are not immediately
affected.
E.g. Release from cracks, leaks etc
Relief system is designed to prevent over-pressure
6
Released of vapour
8
Liquid Discharge
Flow of Liquid through a Hole
A mechanical energy balance describes the various energy
forms associated with flowing fluids:
dP
u
2 g
g z F Ws
g
m
c
where
P is the pressure (force/area)
is the fluid density (mass/volume)
is the avg. instantaneous velocity of the fluid (length/time)
gc is the gravitational constant (length mass/force time)
is the unitless velocity profile correction factor with the
following values: (0.5 for laminar flow), (1.0 for plug flow),
(>1.0 for turbulent flow)
z is the height above datum (length)
F is the net frictional loss term (length force/mass)
Ws is the shaft work (force length)
m is the mass flow rate (mass/time)
10
Liquid Discharge
Flow of Liquid through a Hole
Typical simplification on the mechanical energy balance
dP P
Incompressible Fluid - Density is constant
No elevation difference (z = 0)
No shaft work, Ws = 0
Liquid Discharge
Flow of Liquid through a Hole
Equation for velocity of fluid exiting the leak through a
small hole:
u Co
2 g c Pg
Qm uA ACo 2 g c Pg
The total mass of liquid spilled depends on the total
time that the leak is active.
12
Liquid Discharge
Flow of Liquid through a Hole
The discharge coefficient Co is a function of
the Reynolds number of the fluid escaping the
leak and the diameter of the hole
As a guideline;
For sharp-edge orifices and Re > 30,000, Co ~ 0.61.
The exit velocity is independent of the hole size.
For well rounded-nozzle, Co = 1
For short pipe attached to vessel with length to
diameter ratio < 3, Co = 0.81.
When Co is unknown, use Co = 1 to maximise the
computed flows.
13
4
4
3.41 10 4 ft
3.41 10 4 ft 0.61
lb
ft lbm
lb
in
100 f 144
( 2 ) 54.9 m 32.17
3
lb f s
in
ft
ft
1.48 lbm
s benzene spilled is
The total quantity of
1090 gallons
Liquid Discharge
Flow of Liquid through a Hole in a
Tank
Liquid Discharge
Flow of Liquid through a Hole in a
Tank
Equation for instantaneous velocity of fluid exiting the
leak :
u Co
g c Pg
ghL
2
Qm u A ACo
g c Pg
ghL
2
18
Liquid Discharge
Flow of Liquid through a Hole in a
Tank
Co A 2 g c Pg
g Co A
o
hL h
2 ghL t
t
At
2 At
o
L
Qm u A ACo
g c Pg
o
gCo2 A2
2
ghL
t
At
19
Liquid Discharge
Flow of Liquid through a Hole in a
Tank
The time te for the vessel to empty to the level of the
leak is found;
1 At
te
Co g A
2 g c Pg
g c Pg
o
2
ghL
1 At
te
Co g A
2 ghLo
20
(0.8794)(62.4l b m ft 3 )
54.9 lb m ft 3
d (3.14)(8ft )
At
50.2ft
4
The area of the leak4is
(3.14)(1in )(1ft 144in )
3
A
5
.
45
10
ft
The gauge pressure is 4
Pg (1atm)(14.7 lb f in )(144 in ft ) 2.12 10 3 lb f ft
1 At
Co g A
2 g c Pg
1
50.2 ft
( 0.61 )( 32.17 ft s) 5.45 10 3 ft
ft.lb m
2 32.17
lb f .s
2484 ft
2.12 10
lb
54.9 m
ft 3
g c Pg
o
2
ghL
lb f
ft
ft
2 32.17
12 ft
s
Qm AC o
g c Pg
o
2
ghL
Vapour Discharge
Flow of Vapour through a Hole
Gas and vapour discharges are classified into throttling
and free expansion releases.
For throttling releases, the gas issues through a
small crack with large frictional losses; very little of
energy inherent with the gas pressure is converted
to kinetic energy.
For free expansion releases, most of the pressure
energy is converted to kinetic energy; the
assumption of isentropic behaviour is usually valid.
Source models for throttling releases require detailed
information on the physical structure of the leak; they
will not be considered here. Free expansion release
source models require only the diameter of the leak.
25
Vapour Discharge
Flow of Vapour through a Hole
Vapour Discharge
Flow of Vapour through a Hole
The mass flow rate is given by the following
expression:
1
2/
2gc M P
P
QM C0 AP0
Rg T0 1 P0
P
CP CV
The above expression describes the mass flow
rate at any point during the isentropic
expansion
27
Vapour Discharge
Flow of Vapour through a Hole
For safety studies, the maximum flow rate of vapour
through the hole is required
Pressure ratio resulting in the maximum flow through the
hole or pipe is given by the
Pchoked 2
Po
1
( 1 )
Vapour Discharge
Flow of Vapour through a Hole
Gas Pressurized within
Process Unit
External Surroundings
P < P choked
Po
To
At Throat:
U0=0
P = Pchoked
U = Sonic Velocity
Vapour Discharge
Flow of Vapour through a Hole
Vapour Discharge
Flow of Vapour through a Hole
At the choked condition, the flow is maximum:
QM choked
C0 AP0
gc M
RgT0
32
d
4
5.45 10
ft 2
1 1
2.4
2.4 0.4
0.833
6.00
0.335
Qm choked Co APo g c M 2
R g To 1
1545 ft.lb
1.685lb f
Qm choked
lb f .s 28 lbm lb.mole
o
lb.mole R 540 R
2
2
5.064 10 4 lb m
lb 2
.s
f
3.79 10 2 lbm s
0.335
Flashing Liquid
Liquids stored under pressure above their
normal boiling point temperature present
substantial problems because of flashing.
If leak, the liquid will partially flash into
vapor, sometimes explosively.
Flashing occurs so rapidly that the process is
assumed to be adiabatic.
The fraction of the liquid vaporized is;
mv C p (T0 Tb )
fv
m
H v
36
Flashing Liquid
The fraction of the liquid vaporized can also be
determined using mean heat capacity and
mean latent heat of vaporization over the
temperature range To to Tb;
C p (T0 Tb )
mv
fv
1 exp
m
H v
37
Flashing Liquid
Two-phase flow conditions may be present for
flashing liquids escaping through holes and
pipes.
If the fluid path length of the release is short
(through a hole in a thin wall container), nonequilibrium conditions exist, and the liquid does
not have time to flash within the hole; the fluid
flashes external to the hole. The fluid (liquid)
flow through hole applies;
Qm uA ACo 2 g c Pg
38
Flashing Liquid
If the fluid path length through the
release is greater than 10 cm (through a
pipe or thick-walled container),
equilibrium flashing conditions are
achieved and the flow is choked. A good
approximation is to assume a choked
pressure equal to the saturation vapor
pressure of the flashing liquid. This
condition valid for liquids stored at a
pressure higher than the saturation vapor
pressure (P > P sat). The following
equations
sat
apply; Qm ACo 2 f g c P P
39
Flashing Liquid
For liquids stored at their saturation pressure P
= P sat, the mass flow rate is determined by;
H v A g c
Qm
v fg
TC p
40
Rg TL
Rg TL
41
KATP sat
106
kQv PTL
M
Ko = 0.83 cm/s for water
42
Qm
H v
qg
st
1/ 2
43
Conclusion
Source models represent the material
release process - information for determining
the consequences of an accident
The purpose of the source model is to
determine:
The form of material released, solid, liquid or
vapour;
The total quantity of material released; and
The rate at which it is released.
These information is required for any
quantitative dispersion model study.
Two types of release
aperture release &
mechanisms: wide
limited aperture
44
Thank you
for your attention.
45
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