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Rp
. cm2
0
250
14
35
1000
143
0.152
1.76
90
5000
223
0.097
1.13
94
CLASSIFICATION OF INHIBITOR
The reduction
potential of
chromate ion
to solid Cr2O3
is possible to
increase the
corrosion
potential of
steel into its
passivation
region but not
for molybdate
and tungstate.
NO2-+8H++6e = NH4++2H2O
6Fe(OH)2 = 2Fe3O4+4H2O+4H++4e2Fe3O4+H2O=3(-Fe2O3)+2H++2e2H2O = 2H++ 2OH6Fe(OH)2+NO2-=3(Fe2O3)+NH4++3H2O+2OHSodium nitrite is more effective in suppressing the
aggressive properties of chlorides than are benzoate
and chromate. In the presence of sulfate, nitrate is
slightly less effective than are chromate and
benzoate.
CNaNO2
%mass %mass
CNaNO2
T, hr
CNaCl
0.5
0.20
0.4
20.5
0.5
0.35
0.7
49.5
0.5
0.5
0.45
1.00
0.9
2.0
Pot.
mV
-11
State of
metal
surface
corrodes
+271 protected
Chromate-base inhibitors are the leastexpensive inhibitors and were used until
recently in a variety of application (e.g.
recirculation cooling systems of internal
combustion engines, refrigeration units
and cooling towers). Sodium chromate,
typically in concentrations of 0.04 to 0.1%
was used for this applications. At higher
temperatures or in fresh water with
chloride concentration above 10 ppm,
higher concentration are required. If
necessary, sodium hydroxide is added to
adjust the pH to a range of 7.5 9.5. If
the concentration of chromate falls below
a concentration of 0.016% corrosion will
be accelerated.
Cathodic Inhibitors
Organic Inhibitors
Precipitation Inhibitors