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Chapter 16
CH3COOH (aq)
common
ion
16.2
16.3
16.3
0.30
0.00
0.52
-x
+x
+x
0.30 - x
0.52 + x
x = 1.038 X 10 -4
pH = 3.98
[HCOOH]
16.2
HA (aq)
H+ (aq) + A- (aq)
Ka [HA]
[H ] =
[A-]
Ka =
[H+][A-] pK = -log K
a
a
[HA]
[HA]
[A-]
[A
]
-log [H ] = -log Ka + log
[HA]
+
Henderson-Hasselbach
equation
[conjugate base]
pH = pKa + log
[acid]
[A
]
pH = pKa + log
[HA]
16.2
0.30
0.00
0.52
-x
+x
+x
0.30 - x
0.52 + x
[HCOO
]
pH = pKa + log
[HCOOH]
[0.52]
= 4.01
pH = 3.77 + log
[0.30]
HCl
HCl + CH3COO-
H+ + ClCH3COOH + Cl-
16.3
[NH4+] [OH-]
[NH3]
Initial
Change
End
= 1.8 X 10-5
0.30
-x
0.30 - x
0.36
+x
0
+x
0.36 + x
(.36 + x)(x)
1.8 X 10-5 =
1.8 X 10
-5
(.30 x)
0.36x
0.30
x = 1.5 X 10-5
pOH = 4.82
pH= 9.18
16.3
start (M)
end (M)
Ka=
0.01
0.29
NH4+ (aq) + OH- (aq)
0.28
0.0
[H+] [NH3]
= 5.6 X 10 -10
[NH4+]
[H+] 0.25
0.28
0.24
H2O (l) + NH3 (aq)
0.25
-10
pH = 9.20
16.3
pKa = 9.25
[0.30]
pH = 9.25 + log
= 9.17
[0.36]
0.01
0.29
NH4+ (aq) + OH- (aq)
0.28
0.0
0.24
H2O (l) + NH3 (aq)
0.25
[0.25]
pH = 9.25 + log
= 9.20
[0.28]
16.3
16.3
Titrations
In a titration a solution of accurately known concentration is
added gradually added to another solution of unknown
concentration until the chemical reaction between the two
solutions is complete.
Equivalence point the point at which the reaction is complete
Indicator substance that changes color at the
endpoint (hopefully close to the equivalence point)
Slowly add base
to unknown acid
UNTIL
The indicator
changes color
(pink)
4.7
100%
ionization!
No equilibrium
16.4
16.4
NH4Cl (aq)
NH4Cl (aq)
16.4
Acid-Base Indicators
16.5
pH
16.5
16.5
16.5
0.05
0.00
0.00
-x
+x
+x
Equilibrium (M)
0.05 - x
x2
[OH-][HNO2]
-11
=
2.2
x
10
Kb =
=
[NO2-]
0.05-x
pOH = 5.98
pH = 14 pOH = 8.02
Co(H2O)62+
CoCl42-(aq)
CoCl24
16.10
16.10
Common Ligands
Ligands
H2O
aqua
NH3
ammine
OHClBrCNSCN-
hydroxy
chloro
bromo
cyano
thiocyanato (bonded through
sulphur)
isothiocyanato (bonded through
nitrogen)
Names
Names: ligand first, then cation
Examples:
tetraamminecopper(II) ion: Cu(NH3)42+
diamminesilver(I) ion: Ag(NH3)2+.
tetrahydroxyzinc(II) ion: Zn(OH)4 2-
Coordination Number
Total number of bonds from the ligands
to the metal atom.
Coordination numbers generally range
between 2 and 12, with 4
(tetracoordinate) and 6 (hexacoordinate)
being the most common.
Lewis
base/ligand
coordination
number
Ag(NH3)2+
NH3
Ag+
[Zn(CN)4]2-
CN-
Zn2+
[Ni(CN)4]2-
CN-
Ni2+
[PtCl6] 2-
Cl-
Pt4+
Cl
Ni2+
[Ni(NH3)6]2+ NH3