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BENZENE AWARENESS
PREPARED BY: YASREF SAFETY TEAM
Benzene
Learning Objective?
What is Benzene?
What are its Properties ?
Where it might be found generally and at Yasref Facilities?
Who might be exposed?
Hazards of benzene
Potential Health effects
Exposure limits
Control Measure (How to protect yourself from benzene)
Health Monitoring and Surveillance
Air Monitoring
WISHA rules on benzene
Benzene
Benzene is organic chemical compound which is a
colorless and flammable liquid with a pleasant, sweet smell.
Chemical formula C6H6
Other name Benzol or Benzole (In Europe), Coal
Naphtha, Phene, Phenyl Hydride, Pyrobenzol.
It is a component of gasoline. It is an important industrial
solvent and precursor in the production of drugs, plastics,
gasoline, synthetic rubber, and dyes.
Benzene is a natural constituent of crude oil, but it is
usually synthesized from other compounds present in
petroleum.
Benzene is an aromatic hydrocarbon, and the second [n]annulene ([6]-annulene).
Benzene - Properties
Physical and Chemical
o Systematic name Benzene
o Molecular shape Planar
o Dipole moment 0 D
o Molar mass 78.11 g/mol
o Appearance Colorless liquid
o CAS number [71-43-2]
o Density and phase 0.8786 g/cm
o Solubility in water 1.79 g/l (25 C)
o Melting point 5.5 C (278.6 K)
o Boiling point 80.1 C (353.2 K)
o Viscosity 0.652 cP at 20 C
o Burns with sooty flame.
BEU
CCR
Tankfarm
Laboratory
NGL-Berth 71 &72
Benzene - Hazards
A. Fire, Explosion & Reactivity
.Fire
o. Flash Point (closed cup): - 11 deg. C (12 deg. F)
o. Autoignition Temperature: 580 deg. C (1076 deg.
F)
o. Flammable limits in Air. % by Volume: Lower:
1.3%, Upper: 7.5%
o. Extinguishing Media: Carbon dioxide, dry
chemical, or foam.
Benzene - Hazards
Explosion
o A concentration exceeding 3,250 ppm is considered a potential fire
explosion hazard
Benzene - Hazards
Reactivity/Stability
o Chemical Stability: Normally stable.
o Conditions to Avoid: Open flames, sparks, static discharge, heat
and other ignition sources.
o Incompatible Materials: Reacts explosively with: halogens (e.g.
chlorine). Increased risk of fire and explosion on contact with: nitric
acid, oxidizing agents (e.g. peroxides).
o Corrosive : non corrosive o carbon steel, aluminum alloys.
o Hazardous Decomposition Products: Very toxic carbon
monoxide, carbon dioxide; very toxic, flammable aldehydes; and
other chemicals.
o Possibility of Hazardous Reactions: None known.
Benzene - Hazards
B. Toxicity
VERY TOXIC
CANCER
HAZARD
MUTAGEN
ASPIRATION
Hazard
IRRITANT
o Skin Contact
o Skin Absorption
o Eye Contact
Skin Contact:
TWA 8 hrs.
2.5 PPM
STEL 15 minutes
PEL-OSHA
1 PPM
TWA- 8 hrs.
STEL-OSHA
5 PPM
STEL 15 minutes
Warning Signs
Warning signs are posted at the entrance
to any area where the levels of benzene
exceed the OSHA permissible limits.
All containers containing benzene also
have a warning label.
Air Monitoring
MATERIALS IN
SYSTEM
POTENTIAL PHYSICAL HAZARDS
BARRICADING AS REQUIRED
FIRST AID IF EXPOSED
LOCATION OF SAFETY EQUIPMENT
PPE REQUIRED FOR LINE BREAK
Using Respirators
Respirators must be worn at
all times when the amount
of benzene in the air is
above the permissible limit.
Respirators must fit properly
to prevent leaks.
You must have a medical
evaluation before you wear
a respirator.
Respirators required at
this worksite
Medical Monitoring
What medical monitoring is needed?
A medical exam is made available
to you if you are exposed to
benzene above 0.5 ppm 30 days or
more per year, or above 1 ppm
more than 10 days per year.
The medical exam includes a
complete physical exam and blood
tests.
The medical exam is made
available to you before you start
working around benzene and yearly
Link to contents of medical evaluati
after that.
on
Records
Medical and Air Monitoring Records
You have the right to
see any of your medical
records related to
benzene.
You also have the right
to see results of any air
sampling for benzene
we have done.
Benzene Regulations
The OSHA benzene
regulations contains
much more information in
detail.
A copy of this standard is
available.