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Atoms
Radioactivity
Half-Life
Atoms
An atom is the smallest particle of
an element that has all of the
properties of that element.
Subatomic Particles
Subatomic
Particle
Proton
Symbol
p,
+
Electron
e-,
Neutron
n,
Charge
Location
in Atom
Mass
Positive
in the
nucleus
1.67310-24 g
Negative
outside of
the nucleus
9.10910-28 g
Neutral
in the
nucleus
1.67510-24 g
Particle
Mass (amu)
Proton
1.007276 1
Neutron
1.008665 1
Electron
0.0005486
Charge of an Atom
Atoms are electrically neutral.
The number of protons in an atom
equals the number of electrons.
Ions
Ions are formed when an atom gains or
loses electrons.
anion negatively charged ion formed
when an atom gains electrons
cation positively charged ion formed
when an atom loses electrons
We will talk more about ions later this
year.
Atomic Number
determined by the number of
Mass Number
equal to the sum of the neutrons
Beryllium-9
Determine the number of neutrons in
Argon-40.
Nuclear
Symbol
Atomic
Mass
Number Number
Sodium -22
11
22
11
11
11
Fluorine-19
19
10
Bromine-80
35
80
35
45
35
Calcium-40
20
40
20
20
20
Hydrogen-1
Isotopes
All atoms of the same element
have the same number of protons,
but the number of neutrons may
vary.
Isotopes are atoms of the same
element which have different
numbers of neutrons.
Nuclear
Symbol
Number
of
Protons
Number
of
Electrons
8
8
8
8
8
8
Number
Mass
of
Number
Neutrons
8
9
10
16
17
18
Mass
(amu)
15.99415
16.999131
17.999160
Example Problem
Isotope
Atomic Mass
Oxygen 16
Oxygen 17
Oxygen 18
15.99415 amu
16.999131 amu
17.999160 amu
Percent
Abundance
99.762%
0.038%
0.200%
= 15.95608 amu
16.999131 amu x
= 0.0064597 amu
17.99160 amu
= 0.03598 amu
Mass (amu)
Percent
Abundance
Mass Number
19.99244
90.51
20
20.99395
0.27
21
21.99138
9.22
22
= 18.09515744 amu
20.99395 amu
= 0.056683665 amu
21.99138 amu
= 2.027605236 amu
Discovery of
Radioactivity
Radioactivity was accidently discovered in
1896 by the French chemist Henri Becquerel.
Becquerel was studying the properties of
fluorescent materials, substances that glow in
the dark having been exposed to light. On one
occasion, Becquerel placed the minerals he
was studying along with some unexposed
photographic film in a laboratory drawer.
When he retrieved the film on a later date, he
found that it was foggy.
Discovery of
Radioactivity
Upon further investigation, Marie Curie
and her husband Pierre, were able to
determine that the fogginess was caused
by rays emitted by the uranium in the
mineral samples. Marie Curie named the
process by which materials give off such
rays radioactivity; the rays and particles
emitted by a radioactive source are called
radiation.
nonionizing radiation.
Radioisotopes
Radioisotopes are isotopes that are
radioactive because they have unstable
nuclei.
Nuclear Stability
The stability of the nucleus depends upon its ratio of
neutrons to protons. Too many or too few neutrons lead
to an unstable nucleus.
When the number of protons in stable nuclei is plotted
against the number of neutrons, a beltlike graph is
obtained. This stable nuclei cluster over a range of
neutron-proton ratios is referred to as the band of stability.
Stable isotopes fall within the band of stability and have
neutron to proton ratios of nearly 1:1 at the lower range
and nearly 1.5:1 at the upper range. Such isotopes
tend to be stable. Radioactive isotopes fall outside of the
band of stability.
Band of Stability
Would you expect Helium-4
to be a stable isotope? Why
or why not?
Yes, the neutron to proton
ratio is 1:1. (falls within the
band of stability)
Would you expect Carbon14 to be a stable isotope?
Why or why not?
No, the neutron to proton
ratio is 1.3:1 (falls above the
band of stability)
Alpha
Beta
beta particles
alpha particles
Composition
(electron)
(helium nucleus)
4
He
2
Symbol
Mass
Electric
Charge
0
e
-1
-1
Gamma
form of
electromagnetic
radiation
0
or
4 amu
nearly 0 amu
(0.0055 amu)
0 amu
2+
1-
stopped by
stopped by
Electron Capture
Electron capture ( ) occurs when
an inner orbital electron is captured
by the nucleus of its own atom.
The inner orbital electron combines
with a proton and a neutron is
formed.
Electron capture also occurs in
atoms with too many protons.
Electron Capture
Describe the change in the mass number.
The mass number stays the same.
Describe the change in atomic number.
The atomic number decreases by 1.
What happens to the neutron to proton ratio?
The neutron to proton ratio increases.
1.
2.
3.
4.
+
+
beta decay
electron capture
alpha decay
positron emission
2.
3.
4.
Decay Series
Write the series of reactions that
represent the decay series for
uranium-238.
Transmutation
Transmutation conversion of an atom of one element
to an atom of another element.
Transmutation may occur through radioactive decay.
Induced Transmutation may also occur when high
energy particles (protons, neutrons, or alpha
particles) bombard the nucleus.
Transuranium elements elements in the periodic table
with atomic numbers above 92. These elements have
been synthesized in nuclear reactors and nuclear
accelerators; which accelerate the bombarding particles
to very high speeds.
Transmutation
The nuclear equation for the induced
transmutation of aluminum-27 into
phosphorus-30 by alpha particle
bombardment is written below.
Write the balanced nuclear equation for the induced transmutation of aluminum-27
into sodium-24 by neutron bombardment. An alpha particle is released in the
reaction.
Nuclear Fusion
In nuclear fusion, light nuclei combine to form
a heavier, more stable nucleus.
Nuclear fusion occurs in the sun where
hydrogen nuclei fuse to make helium nuclei.
Nuclear Fission
In nuclear fission, fissionable isotopes split
when bombarded with neutrons.
The isotopes release
neutrons that cause a
chain reaction.
Half-Life
Todays Objectives
1.Define half-life and calculate
the half-life of certain isotopes.
2.Use half-life information to
determine the amount of a
radioisotope remaining at a
given time.