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Large-scale battery
Li
Na
Almost-infinite resource
Oxidative feature is
not completely clear
Anode
Material
Synthesis
Method
2013
ChemCo
mm
Fe2O3@GN
S
Ethonaldispersion
+
Cacilnation
80:20
(AM:PVDF)
1 M NaPF6
EC: DMC
(1:1)
2014
JPS
g-Fe2O3/
a-Fe2O3
Heat
pyrolysis
65:20:15
(AM:CB:CMC)
2015
CM
-FeOOH
(Nanorods)
Thermal
hydrolysis
microwave
2015
Ele. Acta
Fe2O3-RGO
Anode
Composition
Electrolyte
Capacity
Cycle-life
Retention
350
400
(200 mA/g)
(10 nd)
(100 mA/g)
(200 cycles)
1MNaClO4
EC:DEC
(2:1)
300
280
(130 mA/g)
(2 nd)
(130 mA/g)
(60 cycles)
50:30:5:15
(AM:G:Sp:CM
C)
1 M NaClO4
PC/5 wt%
FEC
523
200
(80 mA/g)
(2 nd)
(500 mA/g)
(100 cycles)
80:10:10
(AM:Sp:PVDF)
1 M NaClO4
EC:PC (1:1
w:w)
250
300
(100 mA/g)
(50 mA/g)
(50 cycles)
150
145
(20 mA/g)
(2 nd)
(20 mA/g)
(40 cycles)
450
300
(100 mA/g)
(2 nd)
(100 mA/g)
(200 cycles)
2015
Ele. Acta
Fe2O3
MCMB
Spex-milling
80:10:10
(AM:Sp:PVDF)
1M
NaClO4EC:DMC
(1:1 w:w)
2015
JMCA
a-Fe2O3
@TiO2
(Core-shell)
Thermal
hydrolysis
70:20:10
(AM:AB:PVDF)
1 M NaClO4
/PC
2015
JMCA
a-Fe2O3
(Core-shell)
Hydrotherma
l
75:15:10
(AM:AE:LA
132)
1 M NaPF6
EC/DEC
(V/V=1/1)
733
(6000 mA/g)
300
2015
JPS
a-Fe2O3/
(rGO)
Hydrotherma
l
80:15:5
(AM:CB:CMC)
1 M NaClO4
EC/DEC
1170
370
(37 mA/g)
(1 st)
(100 mA/g)
(150 cycles)
300
200
2015
1 M NaClO4
(100 mA/g)
(80 cycles)
Fe(NO3)39H
2O
Ethanol
200 C for 10 h
GNS
Fe2O3@GNS
40 C for 24 h
Fe(NO3)39H2O/GNS
Fig. 1
(a) Raman spectra of the pristine GNS, Fe2O3, and Fe2O3@GNS,
(b) the Mossbauer spectrum of Fe2O3@GNS.
Cycling performance of
pure GNS at a current of
100 mA/g.
Conclusion (Literature)
(1) GNS builds the electron transport path.
(2) The small size of the active material Fe2O3 significantly
reduces the Na diffusion length.
(3) The active material Fe2O3 anchored onto GNS can
effectively enhance the strain-accommodating capability
and prevent the pulverization of Fe2O3 upon Na-ion
insertionextraction.
Vision
SEI formation mechanism and Fe2O3-graphene-compostie
have been studied.
Fe2O3 nanorods (by-product from hydrothermal synthesis).