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Mechanism of leaching:Extraction involves two steps which are:1- Contacting step:- of solvent and the material to be
Treated, so as to transfer soluble constituent to the
Solvent.
2- Separation step:- of the solution formed from the
relatively exhausted solids.
The above two steps may be conducted in separate
Equipment or in one and the same equipment.
Solution resulting from separation step is termed
Overflow, Solids left over are termed Underflow.
P+Q=R
P x AP + Q x AQ = R x AR
P x BP + Q x BQ = R x BR
P x SP + Q x SQ = R x SR
By using lever arm principle,
the length and amounts
are calculated as follows:PR
Q a
= =
RQ
P b
N-M=K
N x AN - M x AM = K x AK
N x BN - M x BM = K x BK
N x SN - M x SM = K x SK
By using lever arm principle,
the length and amounts
are calculated as follows:NK
M
b'
=
=
MK
N a' + b'
0.32
0.2
0.35
0.3
0.4
0.4
=r=1
x
A+B+S
S r
B
xB
A+B+S
xS
=r
1 - ( x A + xS )
x S = r - r (x A + x S ) = r - r x A + r x S
(1+ r) x S = r - r x A
r
r
x A ( It's a striaght line equation)
1+ r 1+ r
If x S = 0
x A =1
xS =
If x A = 0
x S = 1/2
Methods of Operation (Types of contact):1-Simple single stage:Considering a theoretical extraction stage where L 0
with composition x0 is brought into contact with a
solvent V0 having composition y0 . The amount L1 and
Composition x1 of the
product underflow as
well as
the amount V1 and
comp. y1
of the overflow are to be
determined.
determ
OMB:- L 0 + V0 = L1 + V1 = M
CMB:- L 0 x 0 + V0 y 0 = L1x1 + V1 y1 = M x M
x 0 , y 0 , x M lies on straight line
and x1 , y1 , x M lies on straight line
y0 x M
L0
a
Q
=
=
x0xM
V0
b
L0
L0
y0 x M
a
=
=
=
L 0 +V0 M
y0 x 0
a+b
get a & b
Also:y1x M
L1
d
Q
=
=
x1 x M
V1
c
L1
L1
y1x M
d
=
=
L1 +V1 M
x 1x M
d+c
get L1 &V1
V0 + L 0 = V1 + L1 = M
CMB:-
V0 y 0 + L 0 x 0 = V1 y1 + L1x 1 = M x M1
V0 + L 0 = V2 + L 2 = M
CMB:-
V0 y 0 + L 0 x 0 = V2 y 2 + L 2 x 2 = M x M 2
OMB:- Vn+1 + L 0 = V1 + L n = M
CMB:- Vn+1 y n+1 + L 0 x 0 = V1 y1 + L n x n = M x M
Condition of infinite number of stages:To increase overflow composition the number of stages
must be increased.
the number of stages
increases till reaching
the maximum overflow
composition (y1max).
Steps:Connect yn+1 with (B)
To cut U.F locus in x n min
connect it with xM then
extend the line to cut O.F
in y 1max.
O.F
y n+1 - y n act
=
0.8
*
y n+1 - y n
U.F
xn-1 - x n act
=
0.8
*
xn-1 - x n
or
KgA+Kg S Kg solution
Ib solution
There will be a value of N for the overflow where (N = 0)
and for the underflow N will have different values, depending
upon the solute concentration in the liquid.
The compositions of solute in the underflow& overflow will be
expressed as wt fractions:Kg A
Kg solute
yA =
=
( overflow liquid)
Kg A+Kg S
Kg solution
Kg A
Kg solute
xA =
=
( underflow liquid)
Kg A+Kg S
Kg solution
B
0
, N=
0
A + S 100 0
Pure S = 100% , A = 0 , B = 0
A
0
B
0
x or y =
=
=0 , N=
0
A + S 0 + 100
A + S 0 100
Pure B = 100% , A = 0 , S = 0
A
0
0
B
100
x or y =
=
=
, N=
A+S 0+0
0
A+S
00
Kg inert solid
For the entering solid feed to be leached, N 0 =
Kg solute A
and x 0 = 1.0 . And for pure solvent N n+1 = 0 , y n+1 = 0 .
A typical equilibrium diagram is shown in the
following
Figure.
The lower curve of N vs yA , where N = 0 on the
axis, represents the locus of overflow(where all the
solids has been removed).
The upper curve N vs xA , Represents the locus of
underflow.
The tie lines are vertical, and on x-y diagram, the
Equilibrium line is yA = xA
y0 x M
L '
a
= 0 =
x0xM
V0 '
b
L0 '
L0 '
y0 x M
a
=
=
=
L0 '+V0 ' M
y0 x 0
a+b
get a & b
Also:y1x M
L1 '
d
Q
=
=
x1 x M
V1 '
c
L1 '
L '
yx
d
1 = 1 M =
L1'+V1 ' M'
x1 x M
d+c
Q L0 A + S B
= (A+S) + B
= L0' + B
L0
A+S
L0
L0'
A+S
B
=
+
A+S A+S
= 1 + N0
L0
L0' =
1 + N0
V1
L1
also V1' =
& L1 '
1+N1
1+ N1
OMB:- Vn+1 + L 0 = V1 + L n = M
Vn+1' + L 0 ' = V1' + L n ' = M'
CMB:- Vn+1' y n+1 + L 0' x 0 = V1' y1 + L n ' x n = M' x M
Operating relations:Vn+1' - L n ' V1' L 0' =V2 ' - L1 ' R
Vn+1' y n+1 - L n 'x n =V1'y1 -L 0'x 0 = V2'y 2 - L1'x1 = R x R