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Microscopy
By Lucas Carlson
Reed College
March 2004
ImagefromanSTM
TheScanningTunnelingMicroscope(STM)
TheSTMisanelectronmicroscopethat
usesasingleatomtiptoattainatomicresolution.
History
The scanning tunneling microscope was
developed at IBM Zrich in 1981 by Gerd
Binning and Heinrich Rohrer who shared the
Nobel Prize for physics in 1986 because of
the microscope.
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Gerd Binning
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Heinrich
Rohrer
General Overview
An extremely fine conducting probe is held
about an atoms diameter from the sample.
Electrons tunnel between the surface and the tip,
producing an electrical signal.
While it slowly scans across the surface,
the tip is raised and lowered in order to keep
the signal constant and maintain the distance.
This enables it to follow even the smallest
details of the surface it is scanning.
The Tip
150xMagnification
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Quantum Tunneling
Classical
WaveFunction
ForFiniteSquare
WellPotential
WhereE<V
Classically, when an object hits a potential that
it doesnt have enough energy to pass, it will
never go though that potential wall, it always
bounces back.
In English, if you throw a ball at a wall, it will
bounce back
at you.
Quantum Tunneling
Quantum
WaveFunction
ForFiniteSquare
WellPotential
WhereE<V
In quantum mechanics when a particle hits a
potential that it doesnt have enough energy
to pass, when inside the square well, the wave
function dies off exponentially.
If the well is short enough, there will be a noticeable
probability of finding the particle on the other side.
Quantum Tunneling
The finite square well potential is a good
approximation for looking at electrons on conducting
slabs with a gap between them.
Quantum Tunneling
Moregraphsoftunneling:
n(r)isthe
probabilityof
findinganelectron
V(r)isthepotential
Anelectrontunnelingfromatomtoatom:
Quantum Tunneling
Nowlookingmoreindepthatthecaseoftunneling
fromonemetaltoanother.EFrepresentstheFermi
energy.Creatingavoltagedropbetweenthetwo
metalsallowscurrent.
Sample
Tip
Quantum Tunneling
Throughabarrier,quantummechanicspredictsthatthe
wavefunctiondiesoffexponentially:
Sotheprobabilityoffindinganelectronafterabarrierof
widthdis:
And:
Wheref(V)istheFermifunction,whichcontainsaweighted
jointlocaldensityofstates.Thisamaterialpropertyobtained
bymeasurements.
Quantum Tunneling
Where:
Quantum Tunneling
So if you bring the tip close enough to the surface,
you can create a tunneling current,
even though there is a break in the circuit.
The size of the gap in practice is on the order
of a couple of Angstroms (10-10 m)!
As you can see, the current is VERY sensitive to the
gap distance.
Quantum Tunneling
atomic resolution.
Note
A STM does not measure nuclear position
directly. Rather it measures the electron
density clouds on the surface of the sample.
In some cases, the electron clouds represent
the atom locations pretty well, but not
always.
Small Movements
To get the distance between the tip and the
sample down to a couple of Angstroms
where the tunneling current is at a measurable
level, STMs use feedback servo loops and converse
piezoelectricity.
Servos
Servos are small devices
with a shaft that can be
precisely controlled with
electrical signals.
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Converse Piezoelectricity
Piezoelectricityistheabilityofcertaincrystalsto
produceavoltagewhensubjectedtomechanical
stress.
Whenyouapplyanelectricfieldtoa
piezoelectriccrystal,thecrystaldistorts.Thisis
knownasconversepiezoelectricity.The
distortionsofapiezoisusuallyontheorderof
micrometers,whichisinthescaleneededtokeep
thetipoftheSTMacoupleAngstromsfromthe
surface.
ElectricField
Pizos
Thetip
Thereisnowayaroundthis,tryusinganAFM
Vibration-Isolation
TheoriginalSTMdesignhadthetunnelunitwith
permanentmagnetslevitatedonasuperconductinglead
bowl.Theyused20Lofliquidheliumperhour.
Vibration-Isolation
Thesimpleandpresentlywidelyusedvibrationprotection
withastackofmetalplatesseparatedbyvitonanultra
highvacuumcompatiblerubberspacer.
Original Trace
Si(111)tracetakenin1983.
Processed Trace
Computerprocessedversion
ofthesametraceofSi(111)
Thegrayscalepicturecanbeinterpretedasacontour
map(3)whichcanthenbeaveragedouttomake
smooth(4)andfinallycolored(below).
Uses of STM
Measuringhighprecisionopticalcomponentsanddisk
drivesurfaceroughnessofmachinedorgroundsurfaces
isacommonuseforSTM.
Belowisatraceofanindividualturnmarkona
diamondturnedaluminumsubstratetobeusedfor
subsequentmagneticfilmdepositionforahigh
capacityharddiscdrive.
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1micron
Uses of STM
Bymeasuringvariationsincurrent,voltage,tip/surface
separation,andtheirderivatives,theelectronicpropertiesof
differentmaterialscanbestudied.
Onesuchelementstudiedwasthebuckyball(C60).When
youpressdownonabuckyballby1/10thnm,itlowersthe
resistanceofthebuckyballby100times.
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C.JoachimJ.K.Gimzewski,
"Anelectromechanicalamplifier
usingasinglemolecule,
ChemicalPhysicsLetters,Vol.
265,Nos.35,page353,
February7,1997.
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DifferentSTMIdeas
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References
Carbon
Monoxide
Man
G.BinnigandH.Rohrer."ScanningTunnelingMicroscopy",
IBMJRes.Develop.,30:355,1986.
G.Binnig,H.Rohrer,ScanningTunnelingMicroscopy
FromBirthtoAdolescence,Nobellecture,December8,
1986.
TitWahHui,ScanningTunnelingMicroscopyATutorial,
http://www.chembio.uoguelph.ca/educmat/chm729/STMpage/
stmtutor.htm
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Wikipedia,ScanningTunnelingMicroscope,
http://en.wikipedia.org/wiki/Scanning_tunneling_microscope
Carbon Monoxide on Platinum (111)NobeleMuseum,TheScanningTunnelingMicroscope,
http://www.nobel.se/physics/educational/microscopes/scannin
g/index.html
Picturesfromhttp://www.almaden.ibm.com/vis/stm/blue.html