Академический Документы
Профессиональный Документы
Культура Документы
Boltzman statistics:
Fermi-Dirac statistics:
Bose-Einstein statistics:
Maxwell-Boltzmann statistics:
Problem 13-4: Show that for a system of N particles
obeying Maxwell-Boltzmann statistics, the occupation
number for the jth energy level is given by
ln Z
N j NkT
j
where EJ = EJ (x)
x is an extensive property
such as volume (see eqn
12.21!)
define
Since dQ = TdS
and
dW = PdV = YdX
The equation
could be interpreted as: An increase
in the systems internal energy could be brought by a decrease
in volume with an associated increase in the EJ. the energy
levels are shifted to higher values with no redistribution of the
particles among the levels.
For MB statistics
S k ln(WMB ) k ln( g j )
Nj
ln( N j !)
F U TS NkT (ln Z ln N 1)
N E j kT
e
gj Z
1
e
( E j u )
kT
13.8
Nj
gj
E j u
kT
a = 1 for FD statistics
a = -1 for BE statistics
a = 0 for MB statistics
13-10
(a) using results from chapter 9, show that
S
u T
N U ,V
(b) It follows from the statistical definition of the entropy that
u
ln W
N
kT
Consider a system with a chemical potential u = - 0.3eV. By
what factor is the number of possible microstates of the
system increased when a single particle is added to it at room
temperature?
(k = 8.617 x 10-5 eVK-1)
Solution: (a) using equation 13.53 directly
Chapter 14:
The Classical Statistical
Treatment of an Ideal Gas
1. Internal Energy:
n
U N j j
and
j 1
Nj
N j kT
e
gj Z
N j
N
kT
U
e g j j
Z
j Z
We have
Z g je
j
kT
j g j j e kT
g je
j
kT
j
d
kT
dT
j
1
kT
g
j
j
= kT 2 j
(keeping V constant means (V) is constant)
Therefore,
or
N
2 Z
U (kT )
Z
T
ln Z
U NkT
T
2
g e kT ( ( 1 ))
j j
j
kT 2
2. Gibbs Function
since G = N
G = - NkT (ln Z ln N)
3. Enthalpy
G = H TS
H = G + TS
= U + NkT = NkT2
= NkT (1 + T
+ NkT
)
4. Pressure
F
P
(ln Z ln N 1)
P NkT
(ln Z )
P NkT
0 0
V
(ln Z )
P NkT