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COMPOSITES
Particle Reinforced
Large
Dispersion
Particle Strengthened
Fibre Reinforced
Continuous
(Aligned)
Aligned
Discontinuous
Structural
laminates
(short)
Randomly Oriented
Sandwich
panels
Earliest examples
The most primitive composite materials
comprised straw and mud in the form
of bricks for building construction.
The ancient brick-making process can
still be seen on
Egyptian tomb paintings in the
Metropolitan Museum of Art
Modern composites
The most advanced examples are used
on spacecraft in demanding
environments.
The most visible applications:
roadways in the form of either steel and
portland cement concrete,
Mastic asphalt and asphalt concrete.
Mechanics
A polymer matrix material called a resin or
resin solution.
There are many different polymers available
depending upon the starting raw ingredients.
Broad categories, each with numerous
variations. The most common categories are
known as polyester, vinyl ester, epoxy,
phenolic, polyimide, polyamide, and others.
The reinforcement materials: fibers & ground
minerals.
Fibers transformed into a textile material
such as a felt, fabric, knit or stitched
construction.
Examples
Fiber Reinforced Polymers or FRPs:
Classified by type of fiber:
Wood (cellulose fibers in a lignin and hemicellulose matrix)
Carbon-fiber reinforced plastic or CFRP
Glass-fiber reinforced plastic or GFRP
Classified by matrix:
Thermoplastic Composites
short fiber thermoplastics
long fiber thermoplastics or long fiber reinforced
thermoplastics
glass mat thermoplastics
continuous fiber reinforced thermoplastics
Thermoset Composites
Reinforced carbon-carbon (carbon fiber in a graphite matrix)
Engineered wood
Plywood
Oriented strand board
Wood plastic composite (recycled wood
fiber in polyethylene matrix)
Pykrete (sawdust in ice matrix)
Plastic-impregnated or laminated paper or
textiles
Arborite
Formica (plastic)
Buckypaper Composites
Road design
consists of two important technical
aspects:
geometrical road design
structural road design
Reinforced carbon-carbon
Reinforced Carbon-Carbon
(carbon-carbon or RCC) is a
composite material consisting
of carbon fiber reinforcement
in a matrix of graphite, often
with a silicon carbide coating
to prevent oxidation. It was
developed for the nose cones
of
intercontinental ballistic missil
es
, and is most widely known as
the material for the nose cone
and leading edges of the
space shuttle.
Composition
MMCs are made by dispersing a reinforcing
material into a metal matrix. The reinforcement
surface can be coated to prevent a chemical
reaction with the matrix. For example, carbon
fibers are commonly used in aluminum matrix to
synthesize composites containing low density
and high strength. However, carbon reacts with
aluminum to generate a brittle and water-soluble
compound Al4C3 on the surface of the fiber. To
prevent this reaction, the carbon fibers are
coated with nickel or titanium boride.
Matrix
The matrix is the monolithic material into which
the reinforcement is embedded, and is
completely continuous. This means that there is
a path through the matrix to any point in the
material, unlike two materials sandwiched
together. In structural applications, the matrix is
usually a lighter metal such as aluminum,
magnesium, or titanium, and provides a
compliant support for the reinforcement. In high
temperature applications, cobalt and cobaltnickel alloy matricies are common.
Reinforcement
MMC manufacturing can be broken into three types: solid, liquid, and vapor.
Solid state methods
Powder blending and consolidation (powder metallurgy): Powdered metal
and dicontinuous reinforcement are mixed and then bonded through a
process of compaction, degassing, and thermo-mechanical treatment
(possibly via hot isostatic pressing (HIP) or extrusion).
Foil diffusion bonding: Layers of metal foil are sandwiched with long fibers,
and then pressed through to form a matrix.
Liquid state methods
Electroplating / Electroforming: A solution containing metal ions loaded with
reinforcing particles is co-deposited forming a composite material.
Stir casting: Discontinuous reinforcement is stirred into molten metal, which
is allowed to solidify.
Squeeze casting: Molten metal is injected into a form with fibers preplaced
inside it.
Spray deposition: Molten metal is sprayed onto a continuous fiber substrate.
Reactive processing: A chemical reaction occurs, with one of the reactants
forming the matrix and the other the reinforcement.
Vapor deposition
Physical vapor deposition: The fiber is passed through a thick cloud of
vaporized metal, coating it. [1]
Applications
Carbide drills are often made from a tough cobalt matrix with hard
tungsten carbide particles inside.
Some tank armors may be made from metal matrix composites, probably
steel reinforced with boron nitride. Boron nitride is a good reinforcement
for steel because it is very stiff and it does not dissolve in molten steel.
Some automotive disc brakes use MMCs. Early Lotus Elise models used
Aluminum MMC rotors, but they have less than optimal heat properties
and Lotus has since switched back to cast-iron. Modern highperformance sport cars, such as those built by Porsche, use rotors made
of carbon fiber within a silicon carbide matrix because of its high specific
heat and thermal conductivity. 3M sells a preformed aluminum matrix
insert for strengthening cast aluminum disc brake calipers [2], allowing
them to weigh as much as 50% less while increasing stiffness.
Toyota has since used metal matrix composites in the 2ZZ-GE engine
block, and the Porsche Boxster and 911 use MMCs to reinforce the
engine's cylinder sleeves. (Lotus uses the 2ZZ-GE in later Elise S2
versions). The 2ZZ-GE engine is actually designed and built by Yamaha,
as were the Iron-block Toyota 4A-GE, etc. Prior, Honda had already used
Aluminum MMC in its high-performance engine blocks such as the H22
and later the K20.
Concrete.
Composition
The composition of concrete is determined initially during
mixing and finally during placing of fresh concrete. The
type of structure being built as well as the method of
construction determine how the concrete is placed and
therefore the composition of the concrete mix (the mix
design).
Cement
Main article: Portland cement
Portland cement is the most common type of cement in
general usage. It is a basic ingredient of concrete, mortar
and plaster
Water
Potable water can be used for
manufacturing concrete. The w/c ratio
(mass ratio of water to cement) is the key
factor that determines the strength of
concrete. A lower w/c ratio will yield a
concrete which is stronger, while a higher
w/c ratio yields a concrete with a lower
strength
Aggregates
The water and cement paste hardens and develops
strength over time. In order to ensure an economical and
practical solution, both fine and coarse aggregates are
utilised to make up the bulk of the concrete mixture.
Sand, natural gravel and crushed stone are mainly used
for this purpose. However, it is increasingly common for
recycled aggregates (from construction, demolition and
excavation waste) to be used as partial replacements of
natural aggregates, whilst a number of manufactured
aggregates, including air-cooled blast furnace slag and
bottom ash are also permitted.
Admixtures
Admixtures are materials in the form of powder
or fluids that are added to the concrete to give it
certain characteristics not obtainable with plain
concrete mixes. In normal use, admixture
dosages are less than 5% by mass of cement,
and are added to the concrete at the time of
batching / mixing. The most common types of
admixtures are:
Additions
Additions are very fine inorganic materials that usually have
pozzolanic or latent hydraulic properties. They are added at the
concrete mixer to improve the properties of concrete. The term is
not used when the materials are added at the factory as
constituents of blended cements.
Fly ash: A by product of coal fired elgenerating plants, it is used to
partially replace Portland cement (by up to 60% by mass). The
properties of fly ash depend on the type of coal burnt. In general,
silicious fly ash is pozzolanic, while calcareous fly ash has latent
hydraulic properties.
Ground granulated blast furnace slag (ggbs): A by product of steel
production, is used to partially replace Portland cement (by up to
80% by mass). It has latent hydraulic properties.
Silica fume: A byproduct of the production of silicon and ferrosilicon
alloys. Silica fume is similar to fly ash, but has a particle size 100
times smaller. This results in a higher surface to volume ratio and a
much faster pozzolanic reaction. Silica fume is used to increase
strength and durability of concrete, but generally requires the use of
superplasticizers for workability
Characteristics
During hydration and hardening, concrete
needs to develop certain physical and
chemical properties. Among other
qualities, mechanical strength, low
moisture permeability, and chemical and
volumetric stability are necessary.
Workability
Workability (or consistency, as it is known in Europe) is the ability of
a fresh (plastic) concrete mix to fill the form / mould properly with the
desired work (vibration) and without reducing the concrete's quality.
Workability depends on water content, chemical admixtures,
aggregate (shape and size distribution), cementitious content and
age (level of hydration)
Curing
Because the cement requires time to fully hydrate before it acquires
strength and hardness, concrete must be cured once it has been
placed. Curing is the process of keeping concrete under a specific
environmental condition until hydration is relatively complete. Good
curing is typically considered to use a moist environment which
promotes hydration, since increased hydration lowers permeability
and increases strength, resulting in a higher quality material.
Allowing the concrete surface to dry out excessively can result in
tensile stresses, which the still-hydrating interior cannot withstand,
causing the concrete to crack.
Strength
Concrete has relatively high compressive strength, but
significantly lower tensile strength (about 10% of the
compressive strength). As a result, concrete always fails
from tensile stresses even when loaded in
compression. The practical implication of this is that
concrete elements subjected to tensile stresses must be
reinforced. Concrete is most often constructed with the
addition of steel or fiber reinforcement. The
reinforcement can be by bars (rebar), mesh, or fibres,
producing reinforced concrete. Concrete can also be
prestressed (reducing tensile stress) using internal steel
cables (tendons), allowing for beams or slabs with a
longer span than is practical with reinforced concrete
alone.
Elasticity
The modulus of elasticity of concrete is a funcion of the modulus of
elasticity of the aggregates and the cement matrix and their relative
proportions. The modulus of elasticity of concrete is relatively linear at
low stress levels but becomes increasing non-linear as matrix
cracking develops. The elastic modulus of the paste may be in the
order of 10 GPa and aggregates about 45 to 85 GPa. The concrete
composite is then in the range of 30 to 50 GPa.
Expansion and shrinkage
Concrete has a very low coefficient of thermal expansion. However if
no provision is made for expansion very large forces can be created,
causing cracks in parts of the structure not capable of withstanding
the force or the repeated cycles of expansion and contraction.
As concrete matures it continues to shrink, due to the ongoing
reaction taking place in the material. Brickwork made of clay tends to
expand for some time after manufacture of the bricks, and the relative
shrinkage and expansion of concrete and brickwork require careful
accommodation when the two forms of construction interface.
Cracking
Concrete is placed while in a wet (or plastic) state, and therefore can be
manipulated and molded as needed. Hydration and hardening of concrete during
the first three days is critical. Abnormally fast drying and shrinkage due to factors
such as evaporation from wind during placement may lead to increased tensile
stresses at a time when it has not yet gained significant strength, resulting in
shrinkage cracks. The early strength of the concrete can be increased by keeping
it damp for a longer period during the curing process. Minimizing stress prior to
curing minimizes cracking. High early-strength concrete is designed to hydrate
faster, often by increased use of cement, which increases shrinkage and cracking.
Creep
Creep is the term used to describe the permanent movement or deformation of a
material in order to relieve stresses within the material. Concrete which is
subjected to forces is prone to creep. Creep can sometimes reduce the amount of
cracking that occurs in a concrete structure or element, but it also must be
controlled. The amount of primary and secondary reinforcing in concrete
structures contributes to a reduction in the amount of shrinkage, creep and
cracking.
Types of concrete
Regular concreteRegular concrete is the lay term describing concrete that is produced by
following the mixing instructions that are commonly published on packets of cement,
typically using sand or other common material as the aggregate, and often mixed in
improvised containers. This concrete can be produced to yield a varying strength from
about 10 MPa to about 40 MPa, depending on the purpose, ranging from blinding to
structural concrete respectively. Many types of pre-mixed concrete are available which
include powdered cement mixed with an aggregate, needing only water.
High-strength concrete
High-strength concrete is concrete with a compressive strength generally greater than
6,000 pounds/square inch (40 MPa). High-strength concrete is made by lowering the watercement (w/c) ratio to 0.35 or lower. Often silica fume is added to prevent the formation of
free calcium hydroxide crystals in the cement matrix, which might reduce the strength at
the cement-aggregate bond.
Low w/c ratios and the use of silica fume make concrete mixes significantly less workable,
which is particularly likely to be a problem in high-strength concrete applications where
dense rebar cages are likely to be used. To compensate for the reduced workability,
superplasticizers are commonly added to high-strength mixtures. Aggregate must be
selected carefully for high-strength mixes, as weaker aggregates may not be strong
enough to resist the loads imposed on the concrete and cause failure to start in the
aggregate rather than in the matrix or at a void, as normally occurs in regular concrete.
In some applications of high-strength concrete the design criterion is the elastic modulus
rather than the ultimate compressive strength.
Self-compacting concretes
During the 1980s a number of countries including Japan, Sweden and France developed a
range of concretes that were self-compacting. These self-compacting concretes (SCCs)
are characterised by their extreme fluidity, behaving more like a thick fluid that is selfleveling, as opposed to the traditional concrete that needs consolidating, normally by
vibration or packing.
Shotcrete
Shotcrete uses compressed air to shoot (cast) concrete
onto (or into) a frame or structure. Shotcrete is frequently
used against vertical soil or rock surfaces, as it
eliminates the need for formwork. It is sometimes used
for rock support, especially in tunnelling. Today there are
two application methods for shotcrete: the dry-mix and
the wet-mix procedure. In dry-mix the dry mixture of
cement and aggregates is filled into the machine and
conveyed with compressed air through the hoses. The
water needed for the hydration is added at the nozzle. In
wet-mix, the mixes are prepared with all necessary water
for hydration. The mixes are pumped through the hoses.
At the nozzle compressed air is added for spraying. For
both methods additives such as accelerators and fiber
reinforcement may be used. [3]
The term Gunite is occasionally used for shotcrete, but
properly refers only to dry-mix shotcrete, and once was a
proprietary name.
Pervious concrete
With pervious or "no fines" concrete, carefully controlled amounts of water
and cementitious materials are used to create a paste that forms a thick
coating around aggregate particles. A pervious concrete mixture contains
little or no sand (fines), creating a substantial void content. Using sufficient
paste to coat and bind the aggregate particles together creates a system of
highly permeable, interconnected voids that drains quickly. Typically,
between 15% and 25% voids are achieved in the hardened concrete, and
flow rates for water through pervious concrete are typically around 480 in./hr
(0.34 cm/s, which is 5 gal/ft/ min or 200 L/m/min), although they can be
much higher. Both the low mortar content and high porosity also reduce
strength compared to conventional concrete mixtures, but sufficient strength
for many applications is readily achieved.
Pervious concrete pavement is a unique and effective means to address
important environmental issues and support sustainable growth. By
capturing rainwater and allowing it to seep into the ground, porous concrete
is instrumental in recharging groundwater, reducing stormwater runoff, and
meeting US Environmental Protection Agency (EPA) stormwater regulations.
The use of pervious concrete is among the Best Management Practices
(BMPs) recommended by the EPA, and by other agencies and geotechnical
engineers across the country, for the management of stormwater runoff on a
regional and local basis. This pavement technology creates more efficient
land use by eliminating the need for retention ponds, swales, and other
stormwater management devices. In doing so, pervious concrete has the
ability to lower overall project costs on a first-cost basis.
Cellular concrete
Aerated concrete produced by the addition of an air entraining agent
to the concrete (or a lightweight aggregate like vermiculite ) is
sometimes called Cellular concrete. See also
aerated autoclaved concrete.
Roller-compacted concrete
Roller-compacted concrete, sometimes called rollcrete, is a lowcement-content stiff concrete placed using techniques borrowed
from earthmoving and paving work. The concrete is placed on the
surface to be covered, and is compacted in place using large heavy
rollers typically used in earthwork. The concrete mix achieves a high
density and cures over time into a strong monolithic block. [4]
Roller-compacted concrete is typically used for concrete pavement,
but has also been used to build concrete dams, as the low cement
content causes less heat to be generated while curing than typical
for conventionally placed massive concrete pours.
Asphalt concrete
Strictly speaking, asphalt is a form of concrete as well, with
bituminous materials replacing Portland cement as the binder.
Cermet
Cermet is an abbreviation for "'ceramic" and "metal." A CerMet is a
composite material composed of ceramic (cer) and metallic (met)
materials. A Cermet is ideally designed to have the optimal properties
of both a ceramic, such as high temperature resistance and
hardness, and those of a metal, such as the ability to undergo
plastic deformation. The metal is used as a binder for an oxide,
boride, carbide, or alumina. Generally, the metallic elements used are
nickel, molybdenum, and cobalt. Depending on the physical structure
of the material, cermets can also be metal matrix composites , but
cermets are usually less than 20% metal by volume.
It is used in the manufacture of resistors (especially potentiometers),
capacitors, and other electronic components which may experience
high temperatures.
Some types of cermet are also being considered for use as
spacecraft shielding as they resist the high velocity impacts of
micrometeoroids and orbital debris much more effectively than more
traditional spacecraft materials such as aluminum and other metals.
One application of these materials is their use in vacuum tube
coatings which are key to solar hot water systems.
Cermets are also used in dentistry as a material for fillings and
prostheses.
Bone
Matrix
The matrix comprises the other major constituent of
bone. It has inorganic and organic parts. The inorganic is
mainly crystalline mineral salts and calcium, which is
present in the form of hydroxyapatite. The matrix is
initially laid down as unmineralized osteoid
(manufactured by osteoblasts). Mineralisation involves
osteoblasts secreting vesicles containing alkaline
phosphatase. This cleaves phosphate groups and acts
as the foci for calcium and phosphate deposition. The
vesicles then rupture and act as a centre for crystals to
grow on.
The organic part of matrix is mainly Type I collagen. This
is made intracellularly as tropocollagen and then
exported. It then associates into fibrils. Also making up
the organic part of matrix include various growth factors,
the functions of which are not fully known. Other factors
present include GAGs, osteocalcin, osteonectin,
bone sialo protein and Cell Attachment Factor.
Engineered wood
Engineered wood, also called composite
wood, includes a range of derivative wood
products which are manufactured by
binding together wood strands, particles,
fibers, or veneers with adhesives to form
composite materials. These products are
engineered to precise design
specifications which are tested to meet
national or international standards.
Types
Plywood
Types of plywood
. Softwood plywood is usually made either of Douglas fir or spruce,
pine, and fir, and is typically used for construction and industrial
purposes. Decorative plywood is usually faced with hardwood,
including red oak, birch, maple, lauan (Philippine mahogany) and a
large number of other hardwoods.
Plywood meant for indoor use generally uses the less expensive
urea-formaldehyde glue which has limited water resistance, while
outdoor and marine grade plywood are designed to withstand rot
and use a water resistant phenol-formaldehyde glue to prevent
delamination
Plywood production
Plywood production requires a good log, called a peeler, which is
generally straighter and larger in diameter than one required for
processing into dimensioned lumber by a sawmill. The log is peeled
into sheets of veneer which are then cut to the desired dimensions,
dried, patched and glued together to form the plywood panel. The
panel can then be patched, resized, sanded or otherwise refinished,
depending on the market it was intended for.
History
Plywood has been made for thousands of years; the earliest known
occurrence of plywood was in ancient Egypt around 3500 BC when
wooden articles were made from sawn veneers glued together
crosswise. This was originally done due to a shortage of fine wood.
Thin sheets of high quality wood were glued over a substrate of
lower quality wood for cosmetic effect, with incidental structural
benefits. This manner of inventing plywood has occurred repeatedly
throughout history. Many of the great English furniture makers such
as Sheridan used veneer as a raw material.
Formica (plastic)
Buckypaper
Buckypaper is a thin sheet made from nanotubes that
are 250 times stronger than steel and 10 times lighter. It
is being developed by Dr. Ben Wang with other
professors and students from the Florida State University
research group the
Florida Advanced Center for Composite Technologies
(FAC2T). The project has already attracted research
funding from the Army Research Lab and
Air Force Office of Scientific Research.
The name "Buckypaper" derives from buckyballs and
shows great promise as a building material for
everything from aerospace vehicles, body armor and
next-generation electronics and displays.
Background
Buckypaper is made from carbon nanotubes
amazingly strong fibers about 1/50,000th the diameter of
a human hair that were first developed in the early
1990s. Buckypaper owes its name to
Buckminsterfullerene, or Carbon 60 a type of carbon
molecule whose powerful atomic bonds make it twice as
hard as a diamond. Sir Harold Kroto, now a professor
and scientist with FSU's department of chemistry and
biochemistry, and two other scientists shared the 1996
Nobel Prize in Chemistry for their discovery of
Buckminsterfullerene, nicknamed "buckyballs" for the
molecules' spherical shape. Their discovery has led to a
revolution in the fields of chemistry and materials
science and directly contributed to the development of
buckypaper.
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