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IONIC BONDS
COVALENT BONDS
HYDROGEN BONDS
METALLIC BONDS
IONIC BONDING
Ionic Bond
An IONIC BOND is an electrostatic interaction that holds together a
positively charged ion (cation) and a negatively charged ion
(anion). In an ionic bond, one atom loses an electron to another
atom, forming a cation and anion, respectively. And, as
everyone knows, opposites attract.
Formation of NaCl
Sodium chloride
results from ionic
bonding.
IONIC BONDING
IONIC BONDING
IS THE COMPOUND
AN IONIC COMPOUND?
Mg N
METAL
NONMETAL
SUBSCRIPTS
Metal
IONIC BONDING
Metals will tend to lose electrons
and become
POSITIVE CATIONS
+
Na 11 p
11 e Normal sodium atom
1e -
Na 11 p
10 e to become sodium ion
IONIC BONDING
Nonmetals will tend to gain
electrons and become
NEGATIVE ANIONS
+
Cl 17 p
17 e Normal chlorine atom
1e -
gains an electron
Cl
17 p
18 e -
IONIC BONDING
POLYATOMIC IONS--a group
of atoms that act like one ion
IONIC BONDING
Na
SO
4
SODIUM SULFATE
Crystalline structure
The
POSITIVE
CATIONS
stick to the
NEGATIVE
ANIONS, like
a magnet.
+
+
- - +
+ + - + - +
- + - +
Do they Conduct?
Conducting electricity is allowing
charges to move.
In a solid, the ions are locked in place.
Ionic solids are insulators.
When melted, the ions can move
around.
Melted ionic compounds conduct.
First get them to 800C.
Dissolved in water they conduct.
+
+
-
+
+
+
+
-
+
+
+
+ - + - +
+ - + - + - +
COVALENT BONDING
iv.
An s-orbital does not show any preference for direction. The nonspherical orbitals such as, p- and d-orbitals tend to form bonds in
the direction of the maximum overlap, i.e., along the orbital axis.
v.
Between the two orbitals of the same energy, the orbital which is
non-spherical (e.g., p- and d- orbitals forms stronger bonds than the
orbital which is spherically symmetrical, e.g., s-orbital.
vi.
The valence of an element is equal to the number of half-filled
orbitals present in it.
In the valence bond model, the stability of a molecule is explained in
terms of the following types of interactions.
a.
electron - nuclei attractive interactions, i.e., the electrons of one
atom are attracted by the nucleus of the other atom also.
b.
electron - electron repulsive interactions, i.e., electrons of one
atom are repelled by the electrons of the other atom.
c.
nucleus - nucleus repulsive interactions, i.e., nucleus of one atom
is repelled by the nucleus of the other atom.
Various interactions which act between the two atoms are shown in Fig.
The attractive and the repulsive interactions oppose each other. When
the attractive interactions are stronger than the repulsive
interactions, certain amount of energy is released. Due to the
lowering of energy the molecule becomes stable.
Valence Bond Description of Hydrogen Molecule
Chemical Bond and the Valence Bond Theory: The Orbital Overlap
In the beginning, atoms in a molecule were thought to be held by bonds. These
bonds are represented by drawing a small line () between the combining
atoms. Lewis described a chemical bond in terms of pair of electrons shared
by the combining atoms. So, the pair of electrons shared by the two nuclei
may be considered to be a chemical bond. Thus, the line drawn between the
two atoms to represent a chemical bond in the older concept, may be seen as a
shared pair of electrons in the Lewis concept.
Sharing of an electron pair is possible only when the atom are close enough to
overlap their orbitals. Thus, the orbital overlap is necessary for the sharing
of electrons and hence for the bond formation.
TYPES OF OVERLAPPING
Various types of atomic orbital overlap leading to the formation of covalent bond
are:
1. s s overlap .
In this type of overlap, half-filled
s -orbitals of the two combining atoms overlap each other. This is shown in
Fig.
2. s p overlap .
Here a half-filled s -orbital of one atom overlaps with one of the p
-orbitals having only one electron in it. This is shown in Fig
3. pp overlap along the orbital axis. This is called head on, end-on or
end-to-end linear overlap. Here, the overlap of the two half-filled p-orbitals
takes place along the line joining the two nuclei. This is shown in Fig.
A covalent bond formed due to the overlap of orbitals of the two atoms
along the line joining the two nuclei (orbital axis) is called sigma ( )
bond. For example, the bond formed due to s-s and s-p, and p-p
overlap along the orbital axis are sigma bonds, (by convention Z-axis
is taken as inter-nuclear axis.
A covalent bond formed between the two atoms due to the sideways
overlap of their p -orbitals is called a pi ( ) bond
COVALENT BONDING
COVALENT BOND
FORMATION
COVALENT BONDING
IS THE COMPOUND
A COVALENT COMPOUND?
CO
NONMETAL
NONMETAL
2
YES since it is made of only nonmetal elements
Covalent bonding
Fluorine has seven valence electrons
Covalent bonding
Fluorine has seven valence electrons
A second atom also has seven
Covalent bonding
Fluorine has seven valence electrons
A second atom also has seven
By sharing electrons
Covalent bonding
Fluorine has seven valence electrons
A second atom also has seven
By sharing electrons
Covalent bonding
Fluorine has seven valence electrons
A second atom also has seven
By sharing electrons
F F
Covalent bonding
Fluorine has seven valence electrons
A second atom also has seven
By sharing electrons
F F
Covalent bonding
Fluorine has seven valence electrons
A second atom also has seven
By sharing electrons
F F
Covalent bonding
Fluorine has seven valence electrons
A second atom also has seven
By sharing electrons
Both end with full orbitals
F F
Covalent bonding
Fluorine has seven valence electrons
A second atom also has seven
By sharing electrons
Both end with full orbitals
F F
8 Valence
electrons
Covalent bonding
Fluorine has seven valence electrons
A second atom also has seven
By sharing electrons
Both end with full orbitals
8 Valence
electrons
F F
Water
H
O
Water
Put the pieces together
The first hydrogen is happy
The oxygen still wants one more
HO
Water
The second hydrogen attaches
Every atom has full energy levels
HO
H
Hydrogen Bonding
If a hydrogen atom is bonded to a highly electronegative element such as
fluorine, oxygen, nitrogen, then the shared pair of electrons lies more
towards the electronegative element. This leads to a polarity in the
bond in such a way that a slight positive charge gets developed on Hatom, viz.,
H+ : O H+ : F H+ : N
This positive charge on hydrogen can exert electrostatic attraction on the
negatively charged electronegative atom of the same or the other
molecule forming a bridge-like structure such as
X H+ Y H+
where X and Y are the atoms of strongly electronegative elements.
The bond between the hydrogen atom of one molecule and a more
electronegative atom of the same or another molecule is called
hydrogen bond.
Water (H2O).
Ice (H2O(s)).
Each Oxygen is "linked" in by a combination of a covalent bond and a
hydrogen bond to 4 other Oxygens.
Notice that each Oxygen can be linked to Hydrogen in one of two ways.
Or
Carbon dioxide
C
O
Carbon dioxide
Attaching 1 oxygen leaves the oxygen 1
short and the carbon 3 short
CO
Carbon dioxide
OC O
Carbon dioxide
O CO
Carbon dioxide
O CO
Carbon dioxide
O CO
Carbon dioxide
O C O
Carbon dioxide
O C O
Carbon dioxide
O C O
Carbon dioxide
The only solution is to share more
Requires two double bonds
Each atom gets to count all the atoms
in the bond
O C O
Carbon dioxide
The only solution is to share more
Requires two double bonds
Each atom gets to count all the atoms
in the bond
8 valence
electrons
O C O
Carbon dioxide
The only solution is to share more
Requires two double bonds
Each atom gets to count all the atoms
in the bond
8 valence
electrons
O C O
Carbon dioxide
The only solution is to share more
Requires two double bonds
Each atom gets to count all the atoms
in the bond
8 valence
electrons
O C O
Examples
HCN
Put in single bonds
Need 2 more bonds
Must go between C and N
HC N
HCN
Put in single bonds
Need 2 more bonds
Must go between C and N
Uses 8 electrons - 2 more to add
HC N
HCN
Put in single bonds
Need 2 more bonds
Must go between C and N
Uses 8 electrons - 2 more to add
Must go on N to fill octet
HC N
Polar Bonds
When the atoms in a bond are the same, the
electrons are shared equally.
This is a nonpolar covalent bond.
When two different atoms are connected,
the atoms may not be shared equally.
This is a polar covalent bond.
How do we measure how strong the atoms
pull on electrons?
Electronegativity
A measure of how strongly the atoms attract
electrons in a bond.
The bigger the electronegativity difference
the more polar the bond.
0.0 - 0.3 Covalent nonpolar
0.3 - 1.67 Covalent polar
>1.67 Ionic
Polar Molecules
Molecules with ends
Polar Molecules
Molecules with a positive and a negative end
Requires two things to be true
The molecule must contain polar bonds
This can be determined from differences in
electronegativity.
Symmetry can not cancel out the effects of the
polar bonds.
Must determine geometry first.
Is it polar?
HF
H2O
NH3
CCl4
CO
Intermolecular Forces
What holds molecules to each other
Intermolecular Forces
They are what make solid and liquid molecular
compounds possible.
The weakest are called van der Waals forces there are two kinds
Dispersion forces
Dipole Interactions
depend on the number of electrons
more electrons stronger forces
Bigger molecules
Dipole interactions
Depend on the number of electrons
More electrons stronger forces
Bigger molecules more electrons
Fluorine is a gas
Bromine is a liquid
Iodine is a solid
Dipole interactions
Occur when polar molecules are attracted to
each other.
Slightly stronger than dispersion forces.
Opposites attract but not completely hooked
like in ionic solids.
Dipole interactions
Occur when polar molecules are attracted to
each other.
Slightly stronger than dispersion forces.
Opposites attract but not completely hooked
like in ionic solids.
HF
HF
Dipole Interactions
Hydrogen bonding
Are the attractive force caused by hydrogen
bonded to F, O, or N.
F, O, and N are very electronegative so it is
a very strong dipole.
The hydrogen partially share with the lone
pair in the molecule next to it.
The strongest of the intermolecular forces.
Hydrogen Bonding
H
+
+ H O
H +
H
H
H O
H
H
H
H O
H
H O
O
H
Hydrogen bonding
MOLECULAR
SHAPES
OF
COVALENT
COMPOUNDS
VSepR tHEORY
ALENCE
VSEPR
HELL
LECTRON
AIR
EPULSION
What Vsepr
means
Things to
remember
Atoms bond to form an Octet
(8 outer electrons/full outer
energy level)
Bonded electrons take up less
space then unbonded/unshared pairs of
HERE ARE
THE
RESULTING
MOLECULAR
SHAPES
Linear
EXAMPLE:
BeF2
Number of Bonds = 2
Number of Shared Pairs of Electrons = 2
Bond Angle = 180
Trigonal Planar
EXAMPLE:
GaF3
Number of Bonds = 3
Number of Shared Pairs of Electrons = 3
Number of Unshared Pairs of Electrons = 0
Bond Angle = 120
Bent #1
EXAMPLE:
H2O
Number of Bonds = 2
Number of Shared Pairs of Electrons = 2
Number of Unshared Pairs of Electrons = 2
Bond Angle = < 120
Bent #2
EXAMPLE:
O3
Number of Bonds = 2
Number of Shared Pairs of Electrons = 2
Number of Unshared Pairs of Electrons = 1
Bond Angle = >120
Tetrahedral
EXAMPLE:
CH4
Number of Bonds = 4
Number of Shared Pairs of Electrons = 4
Number of Unshared Pairs of Electrons = 0
Bond Angle = 109.5
Trigonal Pyramidal
EXAMPLE:
NH3
Number of Bonds = 3
Number of Shared Pairs of Electrons = 4
Number of Unshared Pairs of Electrons = 1
Bond Angle = <109.5
Trigonal bIPyramidal
EXAMPLE:
NbF5
Number of Bonds = 5
Number of Shared Pairs of Electrons = 5
Number of Unshared Pairs of Electrons = 0
Bond Angle = <120
OCTAHEDRAL
EXAMPLE:
SF6
Number of Bonds = 6
Number of Shared Pairs of Electrons = 6
Number of Unshared Pairs of Electrons = 1
Bond Angle = 90
Metallic Bonds
How atoms are held together in
the solid.
Metals hold onto there valence
electrons very weakly.
Think of them as positive ions
floating in a sea of electrons.
Sea of Electrons
Electrons are free to move through the
solid.
Metals conduct electricity.
+ + +
+ + + +
+ + + +
Malleable
+ + +
+ + + +
+ + + +
Malleable
Electrons allow atoms to slide by.
+ + + +
+ + + +
+ + + +
Sub Topic 6:
(v) The electrons of the constituent atoms of a molecule are distributed over all the
available
MOs in accordance with the Aufbau principle, the Pauli's exclusion principle and
Hunds rule.
(vi) Like atomic orbitals (AOs), the molecular orbitals can also be arranged
according to their energies. The internuclear axis is taken to be in the z-direction.
For the molecule or molecular ions formed from Li, Be, B, C, and N, the energies
of 2s and 2p orbitals are quite close to each other. Because of the repulsion
between the electrons that occupy 2s and 2p orbitals, the energy of the 2p
molecular orbital gets raised. Relative to 2p orbitals.
The presence of one or more unpaired electrons accounts for the paramagnetic
nature of the molecule. The electronic configuration in which all the
electrons are paired indicate the diamagnetic nature of the species.
The strength of a chemical bond is described in terms of a parameter called bond
order.
As per definition, the bond order is expressed as,
Bond order = (No. of electrons in BMO-No. of electrons in ABMO)/2=(Nb-Na)/2
where, N b is the total number of electrons in bonding MOs.
N a is the total number of electrons in antibonding MOs.
(a)
When, N b > N a : Bond order > 0 (+ ve). Then, a stable bond formation is
indicated.
(b)
When, N b N a : Bond order 0. Then, the bond is unstable. In fact. such a
bond is not formed.
Conditions For the Formation of MOs From the Atomic Orbitals
Formation of MOs by the combination of atomic orbitals takes place only if the
following conditions are satisfied:
(i) The combining atomic orbitals should have nearly equal energies. Only the
atomic orbitals of nearly the same energy combine to form MOs. For
example, 1s atomic orbitals of two atoms can combine to form one bonding
1s ) and one antibonding * 1s ) orbitals. The 1s atomic orbital of one
atom cannot combine with 2s or 2p atomic orbital of the other atom.
(ii) The combining atomic orbitals should have the same symmetry.
The atomic orbitals are oriented in space. Only those atomic orbitals
can combine to form molecular orbitals which have the same
symmetry about the molecular axis. For example, a p x orbital of an
atom can combine with a p x orbital of another atom. A p x orbital
cannot combine with a p z orbital.
(iii) The combining atomic orbitals should overlap effectively. MOs
are formed only if the combining atomic orbitals overlap to a
reasonable extent.
In-phase and out-of-phase wave combinations
Matter waves corresponding to the two separate hydrogen 1s orbitals
interact; both in-phase and out-of-phase combinations are possible,
and both occur. One of the resultants is the bonding orbital that we just
considered. The other, corresponding to out-of-phase combination of
the two orbitals, gives rise to a molecular orbital that has its greatest
electron probability in what is clearly the antibonding region of space.
This second orbital is therefore called an antibonding orbital.
Dicarbon
Dioxygen
Types of Hybridisation
Depending upon the nature of the orbitals involved in
hybridisation, different types of hybridisation
become possible. The type of hybridisation shown by
an atom depends upon the requirements of the
reaction.
sp3
one s-orbital
three p-orbitals
four hybrid
orbitals
sp2 (ess pee two) hybridisation. In certain reactions, one s and two p
(say px and py) orbitals of an atom undergo mixing to produce three
equivalent sp2 hybridised orbitals. The three sp2 hybrid orbitals are
oriented in a plane along the three corners of an equilateral triangle,
i.e., they are inclined to each other at an angle of 120. The third porbital (say pz here) remains unchanged. Each hybrid orbital has
33.3% s-character and 66.7% p-character. Formation of sp2-hybrid
orbitals from one s and two p-orbitals is shown in Fig. 6.43.
s + (px + py) sp2
one s-orbital two p-orbitals three hybrid orbitals
THE
END