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Spectroscopy.
Chem. 331
Introduction
Atomic absorption is the absorption
of light by free atoms. An atomic
absorption spectrophotometer is an
instrument that uses this principle to
analyze the concentration of metals
in solution. The substances in a
solution are suctioned into an
excited phase where they undergo
vaporization, and are broken down
into small fragmented atoms by
discharge, flame or plasma.
Atomic Emission
Spectroscopy
By exposing these atoms to such
temperatures they are able to jump
to high energy levels and in return,
emit light. The versatility of atomic
absorption an analytical technique
(Instrumental technique) has led to
the development of commercial
instruments. In all, a total of 68
metals can be analyzed.
Advantages of AA
Determination of 68 metals
Ability to make ppb determinations on major
components of a sample
Precision of measurements by flame are better
than 1% rsd. There are few other instrumental
methods that offer this precision so easily.
AA analysis is subject to little interference.
Most interference that occurs have been well
studied and documented.
Sample preparation is simple (often involving
only dissolution in an acid)
Instrument easy to tune and operate
types)
Atomic Emission (with thermal
excitation), AES
Atomic Absorption, (with optical
photon unit) AAS
Atomic Florescence, AFS
Picture of an inductively-coupled
plasma atomic emission spectrometer
References
www.anachem.umu.se/jumpstation.htm
www.anachem.umu.se/cgi/jumpstation.exe?
AtomicSpectroscopy
www.anachem.umu.se/cgi/jumpstation.exe?
OpticalMolecularSpectroscopy
www.minyos.its.rmit.edu.au/~rcmfa/mstheory.html
http://science.widener.edu/sub/ftir/intro_it.html
http://www.s-a-s.org/
http://www.chemsw.com
http://www.scimedia.com/chem-ed/spec/atomic/aa.htm
http://nercdg.org
http://www.analyticon.com
www.lcgmag.com/
www.lcms.com/
www.dq.fct.unl.pt/QOF/Chroma.html
www-ssg.chem.utas.edu.au/
References ( Contd.)
www.yahoo.com/science/chemistry/chromatography/
www.onlinegc.com
http://www.aurora-instr.com
http://www.chem.ufl.edu/~itl/3417_s98/spectroscopy/aes.
htm
http://www.rohan.sdsu.edu/staff/drjackm/chemistry/chem
link/analytic/analyt1.html
http://www.cofc.edu/~deavorj/521/jpd521.htm
http://www.scimedia.com/chem-ed/spec/atomic/aes.htm
http://elchem.kaist.ac.kr/vt/chem-ed/spec/atomic/aes.htm
http://www.chemistry.adelaide.edu.au/external/socrel/content/icp.htm
http://employees.oneonta.edu/schaumjc/chm361/iron.doc