Академический Документы
Профессиональный Документы
Культура Документы
UNIVERSIT Y OF INDONESIA
Aqueous
Reactions and
Solution
Stoichiometry
Introduction
General properties of aqueous solution
Precipitation reaction
Acid-base reaction
Oxidation-reduction reaction
Concentration of solution
Solution stoichiometry and chemical
analysis
UNIVERSIT Y OF INDONESIA
Introductio
n
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
a
homogeneous
Asolutionis
mixture.
A solution consists of
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
General
Properties of
Aqueous
Solution
An electrolyte may be either
UNIVERSIT Y OF INDONESIA
astrong electrolyteor
aweak electrolyte.
General
Properties of
Aqueous
Solution
Ionic compounds that are soluble in
waterdissociatecompletely
and
exist in solution entirely as ions.
Soluble ionic compounds are strong
electrolytes.
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
Molecular compounds such as sugar
and alcohol are nonelectrolytes.
They have no tendency to come
apart, and they exist in solution
entirely as aqueous molecules.
Some molecular compounds, most
notably acids and weak bases, are
electrolytes.
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
The acids HCl, HBr, HI, HNO3, HClO3,
HClO4, and H2SO4are molecular
compounds thationizein aqueous
solution and exist completely as ions.
For example, hydrogen chloride gas
dissolves in water and ionizes in
solution to give aqueous hydrogen
ion and aqueous chloride ion.
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
All of the seven acids listed above
are strong electrolytes.
They are also called strong acids.
In
both
instances
the
wordstrongdenotes
complete
ionization. (Strong bases are ionic
and are also strong electrolytes.)
UNIVERSIT Y OF INDONESIA
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
General
Properties of
Aqueous
Solution
Weak acids are weak electrolytes.
To represent the equilibrium between
the molecular acid and its ionized
form, we use a double arrow in the
equation.
UNIVERSIT Y OF INDONESIA
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
are
also
weak
Weak
bases
electrolytes.
Ammonia ionizes in water to produce
aqueous
ammonium
ions
and
aqueous hydroxide ions.
Section 4.1
Dissolving NaCl
Dissolving Sugar
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
UNIVERSIT Y OF INDONESIA
General
Properties of
Aqueous
Solution
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
We
convert
the
equation
to
acomplete
ionic
equationby
identifying the strong electrolytes
and representing them as separated
ions.
The equation above becomes
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
UNIVERSIT Y OF INDONESIA
Precipitation
Reaction
Precipitation Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
Anacidis
a molecular substance that ionizes to form
a hydrogen ion (H+) and
increases the concentration of aqueous
H+ions when it is dissolved in water.
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
Weak
bases
are
molecular
compounds that ionize only partially
in water.
Ammonia is an example of a weak
base.
Introduction to Aqueous Bases
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
UNIVERSIT Y OF INDONESIA
Acid-Base
Reaction
OxidationReduction
Reaction
In addition to precipitation and
neutralization reactions, aqueous
ions can participate inoxidationreduction reactions.
Oxidation-reduction reactions involve
the transfer of electrons from one
chemical species to another.
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
A piece of calcium metal, for
example, dissolves in aqueous acid.
Electrons from the calcium metal
have been transferred to the
hydrogen ions.
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
The
calcium
has
undergoneoxidation(loss
of
electrons), and the hydrogen ion has
undergonereduction(gain
of
electrons).
UNIVERSIT Y OF INDONESIA
OXD-Red1
OXD-Red2
OxidationReduction
Reaction
In order to determine whether a
reaction is an oxidation-reduction
reaction, we compare theoxidation
numbers(or oxidation states) of
each element on both sides of the
equation.
UNIVERSIT Y OF INDONESIA
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
OxidationReduction
Reaction
Oxidation numbers can be assigned
using the following rules.
UNIVERSIT Y OF INDONESIA
Exceptions
include
elemental
hydrogen (H2) in which its oxidation
state is zero and metal hydrides (such
as NaH) in which its oxidation state is
minus 1.
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
OxidationReduction
Reaction
Oxidation numbers can be assigned
using the following rules.
UNIVERSIT Y OF INDONESIA
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
OxidationReduction
Reaction
Some common oxidation-reduction
reactions are those between metals
and acids or metals and salts.
Calcium being oxidized by acid is one
example.
Magnesium is also oxidized in acidic
solution.
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
Metals can also be oxidized by
dissolved salts. Nickel metal is
oxidized by a solution of copper
sulfate.
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
ickel metal, however, isnotoxidized
by a solution of calcium sulfate.
UNIVERSIT Y OF INDONESIA
OXD-Red2
OxidationReduction
Reaction
Whether or not such a reaction will
occur can be predicted using
theactivity series.
A metal solid will be oxidized
(dissolved) by the ions of any metal
that occurs below it on the series.
UNIVERSIT Y OF INDONESIA
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
UNIVERSIT Y OF INDONESIA
OxidationReduction
Reaction
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
Dissolution of KMnO4
Dissolution of Mg(OH)2
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
Solution
Stoichiometry
and Chemical
Analysis
Many of the reactions that take place
in aqueous solution are useful in
chemical
analyses,
such
astitrations.
Titration
involves
the
carefully
metered addition of astandard
solutionof one reactant to a flask
containing an unknown quantity of
the other
reactant.
Acid-Base Titration
UNIVERSIT Y OF INDONESIA
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
UNIVERSIT Y OF INDONESIA
Concentration of
Solution
UNIVERSIT Y OF INDONESIA
Thank You