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Assume m=s
qF measures the position of the Fermi level below the intrinsic level Ei for the
semiconductor.
This quantity indicates how strongly p-type the semiconductor is.
Moving EFm up in energy relative to EFs causes a tilt in the oxide conduction band.
We expect such a tilt since an electric field causes a gradient in E i (and similarly in Ev and
Ec).
The energy bands of the semiconductor bend near the interface to accommodate the
accumulation of holes.
It is clear that an increase in hole concentration implies an increase in E i-EF at the
semiconductor surface, since
Since no current passes through the MOS structure, there can be no variation in the Fermi
level within the semiconductor.
Therefore, if Ei-EF is to increase, it must occur by Ei moving up in energy near the surface.
The result is a bending of the semiconductor bands near the interface.
The Fermi level near the interface lies colser to the valence band, indicating a larger hole
concentration than that arising from the doping of the p-type semiconductor.
This raises the potential of the metal. Lowering the metal Fermi level by qV relative to its
equilibrium position.
Tilt of oxide energy band.
Bending of the semiconductor band.
The positive voltage deposits positive charge on the metal and calls for a corresponding net
negative charge at the surface of the semiconductor.
Such a negative charge in p-type material arises from depletion of holes from the region
near the surface, leaving behind uncompensated ionized acceptors.
This is analogous to the depletion region at a p-n junction.
In the depleted region the hole concentration decreases, moving E i closer to EF, and
bending the bands down near the semiconductor surface.
If we continue to increase the positive voltage, the bands at the semiconductor surface
bend down more strongly.
In fact, a sufficiently large voltage can bend E i below EF.
This is particularly interesting case, since E F >> Ei implies a large electron concentration in
the conduction band.
The n-type surface layer is formed not by doping, but instead by inversion of the originally
p-type semiconductor due to the applied voltage, since
no ni e ( EF Ei ) / kT
potential with respect to the vacuum level, and as electron affinity for the oxide and the substra
respect to the conduction band and intrinsic energy.
TheenergybanddiagramsforidealMOS-capacitorsunderdifferentbiasconditions:(a)accumulation,(b)flatband,(c)depletion,and(d)inversion
AdditionalInformation
1
2kT kTs qs
n o kTs qs
Es
[(e
1) (e
1)] 2
qLD
kT
po
kT
When the surface potential is zero (flat band condition), the net space charge is zero.
When the surface potential is negative, it attracts and forms an accumulation layer of the
minority carrier holes at the surface.
The first term in equation is the dominant one, and the accumulation space charge increases very
strongly (exponentially) with negative surface potential.
The integrated accumulation charge involves averaging over depth and introduces a factor of 2 in
the exponent.
Since the charge is due to the mobile majority carriers (holes in this case), the charge piles up
near the oxide-silicon interface. (typically ~ 20 nm)
The band bending is generally small or is said to be pinned to nearly zero.
For a positive surface potential, the second term (linear term) of the equation is the dominant
one.
Although the exponential term exp(qs/kT) is very large, it is multiplied by the ratio of the
minority to majority carrier concentration which is very small, and is initially negligible.
Hence the space charge for small positive surface potential increases as ~
.
The charge is due to the exposed, fixed immobile dopants (acceptor in this case), corresponding
AtequilibriumEiisatsomepointuniformalloverthe
region,butwhenapotentialisappliedtometal,
chargecarriersarenotuniformlydistributeditgets
accumulatednearthesurfaceofsemiconductorand
oxidesobendingoccurs.
Efswillbeconstantbecauseitwillgetdistrubedonly
whenthereisconductionbetweenmetaland
semiconductor.Efswillnotmoveinsemiconductor
Efmwillonlymovebecausemetalisconductora
smallvoltageisenoughforconduction.Tomake
semiconductorEfstomoveup/down,itisnecessaryto
haveconductioninthesemiconductor,becauseof
theaccumulation/depletion/inversionthecarrier
concentrationnearthesurfaceisdifferentfromthe
timeofthermalequilibriumstateofsemiconductor,so
thereisbandbendingofEc,Ev,andEi