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LAWS
BOYLES LAW
The
inverse
relationship
between pressure and volume
It states that the volume of a
sample
of
gas
changes
inversely with the pressure of
the gas as long as the
temperature and the amount
of the gas remain constant.
P1V1 = P2V2
SAMPLE PROBLEMS:
1. A tank of nitrogen has a
volume of 14.0 L and a
pressure of 760.0 mmHg.
Find the volume of the
nitrogen when its pressure is
changed to 400.0 mmHg
while the temperature is held
constant.
CHARLES LAW
States that the Kelvin temperature
and the volume of a gas are directly
related when there is no change in
pressure or amount of gas.
The relationship between volume
and temperature was first observed
by French physicist and balloonist
Jacques Charles.
V1 V2
T1 T2
V1 V2
T1 T2
SAMPLE PROBLEMS
1. A balloon has a volume of
2500.0 mL on a day when
the temperature is 30.00C. If
the temperature at night
falls to 10.00C, what will the
volume of the balloon if the
pressure remains constant?
2.
Find
the
final
temperature of a 2.00L gas sample at 20.00C
cooled until it occupies
a volume of 500 mL.
SAMPLE PROBLEMS:
1. A given mass of gas has a
volume of 800.0 mL at
23.00C and 300.0 torr. What
would the volume of the gas
be at 27.00C and 600.0 torr of
pressure? The amount of gas
is constant.
PV= nRT
Where:
At STP,
P= 1.0 atm= 101.325 kPa
V= 22.4 L
n= 1.0 mole
T= 273 K
R= 0.0821 atm x L/ mol x K
= 8.31kPa x L/ mol x K
SAMPLE PROBLEMS:
3. The volume of a
sample of CO is 405
mL at 10.0 atm and
467 K. What volume
will it occupy at 4.29
atm and 467 K?
Temperature
and
pressure relationship
The pressure of a gas
is directly related to
its Kelvin temperature.
P1 P2
T1 T2
n1 n 2
V1 V2
SAMPLE PROBLEMS:
1. The gas left in a used
aerosol can is at a
pressure of 100 kPa at
270C. If the can is thrown
onto a fire, what will the
internal
pressure
be
when its temperature
reaches 9270C?
.
The
pressure
in
automobile tire is 200 kPa
at a temperature of 270C.
At the end of a journey on
a hot sunny day, the
pressure has risen to 223
kPa.
What
is
the
temperature of the air in
the tire?
AVOGADROS LAW
Equal volumes of
gases at the same
temperature and
pressure contain
equal numbers of
particles.
V1 V2
n1 n2
SAMPLE PROBLEMS
If 23.1 g of oxygen
occupies a volume of 5.0
L
at
a
particular
pressure
and
temperature,
what
volume will 2.5 g of
oxygen
gas
occupy
under
the
same
conditions?
Determine
the
volume
in
liters
occupied by 0.202
mol of a gas at STP.
How many oxygen
molecules are in 3.3
liters of oxygen gas
at STP?
Determine
the
volume
in
liters
occupied by 14.0 g
of N2 at STP.
What
volume
is
occupied by 4.02 x
1022 molecules of H2
at STP?
DALTONS LAW
At constant volume and
temperature, the total
pressure exerted by a
mixture of gases is
equal to the sum of the
partial pressures of the
component gases.
Ptotal=
P1+P2+P3
SAMPLE PROBLEMS
Determine
the
total
pressure of a gas mixture
that contains oxygen,
nitrogen, and helium if
the partial pressures of
the gases are 20.0 kPa,
46.7 kPa, and 26.7 kPa
respectively.