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HIDROKARBON
EVALUASI DAN KORELASI SIFAT-SIFAT GAS DAN CAIRAN
HIDROKARBON
AAN
GRAVITY OF GAS
Gas gravity is the molar mass (molecular weight) of the natural gas
divided by the molar mass of air (28.94 kg/kmol).
yi
C1
0.75
C2
0.07
C3
0.05
n-C4
0.04
n-C5
0.04
C6
0.03
C7
0.02
Solution
a. Assumsing an idela gas behavior
b.
Tci, R
yi,
Tci
Pci
yi.P
ci
C1
0.7
5
16.0
4
12.03
0
343.5
257.
6
67
3
504.
7
C2
0.0
7
30.0
7
2.105
550.1
38.5
70
8
49.6
C3
0.0
5
44.1
0
2.205
666.2
33.3
61
7
30.9
n-C4
0.0
4
58.1
2
2.325
765.6
30.6
22.0
n-C5
0.0
Tpc
847.0
55
1
33.9
MWa
26.1
72.1 2.886
440. Ppc
647.
48 19.4
8
5
Step 5. Calculate Cr
Step 3. Calculate Z
Factor Z =
0.725
Step 4. Calculate
P
Ppr
Step 5. Calculate Cg
Z
950
1.46 0.74
7
100
0
1.54 0.72
5
105
0
1.62 0.71
1
= 0.725
1 Psi = 6.895
Kpa
1
Rn = 0.556
VISCOSITY OF GAS
Viscosity of a fluid is endurance of fluid for flow.
Gas viscosity is a measure of the resistance to flow exerted by the gas and is given in units of
centipoises (cp). Higher values indicate more resistance to flow.
Experimental determination of gas viscosity is difficult. Usually it is not measured but is obtained
from correlations, which include corrections for H2S, CO2, and N2.
Gas viscosity is used in numerous equations, most notably in the definitions of pseudo-pressure and
pseudo-time.
CARR-KOBAYASHI-BURROWS METHOD
Carr, Kobayashi, and Burrows (1954) developed graphical correlations for
estimating the viscosity of natural gas as a function of temperature, pressure,
and gas gravity.
Example:
Solution:
Componen
t
yi
C1
0.850
C2
0.055
C3
0.035
C4
0.010
Calculate the gas viscosity at
3000 psia and 150 degree
Farenheit
yi
MWi yi.MWi
Tci
yi.Tci
Pci
Yi.Pci
673
572.05
C2
0.055 30.07
1.654
550.1 30.2555
708
38.94
C3
0.035 44.09
1.543
666.2 23.317
617
21.595
C4
0.01 58.12
0.581
765.6
551
5.51
Ppc
638.095
MWa
Tpc = 355.204
Ppc = 638.095
17.412
7.656
Tpc 353.204
CARR-KOBAYASHI-BURROWS METHOD
Step 2 : Calculate the viscosity natural gas at 1 atm use figure
Mwa
= 17.412
T = 150 Degree
= 0.0119
Farenheit
cp
Step 3 : Calculate Ppr &
Tpr
CARR-KOBAYASHI-BURROWS METHOD
Step 4 : Estimate the viscosity ratio from
figure
CARR-KOBAYASHI-BURROWS METHOD
(MIXTURE COMPONENT NON HIDROKARBON)
Example
Component
yi
N2
0.05
CO2
0.05
H2S
0.02
C1
0.8
C2
0.05
C3
0.03
Componen
t
N2
CO2
H2S
C1
C2
C3
yi
Mwi
yi.Mwi
0.05
0.05
0.02
0.8
0.05
0.03
28.02
44.01
34.08
16.07
30.07
44.09
Tc
Mwa 19.9653
Tpc
Tpc = 374.51 Rn
Ppc = 696.51 Psi
yi.tci
374.51
Pc
Ppc
yi.Pc
24.655
53.55
26
538.4
35.4
18.51
696.515
CARR-KOBAYASHI-BURROWS METHOD
(MIXTURE COMPONENT NON HIDROKARBON)
Mwa
= 19.965
T = 200 Degree
= 0.0124
Farenheit
cp
CARR-KOBAYASHI-BURROWS METHOD
(MIXTURE COMPONENT NON HIDROKARBON)
Step 4 : Estimate
Compone
nt
N2
yi
% yi
0.05
5%
CO2
0.05
5%
H2S
0.02
2%
= 0.0004 cp
= 0.0002 cp
= 0.00005 cp
CARR-KOBAYASHI-BURROWS METHOD
(MIXTURE COMPONENT NON HIDROKARBON)
T1.719
CARR-KOBAYASHI-BURROWS METHOD
(MIXTURE COMPONENT NON HIDROKARBON)
T1.719
TUGAS
TUGAS
1. Apakah yang dimaksud centipoise? Dan bagaimana
turunannya?
2. Jika pressure reservoir dan temperature 2500 psia dan 175 derajat Farenheit,
Hitung Z factor (Carr-Kobayashi-Burrows method), SG, Bg (Ft 3/Scf), Cg ideal dan real
gas, dan
jika mengikuti komposisi gas:
Component
yi
CO2
0.06
N2
0.03
C1
0.75
C2
0.07
C3
0.04
n-C4
0.03
n-C5
0.02
!
For your attention
Thank you