Kelompok 4

12.8
12-8 A liquid-phase reaction A + B + C is conducted in a 50-L
batch reactor. The reaction is first-order with respect to each
reactant.
(a) Determine the time required for 90% conversion of A, if(i) the
reaction occurs adiabatically;(ii) the reaction occurs isothermally
at T,.
(b) Determine d and T, (as functions of time), if a cooling coil is
placed in the tank to maintain the isothermal conditions required
in (a) part (ii).
(c) For (a) part (i), sketch the conversion-versus-time and
temperature-versus-time profiles.
Data: CA0 and CBO are 0.50 mol/L and 0.75 mol/L, respectively.
The initial temperature (Ti) is 400 K, and the heat capacity of the
reactor contents is 3.8 J /g K. The fluid density is 0.75 g /cm 3, and
the heat transfer parameter (UAc) for part (b) is 100 W/K. The
reaction is exothermic (- 145 kJ/mol A and

Diketahui

:
Cao dan Cbo = 0,5 dan 0,75
To = 400 K
Ka =
Cp = 3,8 J/g.K
UA = 100 W/K

A + B
0,5
0,5XA

0,75

0,5XA

0,5(1-XA) 0,75-0,5XA

0,5XA
0,5XA

 Adiabatik Q=0

KEADAAN

ISOTERMAL

Example 15.4
A liquid-phase reaction A + B
2C is conducted in a non
isothermal multitubular PFR. The reactor
tubes (7 m long, 2
cm in diameter) are surrounded by a coolant which
maintains a constant wall temperature. The reaction is
pseudo-first-order with respect to A, with kA = 4.03 X l05 e5624/T
/s. Th e mass flow rate is constant at 0.06 kg/s, the
density is constant at 1.025 g/cm3, and the temperature at
the inlet of the reactor (T,) is 350 K.
(a) Develop expressions for dXa/dx and dT/dx.
(b) Plot f*(x) profiles for the following wall temperatures (T,):
350 K, 365 K, 400 K, and 425 K.

Data: CA0 = 0.50 mol/L; cp = 4.2 J/g K ;HRA = -210

kJ/mol

 Dik:

Dit:

L= 7m
a. dXa/dx dan dT/dx
d= 2cm
b. Plot grafik antara Xa dg T
kA = 4.03 X l05 e-5624/T /s
m= 0.06 kg/s
CA0 = 0.50 mol/L
cp = 4.2 J/g K
HRA = -210 kJ/mol
U = 1.59 kW/ m2 K
Ti=350K

Penurunan dXa/dx
A

CAO CBO CAO.XACAO.XACAO.XA

CAO(1-XA)

CB0-(CAO.XA) CAO.XA

(
(=
(

(2)
(3)

(4)

Substitusi persamaan (1) ke (4)

=

(5)

Karena r2 = D2/4 sehingga persamaan

menjadi
=

(6)

Penurunan rumus dT/dx

Neraca Energi

-dH + dQ+ Generasi = 0

-mCp dT + U (Ts-T)dAp + (-) (- ) dV = 0
dAp =
dV= D2

Eq 15.2.7

Eq 15.2.5

 Subsitusi persamaan 15.2.6 dan 15.2.7 ke

persamaan 15.2.5
Sehingga persamaan menjadi:
-mCp dT + U D (Ts-T) (-) (- ) D2 = 0
mCp dT = U D (Ts-T) (-) (- ) D2 x
= +
Dari persamaan di atas (

 Sehingga persamaan akhir menjadi :

= +

Grafik
0.03

0.03

0.02
350
365

0.02

400
425
0.01

0.01

0
0