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Properties
of
CONTENTS
INTRODUCTION
1-2
MECHANICAL PROPERTIES
3-7
MAGNETIC PROPERTIES 8-
14
Nanotechnologyis the
collaboration of the
physics
,chemistry,biology,computer
and material sciences
integrated with engineering
entering the nanoscale.This
means science and
engineering focused on
making the particles,things
and devices at the atomic
and molecular scale.
1
Classification of Nanomaterials
Mechanical Properties
Magnetic Properties
Optical Properties
Electrical Properties
2
MECHANICAL PROPERTIES
Tensile test
Determination of
mechanical properties
Stress: = F/S
Strain: = l / l0
Stress,
(Mpa)
Max Necking
stress :
Maxtensile
elasticity:
strength Fract
Yield ure
strength
Strain,
Elastic Plastic (%)
deformation deformation
3
Elastic
Deformation Hookes law: = E
E = Young modulus
(Pa)
Stress,
Stiffness of material
Modulus = slope
Mechanical properties
Hardness
4
Nanostructured materials
Nanoparticles
Comparison:
Al Mg cryomilled
(20 nm)
Al Mg ultra fine
grain (80 nm)
Al Mg coarse (2
mm)
Cryomilling: Milling
in liquid N2
Ultrafine grain:
electrodeposition
5
Mechanical properties of nanomaterials
compared to coarse grain materials
More brittle
Strength and
Hardness of
nanostructured
material
increases with
decreasing size
Grain boundaries
deformation
6
Elongation nanostructured materials
Elongation decreased
Lower density of
mobile dislocations
Short distance of
dislocation movement
Rubber 0.1
Al 70
Fe 200
SiC 440
Diamond 1200
7
MAGNETIC PROPERTIES
Magnetic properties of nanoparticles
8
Apoferritin,
Quaternary structure of the protein.
your bodys The pieces make an open cavity
iron storage that can store thousands of Fe
protein and atoms
precision
magnetic
system.
Types of Magnetism
(Sibel Turksen Thesis)
9
General Hysteresis Plot
Magnetization
M
Magnetization
-M
in opposite direction
I think of the
superparamagnet as a
small ferromagnet.
Because of its small size,
the magnetic moment
wanders. When given an
order to align (when a
magnetic field is imposed)
it aligns with the same
enthusiasm that a
ferromagnet has, which 1
exceeds that of the 0
paramagnet.
Like the paramagnet, the superparamagnet
returns to zero magnetization when the field is
removed. It does so for a different reason: small
size, not intrinsically weak exchange between
the individual moments.
Superparamagn
Paramagne Ferromagn
et t et
Zero field
Applied
field
In a normally ferromagnetic
material, nano scale reduces the
moment, but it can be restored by
applying a magnetic field.
Stabilization
a) By surface coating using appropriate polymeric
stabilizers/surfactants (carboxylates, phospates,
cathecols)
b) By deposition of a layer of inorganic metals (e.g.,
gold), nonmetals (e.g., graphite), or oxides (e.g.
SiO2)
c) By generating polymeric shells that avoid cluster
growth after nucleation (composite particles,
nanocapsule).
d) By the formation of lipid-like coatings (e.g.,
liposomes/ lipid NPs) around the magnetic core.
1
2
MRI imaging
a) SPIO affects T2
b) Gd3+ affects T1
c) Core-shell nanoparticle
enable both imaging
modes.
T1 spin-lattice relaxation
T2 spin-spin relaxation
1
3
Suppose some particles do have magnetic moments.
N S N S N S N S
Magnetorheological effect.
Magnetorheological Effect
A magnetic fluid.
Metallic sphere
EM wave
15
Calculation of SP Frequency
Effective conductivity of
a composite of Drude
metal and insulator:
dots, numerical; full
curves, effective-
medium approximation.
16
Nonlinear optical properties of nanomaterials
1
8
ELECTRICAL PROPERTIES
Quantum confinement
In small nanocrystals, the electronic energy levels are not continuous as
in the bulk but are discrete (finite density of states), because of the
confinement of the electronic wavefunction to the physical dimensions of
the particles. This phenomenon is called quantum confinement and
therefore nanocrystals are also referred to as quantum dots (QDs).
In any material, substantial variation of fundamental electrical and optical
properties with reduced size will be observed when the energy spacing
between the electronic levels exceeds the thermal energy (kT).
Moreover, nanocrystals possess a high surface are and a large fraction
of the atoms in a nanocrystal are on its surface. Since this fraction
depends largely on the size of the particle (30% for a 1-nm crystal, 15%
for a 10-nm crystal), it can give rise to size effects in chemical and
physical properties of the nanocrystal.
19
Electronic band theory
Conduction
band
(empty)
band gap
band gap
Valence
band
(full)
21
Here we are to discuss about fundamentals of electrical
conductivity in nanotubes and nanorods, carbon nanotubes,
photoconductivity of nanorods, electrical conductivity of
nanocomposites. One interesting method which can be used
to demonstrate the steps in conductance is the mechanical
thinning of a nanowire and measurement of the electrical
current at a constant applied voltage. The important point
here is that, with decreasing diameter of the wire, the
number of electron wave modes contributing to the electrical
conductivity is becoming increasingly smaller by well-defined
quantized steps. In electrically conducting carbon nanotubes,
only one electron wave mode is observed which transport the
electrical current. As the lengths and orientations of the
carbon nanotubes are different, they touch the surface of the
mercury at different times, which provides two sets of
information: (i) the influence of carbon nanotube length on
the resistance; and (ii) the resistances of the different
nanotubes. As the nanotubes have different lengths, then
with increasing protrusion of the
fiber bundle an increasing number of carbon nanotubes will
touch the surface of the mercury droplet and contribute to
the electrical current transport.
2
2
Electrical conductivity of bulk metals is based on their
electronic band structures, and the mobility of
electrons is related to their mean free path between
two collisions with the lattice. The collective
motion of electrons in a bulk metal obeys Ohms law, V =
RI, where V is the applied voltage, R is the resistance
of the material and I is the current. As the electronic
band structure changes into
discrete energy levels, Ohms law is no longer valid. If one
electron is transferred to a small particle, the Coulomb
energy of the latter
increases by E C = e^2 /2C, where C is the capacitance of
the particle. If the temperature is low such that kT < e
2 /2C, single electron tunneling processes are
observed.*
* Thermal motion of the atoms in the particle can initiate a
change in the charge and the Coulomb energy so that
further electrons may tunnel uncontrolled
Hence, the I-V characteristic of a quantum dot is not
linear, but staircase-like. No current flows up to V C =
e/2C. If this value is reached, an electron can be
transferred. Following this,
an electron tunnelling process occurs if the Coulomb
energy of the particle is compensated by an external
I-U characteristic of ideal
voltage of V = ne/2C. This behaviour is called
single electron transport,
Coulomb blockade. The where Coulomb blockade is
charging energy increases with decreasing thestep
shown as the size of the
function.
quantum dot.
23
Experimental approaches to measure the Coulomb
blockade.
Two metallic leads with spacing of a few nm are
fabricated. An organic
monolayer is then used to bind nanocrystals to the leads.
When a nanocrystal
bridges the gap between the leads, it can be electrically
investigated.
24
(a) IV characteristic of an isolated 3.3 nm Pd nanocrystal (dotted
line) and the theoretical fit (solid line) obtained at 300 K using a
semiclassical model. (b) The size dependence of the charging energy.
25