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MULTIPHASE
REACTORS
Clicker Questions:
i) What do , and represent?
ii) What do A and A represent?
Before we take a look at mass
balance equations for multiphase
reactors, I suggest you refresh
yourself on mass balance equations
for single-phase reactors. This will
give you better understanding on
the mass balance equation for
multiphase reactors. Refer to
Schmidt book:
i) Batch reactor (pg. 38-39)
ii) PFTR (pg. 51-52)
iii) CSTR (pg. 86-89)
Mass Balance in Multiphase Reactor
(cont.)
Mass balance for phase if the fluid is unmixed (i.e.: in PFR):
???
-
Residence time in and phase: ???
V V
;
V
L
In PFR:
u
**All equations valid for no density change system reactor
Mass transfer between
phases
Mass transfer to or from a mixed phase
Mass transfer for phase in contact with phase in CSTR
Aj as
The mass transfer can be regarded
A reversible
j surface reaction:
A A A
r r " r " k m (C j C j )
V V V
Cont
A
At steady state C A 0 C A r
k m (C
A C
A)
V
dC j A
u
dz
ij ri V
k m (C j C j )
In unmixed phase:
r" k m (C A K eq
CA )
Concentration gradient in the vicinity
of the interface is the driving force of
the mass transfer
However this driving force for mass transfer of a species disappears when
the partial pressure of the species in the gas is in equilibrium with the
concentration of the liquid phase. The equilibrium is conveniently expressed
as Henrys Law: At a constant temperature, the amount of a given gas that
dissolves in a given type and volume of liquid is directly proportional to the
partial pressure of that gas in equilibrium with that liquid.
or
Pj = H j x j yjPT = H j x j
Gas-liquid multiphase reactors.
Falling Film Reactor (FFR)
Consider a vertical tube of length L and
diameter D0 with liquid admitted at the top
such that it forms a falling film that coats
the wall tube.
Gas was added into the top of the tube
(co-current) or into the bottom (counter- L
current) wetted wall column.
Assume the liquid falls with a constant
average velocity (ul) and forms a liquid film
of thickness R0 Ri (Ri = radius in the tube
at the surface of the liquid film).
If the liquid film thickness is constant, the
cross section occupied by the gas is
constant and the velocity of the gas (ug) is
independent of position z if the density of
gas is constant.
Falling Film Reactor (FFR)(cont.)
The gas will occupy a cross sectional area:
Ri2
The liquid will occupy a cross-sectional area:
(R02 Ri2 )
The volumes occupied by the phases are:
V (R R )L
l 2
0 i
2
V R L
g
i
2
L V l
( R 2
R 2
i )L
l l
l 0
u l
L V g
R 2
i L
g g g
g
u
Falling Film Reactor (FFR)(cont.)
Consider the following reaction: A B C D
g l g l L
Lets assume the following:
Reactions are irreversible
Products can easily escape from the phases, so the spesific
products are not important to know.
the reaction occurs only in the liquid phase (no reaction in
gas phase): r l k C l C l ; r g 0
l A B
The rate of mass transfer per unit area is: rmA k mA (C Ag K gl C Al )
Area of interface: 2R L
i
dC Al
l l l l 2Ri g gl l
u k C ACB k m (C A K C A)
dz (R0 - R i )
2 2
Reactor volume is proportional to R02 while the surface area
for mass transfer is proportional to R, the falling film column
will be less efficient for larger reactor sizes.
12 m
dRb
4Rb2 k m 4Rb2 (C A C As )
dt
Practice Questions for BCR
1) Answer all questions (a to d) in Example 12-2 page 496 Schmidt.
2) Question 3 c) Final Paper CPE624 June 2014
Answer: V = 137.5 m3
Practice Questions for BCR (cont.)
3) Question 2 c) Test 2 June 2015 CHE625