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Nucleation
Growth
APPLICATIONS
Transformations in Steel
Precipitation
Recovery, Recrystallization & Grain growth
PHASE TRANSFORMATIONS
Based on
order
1nd order 2nd order
nucleation & growth Entire volume transforms
Bulk Gibbs free energy
Growth
Nucleation
Trasformation till
= of + is
phase
exhausted
Liquid Solid phase transformation
G
Solid (GS)
G ve
G
T Liquid (GL)
G +ve
Tm For sufficient
T Undercooling
T - Undercooling
Solidification = Nucleation + Growth
Nucleation
Homogenous
Nucleation
Liquid solid
walls of container, inclusions
Heterogenous
Solid solid
inclusions, grain boundaries,
dislocations, stacking faults
The probability of nucleation occurring at point in the parent phase is
same throughout the parent phase
In heterogeneous nucleation there are some preferred sites in the
parent phase where nucleation can occur
Growth
Trasformation Nucleation
till
= of +
is
phase
exhausted
Growth
At transformation temperature the probability of jump of atom from
(across the interface) is same as the reverse jump
Growth proceeds below the transformation temperature, wherein the activation
barrier for the reverse jump is higher
Hd
Hd vatom Gv
phase
phase
Time Temperature Transformation (TTT) diagrams A type of phase
diagram
Small driving
force for nucleation
Tm Tm
T
T (K)
T (K)
Time for transformation
Replot
0 0
T (rate sec1) t (sec)
Growth
sluggish
TTT diagram phase transformation
Increasing % transformation
T (K)
99% = finish
1% = start
t (sec)
APPLICATIONS
Precipitation
Eutectoid + Fe3C
+ Fe3C
723C
0.025 %C + Fe3C
T
Fe Fe3C
0.16 0.8 4.3 6.7
%C
Time- Temperature-Transformation (TTT) Curves Isothermal Transformation
Eutectoid steel (0.8%C)
800
Eutectoid temperature
723
Austenite Coarse
600 Pearlite
Fine
400 Bainite
Not an isothermal
300
200
Ms
Austenite
transformation
Mf
100
Martensite
0.1 1 10 102 103 104 105
t (s)
Time- Temperature-Transformation (TTT) Curves Isothermal Transformation
Eutectoid steel (0.8%C)
800
Eutectoid temperature
723
Austenite
Pearlite
600
+ Fe3C
500 Pearlite + Bainite
T
400 Bainite
300
Ms
200
Mf
100
Martensite
0.1 1 10 102 103 104 105
t (s)
Continuous Cooling Transformation (CCT) Curves Eutectoid steel (0.8%C)
800
Eutectoid temperature
723
400
300
Ms
Cooling curves 200
Constant rate Mf
100
Martensite T1 T2
0.1 1 10 102 103 104 105
t (s)
Different cooling treatments Eutectoid steel (0.8%C)
800
723
M = Martensite 600
Water qu
P = Pearlite 500
Fu
No
ll a
T
rm
400
nne
ali
ench
zin
al
300
Oi
g
lq
uen
200
Coarse P
ch
100
M M +P Fine P
[1] [1]
+ Fe3C
[1] Physical Metallurgy for Engineers by Donald S Clark and Wilbur R Varney (Second Edition) Affiliated EastWest Press Pvt. Ltd., New Delhi, 1962
Bainite
[1] [1]
Bainite formed at 348oC Bainite formed at 278oC
+ Fe3C**
Nucleation and growth
Acicular, accompanied by surface distortions
** Lower temperature
carbide could be carbide (hexagonal structure, 8.4% C)
Bainite plates have irrational habit planes
Ferrite in Bainite plates possess different orientation relationship
relative to the parent Austenite than does the Ferrite in Pearlite
[1] Physical Metallurgy for Engineers by Donald S Clark and Wilbur R Varney (Second Edition) Affiliated EastWest Press Pvt. Ltd., New Delhi, 1962
Martensite ( FCC ) Quench ' ( BCT ) Possible positions of
0.8 %C 0.8 %C Carbon atoms
Only a fraction of
the sites occupied
FCC
Austenite
Harness of Martensite as a
function of Carbon content
40
20
% Carbon
0.2 0.4 0.6
T
400 Bainite
300
Ms
Austempering 200
Mf
100
AUSTEMPERING Martensite
Various elements like Cr, Mn, Ni, W, Mo etc are added to plain carbon
steels to create alloy steels
The alloys elements move the nose of the TTT diagram to the right
this implies that a slower cooling rate can be employed to obtain
martensite increased HARDENABILITY
The C curves for pearlite and bainite transformations overlap in the
case of plain carbon steels in alloy steels pearlite and bainite
transformations can be represented by separate C curves
ROLE OF ALLOYING ELEMENTS
Interstitial
Segregation / phase separation
Solid solution Substitutional
Element Added
Compound (new crystal structure)
hardenability
Provide a fine distribution of alloy carbides during tempering
Alloying elements resistance to softening on tempering
corrosion and oxidation resistance
strength at high temperatures
Strengthen steels that cannot be quenched
Make easier to obtain the properties throughout a larger section
Elastic limit (no increase in toughness)
Alter temperature at which the transformation occurs
Alter solubility of C in or Iron
Alter the rate of various reactions
TTT diagram for Ni-Cr-Mo low alloy steel
800
Austenite Pearlite
600
500
T
400
300 Bainite
Ms
200
Mf
100
Martensite
~1 min
t
Precipitation
The presence of dislocation weakens the crystal easy plastic deformation
Putting hindrance to dislocation motion increases the strength of the crystal
Fine precipitates dispersed in the matrix provide such an impediment
Strength of Al 100 MPa
Strength of Duralumin (Al + 4% Cu + other alloying elements) 500 MPa
Al rich end of the Al-Cu phase diagram
L
600
T (C)
400
Sloping Solvus line
high T high solubility
200
low T low solubility
of Cu in Al
Al 15 30 45 60
% Cu
+
Slow equilibrium cooling gives rise to
+ coarse precipitates which is not good
in impeding dislocation motion.*
4 % Cu
*Also refer section on Double Ended Frank-Read Source in the chapter on plasticity: max = Gb/L
To obtain a fine distribution of precipitates the cycle A B C is used
A C
4 % Cu
A Heat (to 550oC) solid solution
supersaturated solution
B Quench (to RT)
Increased vacancy concentration
180oC
20oC
Log(t)
Hardness
Coarsening
Dispersion of of precipitates
fine precipitates with increased
(closely spaced) interparticle spacing
Underaged Overaged
Log(t)
Region of precipitation
Region of solid solution hardening
strengthening (but little solid solution
(no precipitation hardening) strengthening)
180oC Peak-aged
In
s)
Hardness -c
ne
oh
er
zo
e nt
P
(p
(G
re
cip
nt
re ita
te
he
s)
Co
Log(t)
CRSS Increase
Particle
shearing
Particle
By-pass
r f (t )
1 1
r
2
r
Particle radius (r)
Due to large surface to volume ratio the fine precipitates have a tendency
to coarsen small particles dissolve and large particles grow
Coarsening
in number of particles
in interparticle spacing
reduced hindrance to dislocation motion (max = Gb/L)
Recovery, Recrystallization & Grain Growth
Plastic deformation in the temperature range (0.3 0.5) Tm COLD WORK
dislocation density
Point defects and dislocations have strain energy associated with them
(1 -10) % of the energy expended in plastic deformation is stored in the
form of strain energy
dislocation ~ (10 10 )
6 9
dislocation ~ (1012 1014 )
point defect density
Material tends to lose
Cold work Anneal the stored strain energy
dislocation density
Increase in strength
of the material Softening of the material
Low temperature
Recovery
Recrystallization
High temperature
Cold work Anneal Recovery
Recrystallization
Grain growth
Strength
Hardness
Cold work
Electrical resistance
Ductility
Bent crystal
Po
lyg
on
iza Low angle grain boundaries
tio
n
Recrystallization
Region of lower
Region of higher dislocation density
dislocation density
Direction of grain
boundary migration
Further points about recrystallization
Hot Work
Globally
Driven by reduction in grain boundary energy
Locally
Driven by bond maximization (coordination number maximization)
Bonded to
4 atoms
Bonded to
3 atoms
Direction of grain
boundary migration JUMP
Tensile strength
http://www.asminternational.org/documents/10192/1849770/ACF180B.pdf
Distribution of Alloying Elements
In alloy steels, alloying elements can be found,
1.in the free state
2.As intermetallic compounds with iron or with each
other
3.As oxides, sulphides, amd other nonmetal
inclusions
4.In the carbide phase as a solution in cementite or
in the form of independent compounds with carbon
5.As a solution in iron
Alloying elements ma be divided into two
groups:
1.Elements that do not form carbides in
steel, such as Ni, Si, Co, Al, Cu and N
2.Elements that form stable carbides in
steel, such as Cr, Mn, Mo, W, V, Ti, Zr, and
Nb
Alloying elements
Whose affinity for oxygen is greater than
iron, are capable to forming oxides and
other nonmetal compounds. (Al, Si, V, Ti)
and become fine nonmetal inclusions.
80 A: austenite
B: bainite
60
M: martensite
40 P: pearlite
20
0
1 10 100
Example Problem
80
60
40
20
0
1 10 100
A
The time-temperature-transformation diagram
for an iron-carbon alloy of eutectoid composition
and the isothermal heat treatments
Example Problem
(a) Rapidly cool to 250C,
hold for 100s, and quench
to room temperature