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Use of TPE in a variety of fields is still
Production of Tetraphenylethylene Significant environmental risks exist in the
proposed TPE production route. Small
being researched further. In the Bradley Siefker, Raymond Schratz, amount of chemical release poses a risk to
biomedical imaging field TPE has the
potential to be used as a metal-free
David Devlin, Trevor Langton have disastrous and long term effects on the
environment. Any solid or liquid component
fluorescent biomarking chemical Dr. Amy Ciric released must be quarantined immediately to
backbone. Additional applications may prevent runoff and exposure to animal life.
exist as a coating to improve solar cell Project Criteria All chemicals used may pose some
efficiencies and in OLED TVs. Mostly Production Rate: 10,000 tons/year Purity: >99.5% Constraints: Metal-Free Product significant environmental risk and
a commodity chemical at present with emphasize the need for proper release
unit costs of $657/kg. Proposed Production Flow Sheet controls.
List Significant Chemical Hazards
Hazard Code Hazard Meaning Relevant Chemicals
H300 Fatal if swallowed PCl3 , POCl3
H301 Toxic if swallowed Nickel-Glyme
H330 Fatal if inhaled PCl3 , PCl5 , POCl3
H331 Toxic if inhaled Cl2
H350/H351 May cause cancer Nickel-Glyme , Benzophenone
H372/H373 Damage to organs from PCl3, PCl5 , POCl3
repeated exposure
List of Acute Chemical Exposure Hazard Limits
Toxicity Test Cl2 PCl3 PCl5 Benzophenone POCl3
LC50 Inhalation 293 ppm 0.586 ppm 24 ppm - 32 ppm
1 hour 4 hours 4 hours 4 hours
LD50 Dermal - - - 3,535 -
(mg/kg)