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ter 3
:
OXIDATION
AND
REDUCTION
Redox Reaction :
Oxidation Reduction
1. Gain of oxygen 1. Loss of oxygen
2. Loss of hydrogen 2. Gain of hydrogen
3. Increase in oxidation 3. Decrease in oxidation
number number
4. Loss of electrons 4. Gain of electron
REDOX REACTIONS
Defined as reaction in which both Oxidation and
Reduction occur simultaneously.
Reducing agent:
Chemical substance that causes reduction
in another substance and itself is oxidised
oxidation
Reduction
Oxidising agent:
Chemical substance that causes oxidation in another
substance and itself is reduced
Reducing agent:
Causes reduction in another substance.
Itself oxidised
oxidation
Zn + CuO ZnO + Cu
Reduction
Oxidising agent:
Causes oxidation in another substance
Itself reduced
EXAMPLE :
Oxidation
Reducing
Agent Mg (s) + H2O (g) MgO (s) + H2 (g)
Reduction
Oxidising agent
Activity 1 :
Write a balance chemical equation for each equations given
below. Then identify the oxidation, reduction, oxidising agent
and reducing agent for each equations.
a. Iron(II) oxide + carbon monoxide iron + carbon dioxide
b. Ammonia + copper(II) oxide nitrogen + water +copper
3. OXIDATION NUMBER
An arbitrary charge assigned to the element according to a
set of rules. Oxidation no also known as the oxidation state
Mg2+ +2 O2- -2
CaCO3
Na2SO4
(+6) + 4(-2) = -2
2(+6) + 7(-2) = -2
e. In compounds, the more electro negative elements are
given a negative [O] number.
I , Br , Cl , N , O , F
electro negativity increases
example:
F2O
BrF3
2(-1) (+2)
NaIO3 (+3) 3(-1)
Metal hydrides:
NaH AlH3
peroxide:
H2O2 BaO2
a.CrCl3
b.NaMnO4
c.NaClO3
d.Au(OH)4 -
e.CuCl4 3 -
Naming of Compound based on IUPAC
system
1. For the compound that consists a metal that have more
than one oxidation number it is mention in a bracket
after the elements name.
Oxidation : Reduction :
Increase in oxidation number decrease in oxidation number
O +3
2 Fe(s) + 3Cl2 (g) 2FeCl3 (s)
O -1
REDUCTION
Oxidising agent Decrease in oxidation number
Example
2Mg + O2 2MgO
Example :
+1 +1 +1 -2 +1 -2 +1
-2 +6 +6 -2
[O] : [R] :
Loss of electrons Gain of electrons
example:
2Na + Cl2 2NaCl
Zn + 2HCl ZnCl2 + H2
reduction
Gain of e-
Half equations:
Zn Zn2+ + 2e- (oxidation)
2H+ + 2e- H2 (reduction)
Ionic equations: Zn + 2H+ Zn2+ + H2
Oxidation agent : H+
Reduction agent : Zn
Balancing Half Equations For
Oxidation and Reduction
Mg
More ZnSO4
electropositive
metal Zn2+ ion in the salt
solution
(less electropositive)
OXIDATION
oxidized to its metal ions
REDUCTION
Donates electron reduced to its metal
(act as reducing agent) receives electron
(act as oxidizing
agent)
DISPLACEMENT OF ZINC BY MAGNESIUM
FROM ZINC SUPLHATE SOLUTION
Mg is more electropositive than zinc. Mg displaces
zinc from its salt.
oxidition Loss of e-
Mg + ZnSO4 MgSO4 + Zn
reduced Gain of e-
Half equations :
Mg Mg2+ + 2e- (oxidation)
Zn2+ + 2e- Zn (reduction)
1. Mg is more electropositive than Zn.
2. Mg atom undergoes oxidation by donate 2
electrons to Zn2+ ion.
3. Half equation : Mg Mg2+ + 2e-
4. Mg act as reducing agent.
5. Zn2+ ion undergoes reduction by receive 2
electron from Mg atom.
6. Half equation : Zn2+ + 2e Zn
7. ZnSO4 / Zn2+ act as oxidising agent.
8. Oxidation and reduction occurs in same reaction,
so it is a redox reaction.
Try .
Copper metal and Silver nitrate solution
Example : 2 cm3 of
chlorine
I2 + KBr
The colour of Halogens in Water
Halogen aqueous solution
Chlorine Greenish-yellow
Bromine Reddish Brown
Iodine Brown
Example :
Oxidizing Agent : acidified potassium manganate (VII)
solution
Oxidising
agent
Reduction Gain of e-
Oxidation Loss of e-
NEGATIVE POSITIVE
terminal terminal
Salt bridge:
Dilute Sulphuric acid
U-tube
Sodium @ potassium chloride
Sodium @ potassium nitrate
Example : Reaction of iron(II) Sulphate and
Acidified potassium manganate(VII) solution
Observation :
NEGATIVE terminal POSITIVE terminal
-ve
FeSO4 Solution: green brown
Oxidation
acidiedKMnO4 : purple colourless
Reduction
FeSO4 acidied
KMnO4
acidied
KI
KMnO4
[o] : 2I- I2 + 2e-
[r] : MnO4- + 8H+ + 5e- Mn 2++ 4H2O
Salt bridge:
Dilute Sulphuric acid
U-tube
RUSTING AS A REDOX REACTION
Rusting is the corrosion of iron
2 condition for rusting to occur :
The presence of air (oxygen)
The presence of water
O2 O2 O2
O2
+ve terminal
+ve terminal e- e-
(cathode)
O2 + 2H2O+4e- 4OH-
O2 + 2H2 O+4e- 4OH-
Terminal -ve
Fe Fe2+ + 2e-
Anode : Fe Fe2+ + 2e- [oxidation]
O
Cathode : 2 + 2H2O +4e - 4OH- [reduction]
Ag Non-reactive metals
Au
Exists in element form in earth crusts
In extraction of metal carbon in form of coke
is used because
1. Carbon more reactive than zinc, iron ,
tin and lead. Carbon easily reduce
the oxide of these metals
Heated with coke and limestone in blast Molten tin is drained off
furnace into moulds to become tin
block
SnO2 (s) + 2CO (s) Sn (s) + 2CO2 (g)
SnO2 (s) + 2C (s) Sn (s) + 2CO2 (g)
SnO2 (s) + C (s) Sn (s) + CO2 (g) Calcium oxide from the
limestone eliminates the
Reduction of tin(IV) oxide by carbon
monoxide and coke remaining impurities to slag
Redox Reactions in Electrolytic And
Chemical Cells
copper zinc
Cell A Cell B
Electrolysis Voltaic cell
Oxidation and Reduction in Electrolytic Cells
Electrolytic cell Half equation Observation
Electolysis of sulphuric acid with Anode [O]: Anode :
carbon electrode Cathode :
Ions present :__________ Solution :
Cathode [R]:
Electrolysis of copper (II) sulphate Anode [O] : Anode :
with carbon electrode Cathode :
Ions present :__________ Solution :
Cathode [R]: