,

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2NO + O 2 2NO 2 G 0 = 157 ,

2H 2 + O 2 2H 2 O G 0 = 456 ,

(1) ,
(2) .

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:
+ + DD

1 dC A 1 dCB
V
A d B d
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C d D d

CA + + DD
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t 2 t1 t

C1
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t1 t2 t

-


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1.
2.
3.

4.
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= k CAnA CBnB ,

,
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n = nA + nB
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-

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K,


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d
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1) ()
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- dC/ (C0/2) = k dt
ln (C0 / (C0/2) = k t => t = ln2 / k

2)

ln ( C0 / (C0 Co) ) = k t => t = ln (1 / (1-) ) / k

3)
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A2 + B2 2AB - Ea [ 60 - 240]

A + A A2 , Ea [ 1- 60 ]

A+ + - AB , Ea [ 0; ]



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I I

= 168 . = 571


E
k A RT

Ea 1
ln k ln A
R T
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2-4
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n = (2 1)/10

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2 KClO3 2 KCl 3O2

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 :
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l + l > l2
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.

-
CH2(COOH)2 + 4H2O2MnSO ,KIO
3CO2 + 6H2O
4 3

2 3
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2 2

H2O2 H2O2
I2

I2
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1 (III),
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HO(O)C-CH(Br) C(O)OH.

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62 + 62 + n h 6126 + 62
-



>> 1
H2 + Cl2 = 2HCl = 105
 . 7.
1.
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)

1) H() + CH3() CH4()

2) HI() + C2H4() C2H5I()

: ) 1) = 1-60
) 2) -
= 100-160
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.
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.

2() + 2NO() 2NO2 [NO]

4

1 = kC2CNO2
n2=1; nNO=2; n.= n2+ nNO = 3 =

2 = kC 2(4CNO)2 = 16 1

: 16 .
.
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+
, .

20 ,
- () 2.

, % k, .-1
45 0,066
= 0,45 0 =>
1 = (1/k)ln [C0 /(0-0,45C0)] = (1/0,066)ln1,82 = 0,91 .

2/ 1 = 20/10 = 22=4 =>

2 = 0,91/4 = 0,23 .

: 0,91 .; 0,23 .