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Presented By:
Ryan Mcparland & Niket Vasavada
Introduction
The interface bonding between untreated CF and resin matrix limits the excellent
performance of carbon fiber composite, due to the large surface inertia of carbon
fiber.
Therefore surface treatment techniques have been carried out on CF to improve
the mechanical properties of the fibers/epoxy composites without sacrificing tensile
strength of base fibers.
Carbon Black (CB) was introduced onto the surface of CFs by chemical vapour
deposition (CVD).
The paper addresses an effective method of depositing CB on the surface of CFs
and observe the change in mechanical properties of the CFs.
Previous Methods to increase Carbon Fibre
composites
The interface bonding between untreated CF and resin matrix limits the excellent
performance of carbon fiber composite, due to the large surface inertia of carbon
fiber.
Treating the surface of Carbon Fiber:
Chemical Grafting
Electrochemical Method
Plasma Treatment
All methods generate oxygen based functional groups which create a decrease in
the base fibres tensile strength.
Thermal Chemical Vapour Deposition
CF-X 1000C
Gas
N2 (400 sccm) + C2H5OH (20 ml/h) Outlet
Nitrogen
Ethanol
Untreated = 43.6 nm
CF-5 = 54.8 nm
CF-10 = 60.2 nm
The paper proves that by growing CB on the surface of CFs by using CVD, that there is a direct improvement
to the mechanical properties of the fibres/epoxy composites without sacrificing tensile strength.
The experimental results suggest that CB could not only increase surface energy, wettability and CF surface
roughness, but also cover the defects of CF surface.
Compared with untreated CFs composites, a significant increase of ILSS, IFSS and impact property were
achieved in the 5- min-modified CFs, which was 22.0, 44.4 and 22.7%, respectively (13.55, 9 and 16.6% for
10-min-modified CFs).
Meanwhile, the tensile strength (TS) of modified CFs showed a slightly increased in comparison with that of
untreated carbon fiber.
The paper also revealed that there is a optimum time of CB growth between 5 and 10 minutes, greater than
the critical time the carbon bonds begin to stack and decrease the strength of the fiber.
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