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Chapter 8
Amines
Amines
Amines:
CH3-NH2 CH3-NH-CH3
CH3 CH3
CH3—NH2 CH3—NH CH3—N—CH3
- Drop the final “-e” of the parent alkane and replace it by “-amine”.
- Use a number to locate the amino group (-NH2) on the parent chain.
NH2 NH2
NH2 3 5 1
CH3-CH-CH3 NH2 CH3-CH-CH-CH3
3 2
4
H2 N 6
NH2
3 2 1 CH3 CHCH31 2 4
Cl
2-Propanamine
2-propanamine Cyclohexanamine
3-chloro-2-butanamine 1,6-Hexan ediamine
1,6-hexanediamine
Naming Amines
Common name
CH3—CH2—NH2 ethylamine
CH3
|
CH3—N—CH2—CH3 ethyldimethylamine
Aniline (common name)
NH
CH22 CH3 CH3 CH=CH
Aniline
NH
CH22 CH3 CH3 NH
CH22 CH3 CH=CH
NH
CH22 CH3 CH3 CH=CH2
2 1 2
1
1 2
3 3CH3 3
4
4 CH3
Eth ylb enzene Etheylb
Toluen Cl enzene
Styren
Eth ylb
NOenzene Toluen e Styrene
2
– Name the smaller group(s) bonded to nitrogen, and show their locations
on nitrogen by using the prefix “N”.
CH3 CH
NHCH3 NHCH
N 3 N
CH3 C
N-Meth ylan iline N,N-Dimethyl-
N-Meth ylan ilineaniline N,N-Dimeth
cyclopentan amine cyclopentan a
CH3
CH3-N-CH2-CH3 N,N-Dimethylethanamine
Heterocyclic amines
N CH3
H H
H H
.. -...
N.. . ..O – H
+
CH3 + H – ..
O–H CH3 N H
H H
Some amines present in our blood and make it approximately basic (pH = 7.4).
Chemical properties of Amines
(b ) + CH3 COOH
N
Examples
Solutions: