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2015/2016
Exergy Analysis
• Exergy is …
• Thermomechanical exergy: if temperature and/or
pressure of a system differ from that of the
environment;
• Chemical exergy – if there is a composition difference
between the system and environment;
Evaluating Chemical Exergy
Steady state
e e
yCO 2 yH 2O
2
Example
Standard Molar Chemical Exergy, ech (kJ/kmol), of Selected Substances at 298 K and p0
Substance Formula Model Ia Model IIb
Oxygen O2(g) 3,950 3,970
Carbon dioxide CO2(g) 14,175 19,870
Water H2O(l) 45 900
Hydrogen H2(g) 235,250 236,100
Methane CH4(g) 824,350 831,650
Octane C8H18(l) – 5,413,100
Ethanol C2H5OH(l) 1,342,085 1,357,700
kJ
e ch
830,174
kmol
Example
Standard Molar Chemical Exergy, ech (kJ/kmol), of Selected Substances at 298 K and p0
Substance Formula Model Ia Model IIb
Oxygen O2(g) 3,950 3,970
Carbon dioxide CO2(g) 14,175 19,870
Water H2O(l) 45 900
Hydrogen H2(g) 235,250 236,100
Methane CH4(g) 824,350 831,650
Octane C8H18(l) – 5,413,100
Ethanol C2H5OH(l) 1,342,085 1,357,700
kmol
Example
=831,680kJ/kmol=51980kJ/kg
Standard Molar Chemical Exergy, ech (kJ/kmol), of Selected Substances at 298 K and p0
Substance Formula Model Ia Model IIb
Oxygen O2(g) 3,950 3,970
Carbon dioxide CO2(g) 14,175 19,870
Water H2O(l) 45 900
Hydrogen H2(g) 235,250 236,100
Methane CH4(g) 824,350 831,650
Octane C8H18(l) – 5,413,100
Ethanol C2H5OH(l) 1,342,085 1,357,700
Example
=831,680kJ/kmol=51980kJ/kg
H2 + 0.5O2 → H2O(l)
eFch gF 0.5gO2 gH2O(l) (T0, p0 ) eH
ch
2O(l) 0.5 e ch
O2
Standard Chemical Exergy
ch
eO 2
3,970 kJ/kmol
2O 900 kJ/kmol
ch
eH
TABLE A-26
Standard Molar Chemical Exergy, ech (kJ/kmol), of Selected Substances at 298 K and p0
Substance Formula Model Ia Model IIb
Oxygen O2(g) 3,950 3,970
Carbon dioxide CO2(g) 14,175 19,870
Water H2O(l) 45 900
Hydrogen H2(g) 235,250 236,100
Methane CH4(g) 824,350 831,650
Octane C8H18(l) – 5,413,100
Ethanol C2H5OH(l) 1,342,085 1,357,700
Standard Chemical Exergy
ch
eH
2 0 0.5(0) (237,180) (900) 0.5(3,970)
2 236,100 kJ/kmol
ch
eH
TABLE A-26
Standard Molar Chemical Exergy, ech (kJ/kmol), of Selected Substances at 298 K and p0
Substance Formula Model Ia Model IIb
Oxygen O2(g) 3,950 3,970
Carbon dioxide CO2(g) 14,175 19,870
Water H2O(l) 45 900
Hydrogen H2(g) 235,250 236,100
Methane CH4(g) 824,350 831,650
Octane C8H18(l) – 5,413,100
Ethanol C2H5OH(l) 1,342,085 1,357,700