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Chapter 17-18
Thermodynamics and
Electrochemistry
First Law of thermodynamics – Law of conservation of energy (of universe)
Enthalpy change: H (KJ/mol) is a state function, heat exchange at constant pressure.
Internal energy = total energy of the system
E = q + w q is the heat and w is work
SIGNS: + if being absorbed; + if work is done on the system)
Grams of Ca = Amp * time in seconds * (1 mol e /96500 C) * (1 mol Ca/2 mol e) * (molar mass Ca/1 mol Ca)