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Petrochemical Technology
Module 2
Petrochemical Precursors (Raw Material)
Course Outcome
OUTLINE
3. Production
processes,
2.Types of
safety and
precursor
waste
treatment
PRIMARY RAW MATERIALS
RAW
MATERIAL
PRIMARY
OTHER RAW
RAW
MATERIAL
MATERIAL
NG
Syn Gas
Hydrogen Sulfur Carbon Black
mixtures
Methane
Light HC
Ethane
Light Naptha
Primary Secondary RM/
(5-6 Carbon atom)
RM- CO/ NG Intermediates
BP: 30-90oC
Naphta
Heavy Naptha
Heavier HC (6-12 Carbon atom)
BP: 90-200oC
Gas Oil
Syngas:
Can be used Precursor of 2
Can be used as syn
as fuel big volume
gas mixtures
petrochem;
ammonia and
methanol
To produce
Chemicals
fuel
OTHER RAW MATERIALS- OIL
SHALE
Oil shale is a sedimentary rock containing organic
matter rich in hydrogen, known as kerogen Estonian oil
shale:
Thermal Combustion
Drying decomposition
To condensation
OTHER RAW MATERIALS- TAR
SAND (OIL SAND)
• Large deposits of sand saturated with bitumen and water
• Commonly found at or near the earth’s surface
• Western Canada is the largest producer- produce 99%
Canada’s crude oil
• Difficult to handle – summer: soft, sticky
- winter: hard, solid material
Bitumen derived fom the oil sands deposits in Alberta, Canada
areas has an API gravity of around 8oAPI. It is upgraded to an
API gravity of 31oAPI to 33oAPI. The upgraded oil is known as
synthetic crude.
OTHER RAW MATERIALS- GAS
HYDRATES
• Ice-like material; constituted of methane molecule encaged in
cluster of water molecules and held together by hydrogen; H
bond
• This material occurs in large underground deposits found
beneath the ocean floor on continental margins and in places
north of the arctic circle such as Siberia.
• It is estimated that gas hydrate deposits contain twice as
much carbon as all other fossil fuels on earth.
• If proven feasible for recovery, could be a future energy as
well as chemical source for petrochemicals.
• A solid material only under high pressure and low
temperature; hence it cannot be processed by conventional
methods used for natural gas and crude oils.
Summary
References & Acknowledgement
• Jacob A. Moulijn, Michiel Makkee, Annelies Van Diepen
(2007). Chemical Process Technology. John Wiley & Sons.
Developer
Zarina Omar
zarin363@tganu.uitm.edu.my
Faculty of Chemical Engineering