Академический Документы
Профессиональный Документы
Культура Документы
the Earth
http://en.wikipedia.org/wiki/Natural_resources
2
http://www.ecofriendlykids.co.uk/NaturalResourcesEarth.html
Renewable Resources(再生資源)
• They can restock (renew) themselves, be used indefinitely if
they are not over-harvested.
• If consumed at a rate that exceeds their natural rate of
replacement, the standing stock will diminish and eventually
run out.
• Examples of living renewable resources:
• trees (forests and woodlands) and crops
• fish and livestock
• Examples of non-living renewable resources:
• fresh water
• fresh air
• Flow renewable resources (or simply “flow resources”):
renewable, but needing no regeneration or re-growth
e.g., wind, tidal, and solar energy
http://en.wikipedia.org/wiki/Natural_resources
3
http://www.ecofriendlykids.co.uk/NaturalResourcesEarth.html
Non-renewable Resources (非再生資
• Fossil fuels, such as coal, petroleum, and natural gas are often
considered non-renewable resources, as they do not naturally
re-form at a rate that makes the way we use them sustainable.
4
http://en.wikipedia.org/wiki/Natural_resources
Natural Resources and Their
Products
• Forests: timber (for building houses, boats, decks, and furniture;
and making paper)
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http://www3.iptv.org/exploremore/land/issues/iss_natu/natural_resources.cfm
Minerals and Their Chemical
Components
Exercise:
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“Periodic Chart.pdf” in http://www.mii.org/
Common Minerals and Their Uses
Exercise:
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http://www.mii.org/commonminerals.html
Cement & Concrete
Cement: 水泥
Concrete:混凝土
Cement:
• made from limestone, calcium, silicon, iron, and aluminum, plus
lesser amounts of other ingredients
• When water is added to cement, a chemical process occurs as it
dries, allowing it to harden.
Concrete:
• cement + aggregates (e.g., sand, stone)
• Important and widely-used construction material
• Strengthened by steel-rod skeleton
• Annual production: about 6 billion tons
(~1 ton each person on the Earth)
• Life: 50,000 years
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http://www.wisegeek.com/what-is-the-difference-between-concrete-and-cement.htm
Recycling(循環)
Exercise:
9
http://en.wikipedia.org/wiki/Recycling
Recycling (循環)
• Aggregates and concrete
Crushed and used as aggregates for new concrete
• Batteries
Difficulty: so many types of batteries
Some old types contain mercury and cadmium
Lead-acid battery (mostly used in automobiles): containing lead
• Biodegradable waste
• Electronics waste (recovering metals)
• Various types of metals (e.g., _________________________________)
• Paper
• Glass
• Plastic
• Rubber
• Textiles
• Timber
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http://en.wikipedia.org/wiki/Recycling
Metals
In chemistry:
• A metal is an element that readily loses electrons to form positive
ions (cations) and the cations are surrounded by a sea of
electrons
• Most metals form ionic bonds with non-metals [but not always,
e.g., in Pb(C2H5)4, there is Pb–CH2CH3 covalent bond]
Physical properties:
• Electrical conducting +
+
• Some hard, some soft, some being liquid
+ +
+
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http://en.wikipedia.org/wiki/Metal
Alloys(合金)
• Alloy: a homogeneous mixture of two or more elements, at least
one of the elements is a metal, the resulting mixture has metallic
properties.
Example
The major component of steel is iron and steel is stronger than
iron.
If chromium is added, we have stainless steel which can resist
corrosion.
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http://en.wikipedia.org/wiki/Alloy
Examples of Alloys
• Carbon steel:
iron + carbon (higher carbon content, stronger but more brittle)
- Low carbon steel: ~0.05 – 0.3% carbon content
- Ultra-high carbon steel : ~1 – 2% carbon content
• Stainless steel: steel + chromium (> 10%)
• Brass: copper + zinc (typically ~30 – 35%)
• Solder:
Conventional: Sn60/Pb40 (60% tin + 40% lead)
Lead-free: e.g., SnAgCu (tin + silver + copper);
http://en.wikipedia.org/wiki/Carbon_steel
different SnAgCu compositions: different melting points http://en.wikipedia.org/wiki/Stainless_steel
http://en.wikipedia.org/wiki/Brass
http://en.wikipedia.org/wiki/Bronzes
http://en.wikipedia.org/wiki/Rose_gold
http://en.wikipedia.org/wiki/Solder 13
http://en.wikipedia.org/wiki/List_of_alloys
Energy Resources
• Solar energy
• Wind energy
• Water-related: hydro power
pumped-storage
tidal power
wave power
• Geothermal energy
• Biomass energy
• Garbage energy
• Nuclear energy
• Fossil fuels
14
http://home.clara.net/darvill/altenerg/index.htm
Generation of Electrical
Energy(電能)
• Electrical energy is easily transported (from power plants to
individual customers)
15
Faraday‘s Law(法拉第定律) of
Induction
• In effect:
Changing magnetic field electrical current
http://hyperphysics.phy-astr.gsu.edu /Hbase/electric/farlaw.html
16
Turbine(渦輪機)
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http://en.wikipedia.org/wiki/Turbine
Solar Energy(太陽能)
• Energy from the Sun
• The Sun is a nuclear reactor, 150 million km away. Only a small
fraction of light energy and heat energy (1 part in 1010) reaches
the Earth, but it is a huge amount to the Earth.
Increasing wavelength
Ultra-violet(UV) Visible Infra-red (IR)
Example:
http://www.cuhk.edu.hk/greencampus/en/communication/sc_sp
ring07.pdf
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Wind Energy(風能)
• Energy from wind
• Ancient application: sailing
• Used since Middle Ages: windmill
• Electricity generation:
wind turbine electricity
(reverse of electric fan operation)
Propeller blades
Tower
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http://home.clara.net/darvill/altenerg/index.htm
Hydro Power(水力)
• Energy from the flow of water:
(potential energy of water kinetic energy of water …)
• Ancient application: corn grinding, sailing, war
• Used nowadays to generate 20% of the world’s electricity
Dam
Reservoir Turbine
Generator
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http://home.clara.net/darvill/altenerg/index.htm
Pumped Storage Reservoirs
• They are not facilities or methods to generate electrical power.
They are a way of storing energy so that it can be released
quickly when needed.
23
http://home.clara.net/darvill/altenerg/index.htm
Off-shore Station
http://www.swanturbines.co.uk/ http://www.marineturbines.com/technical.htm
24
Wave Power
• Wave: generated by wind on sea surface
• Method: reverse of a swimming pool wave machine
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http://home.clara.net/darvill/altenerg/wave.htm
Geothermal Energy(地熱能)
• The centre of the Earth: ~6000 C
hot enough to melt rock
• A few km down the surface: > 250 C
• Used for thousands of years in some countries for cooking and
heating
Power station
• If hot enough to
produce steam
electricity
• If not: heating
Cold Hot
water water
down down
Hot region
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http://home.clara.net/darvill/altenerg/geothermal.htm
Biomass(生物量)
• Energy from organisms (usually plants)
• Example: burning of wood for heat and light
• Extraction of fuel: ethanol by fermentation:
corns / canes cane sugar ethanol
• Biodiesel: a fuel made from vegetable oil that runs in any
unmodified diesel engine.
Triglycerides (三酸甘油酯)
(Esters of glycerol with long-chain fatty acids)
27
Triglycerides Biodiesel
NaOH
+
CH3OH
Glycerol
Glycerol part Fatty acid portions Methyl
esters of
fatty acid
(Biodiesel)
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Biodiesel
Example:
1994 Dodge:
100,000 miles on 100% Rapeseed (芥花籽)
29
Garbage Energy
• Burning garbage: generating heat energy, but serious
pollution (e.g., dioxin)
• Bacterial action: generating landfill gas (mainly methane,
CH4)
30
Basis of Nuclear Physics
& Nuclear Power
31
Testing your knowledge on:
molecules, atoms, and subatomic particles
32
Testing your knowledge on:
molecules, atoms, and subatomic particles
Exercise (fill-in-the-blank):
Isotopes are atoms of the same _______ but having different
numbers of ________ in their ________.
33
Nuclides(核素)
1
1H
13
2 12 6C
1H 6C
34
Radioactive(放射性)Substances
35
Radioactivity(放射現象)
The phenomena of radioactivity was discovered in 1896. This
radiation was later shown to be separable by electric (or
magnetic) fields into three types: alpha (a), beta (b) and
gamma (g) rays.
–
a ray
Lead block
Electric plate (negative) Luminescent screen
36
Stability of Nuclides(核穩定性)
37
Radioactive Decay Products
• Neutron
38
Interaction of Radiation with Cells
Examples:
inhibition of cell division, denature of enzymes, mutation of
genetic materials
39
Rate of Radioactive Decay
• Half-life (t1/2): the time it takes for half of its original amount
to decay
1
1 ½ ¼ 1/8 0.9
1/16 …. 0.8
0.7
left. 0.5
lives, 0.3
0
0 10 20 30 40 50 60 70 80 90 100
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Half-lives of Some Radionuclides
Each radionuclide has a characteristic t1/2
Radionuclide Half-life
81Kr 13 seconds
38K 7.6 min
73Se 7.2 hr
131I 8 days
60Co 5.3 yr
137Cs 30 yr
14C 5730 yr
129I 17 million yr
235U 703 million yr
40K 1260 million yr
41
Sources of Radiation
Natural Radiation
• cosmic rays
• terrestrial radiation (including radon)
• food & drinks (40K within body)
Artificial Radiation
• medical instruments
• leakage/disposal
• radioactive fallout (weapon testing)
• consumer products, e.g., smoke detectors, “glow in
the dark” watches
42
Nuclear Fuel(核燃料)
Ba
235U +n 139Ba + 94Kr + 3n n
U
n
Characteristics: 235
n
• Bombarded by neutron Kr
• Chain reaction: Ba
n
Ba
n
1 neutron in, n
U
n
U
n
235 235
3 neutrons out. This neutron
n n
starts the chain Kr Kr
reaction
Ba
But not every neutron can hit n
U
an 235U nucleus. 235
n
n
The reaction may eventually stop. Kr
http://home.att.net/~cat4a/nuclear_III.htm 43
Enriched Nuclear Fuel(核燃料)
To make the chain reaction self-sustaining,
we need to use:
(1) uranium enriched in 235U
44
Critical Mass(臨界質量)
Critical mass: sphere of 600 kg for 15% 235U (~40 cm diameter)
Higher 235U percentage: larger/smaller critical mass
Neutron reflector: larger/smaller critical mass
45
http://en.wikipedia.org/wiki/Image:Critical_mass.svg
Nuclear Power Plant(核能發電廠)
http://science.howstuffworks.com/nuclear-power2.htm
Containment Structure
Steam Generator
Steam Line
Reactor
Turbine
Control
Rods Generator
Cooling Tower
Cooling Water
Pumps Condensor
Neutron absorber
(e.g., boron, cadmium)
46
http://hyperphysics.phy-astr.gsu.edu/hbase/nucene/control.html
Other Nuclear Fuels
47
Nuclear Fusion(核聚變)
48
http://en.wikipedia.org/wiki/Nuclear_fusion
Human-made Nuclear Fusion
49
Nuclear Fusion(核聚變)
in Nuclear Power Plant
50
Accidents of Nuclear Power Plants
51
Nuclear Weapons &
Nuclear Power Plants
Concerns:
• 235U: needs extra work to enrich its percentage
• 329Pu: created in a uranium reactor, the percentage of which is
high enough for nuclear weapons
Advantages
• No CO2 is emitted
• No air is needed
Disadvantages
• In case of accident, the damage is serious
• Using and producing materials, which are the source for
nuclear weapons
• Disposal of nuclear waste: waste cannot be “destroyed”
53
Fossil Fuels(化石燃料)
Industrial Revolution:
increases in the use of fossil fuels
54
What are fossil fuels?
55
Types of Fossil Fuels(化石燃料)
• Coal
• Petroleum (oil)
• Natural gas
• Tar sands and oil shale
• Methane hydrate
56
Carbon Cycle
Exercise:
Find out the carbon distribution in the Nature from internet.
Atmosphere ( )
Vegetation ( )
Fossil Fuels & Cement
Production ( )
Soils ( )
Surface Ocean ( )
Marine Biota ( )
Deep Ocean ( )
http://en.wikipedia.org/wiki/British_thermal_unit 58
http://www.opm.state.ct.us/pdpd2/energy/flows94.htm
Coals(煤)
Most abundant of all fossil fuels, the largest single source of fuel
for the generation of electricity world-wide
59
http://en.wikipedia.org/wiki/Coal
Worldwide Coal Production
Exercise:
Find out the worldwide coal production, coal reserves, and major
coal exporters.
60
Processing of Coal
61
Petroleum(石油)(Oil, Crude Oil)
62
Oil Producing and Consuming
Countries
Exercise:
63
Petroleum(石油)
• Hydrocarbon, mostly alkane (saturated CxHy): C5H12 to C18H38
64
Oil Refinery: Separating Components of
Different Molecular Weights
Exercise:
http://en.wikipedia.org/wik
i/Image:RefineryFlow.png
65
http://en.wikipedia.org/wiki/Oil_refinery
Cracking(裂解)
• e.g. CH3CH2CH2CH3
CH2=CH2 + CH3CH3
66
Knocking of Gasoline(汽油)
• Consequences of knocking:
power loss and engine wearing
67
http://en.wikipedia.org/wiki/Octane_rating
Octane Rating
68
http://en.wikipedia.org/wiki/Octane_rating
Octane Rating
iso-octane: set at 100 n-heptane: set at 0
Example:
84 liters of iso-octane + 16 liters of n-heptane
84% (by volume) in iso-octane
16% (by volume) in n-heptane
Octane Rating: 84
e.g.,
n-octane: -10
benzene: 101
ethane: 108
70
http://en.wikipedia.org/wiki/Image:09-03-06-Octane.jpg
Anti-knocking Agent
Tetra-ethyl lead (TEL):
• Added to gasoline to increase octane rating
• About 0.05% of TEL in gasoline
• Pb(CH2CH3)4, mostly covalent in nature, not containing Pb4+ and
CH2CH3–
How it works:
• Knocking causes formation of radicals, e.g., CH3, from gasoline
• Chain reaction: these radicals destroy other gasoline molecules
• Pb(CH2CH3)4 Pb(CH2CH3)3 + CH2CH3 (or Pb + 4 CH2CH3 ?)
These radicals from TEL and remove radicals from gasoline
Sometime literatures say that Pb + O2 PbO2
and the PbO2 reacts with the radicals from gasoline
71
Problems of Leaded Gasoline
Rh = rhodium
Pt = platinum
Both are metals with catalytic property
72
Natural Gas(天然氣)
• Formation process: similar to that of petroleum
• Components: (%)
methane (CH4): 70 – 90
ethane (C2H6): 5 – 15
propane (C3H8), butane (C4H10): < 5
Exercise:
73
Tar Sand
• Worldwide sources:
Canada, Venezuela, and USA.
74
http://en.wikipedia.org/wiki/Tar_Sands
Oil Shale(油頁岩)
• A fine-grained sedimentary rock containing significant traces
of kerogen (a solid mixture of organic chemical compounds)
that have not been buried for sufficient time to produce
conventional fossil fuels.
75
http://en.wikipedia.org/wiki/Oil_shale
Methane Hydrate (Methane Ice)
• Ice that contains a large amount of methane within its crystal
structure
76
http://en.wikipedia.org/wiki/Methane_hydrates