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Engineering India
Engineering Metallurgy
By
Dr. Bharat S. Padekar
(PhD IIT Bombay, India & Monash University, Australia)
Definitions
• System-Part of the universe under study
• Phase- Homogeneous, physically distinct and
mechanically separable part of the system
• Variable- a particular phase exist under various
conditions of temperature, pressure and
concentration– these are called as variable
• Component- elements present in the system
• Alloy- mixture of two or more elements having
metallic properties.
Why Alloys
To impart
• Strength
• Toughness
• Machinability
• Formability / Ductility
• Creep resistance
• Fatigue resistance
• Corrosion Resistance
Stable equilibrium exists when the object is in its lowest energy condition;
metastable equilibrium exists when additional energy must be introduced before
the object can reach true stability; unstable equilibrium exists when no additional
energy is needed before reaching metastability or stability
Pressure Temperature phase diagram of
Water
• P = Number of phase
• C = Number of components
• F = Number of Degrees of Freedom
(temperature and pressure)
In metallurgical and materials engineering,
pressure is maintained at one atmosphere and
the Gibbs Phase Rule reduces to
F=C-P+1
Binary Phase Diagram
Mg Al
Mg Phase on grain boundary